Authenticating the recovery location of meteorites: The case of Castenaso

Abstract— This forensic work aims to authenticate the recovery location of Castenaso, a 120 g ordinary chondritic (L5) meteorite reportedly found in 2003 along the sandy bank of the Idice Stream, near the village of Castenaso (Bologna, Emilia‐Romagna, Italy). Using the hypothesis that Castenaso was instead a hot‐desert meteorite, we conducted a comparative mineralogical and geochemical study of major weathering effects on European and Saharan ordinary chondrites as potential markers of the environment where Castenaso resided during its terrestrial lifetime. Inductively coupled plasma‐mass spectrometry (ICP‐MS) data reveals that Castenaso is significantly enriched in Sr, Ba, Tl, and U, and suggests geochemical alteration in a hot‐desert environment. The alteration is minor: Castenaso is not coated by desert varnish and does not show significant light rare earth element (LREE) enrichment or loss of Ni and Co. The apparent contrast in size, morphology, and composition between the soil particles filling the external fractures of Castenaso and those from the bank of the Idice Stream observed under the scanning electron microscope (SEM) suggests that Castenaso did not reside at the reported find location. Abraded quartz grains (up to 1 mm in size) in Castenaso are undoubtedly from a hot‐desert eolian environment: they are well‐rounded and show external surfaces characterized by the presence of dish‐shaped concavities and upturned silica plates that have been subject to solution‐precipitation and subsequent smoothing. We therefore conclude that Castenaso is one of the many hot‐desert ordinary chondrite finds, probably from the Sahara, that is currently available on the market. This forensic work provides the scientific grounds for changing the name of this meteorite.     

Fabrication of synthetic calcite–muscovite rocks with variable texture — An analogue to cataclasite fabrics?

A series of large diameter calcite–muscovite aggregates has been prepared from calcite and muscovite powders, in order to gain a better understanding of how texture develops in impure carbonate rocks. The development of the microstructure and the crystallographic preferred orientation (CPO, texture) during the preparation process is described. The synthetic rocks have been fabricated from powders of calcite and muscovite by uniaxial cold-pressing at loads up to 400 MPa and subsequent hot isostatic pressing (HIPping) at pressures of 150 to 170 MPa and a temperature of 670 °C. The resulting textures and microstructures are homogeneous throughout the samples. The calcite CPO is generated by rigid body rotation and twinning during cold-pressing and is not significantly altered by recrystallization during HIPping. Grain growth during HIPping is observed in pure calcite samples, but is inhibited through high porosity and the presence of muscovite in the mixed aggregates. The preferred orientation of the calcite c-axes is found to increase with increasing uniaxial cold pressure, and to be independent of the muscovite content. The magnetic bulk susceptibility of the starting material has been changed by the formation of ferromagnetic impurities during fabrication. Comparison of the samples to natural calcite fabrics from fault zones show the potential of the experiments and fabric analyses presented to analyze and to better understand the deformation mechanisms of fault zones.     

A Combined Analytical and Numerical Approach for the Evaluation of Radial Loads on the Lining of Vertical Shafts

The evaluation of the load acting on a shaft support is of fundamental importance for the correct dimensioning of the structure. The load acting on the support can appear somewhat complex. One approach to define the load on the lining may be to use the convergence-confinement method (CCM) normally used in the tunneling design. This process involves intersecting the convergence-confinement (CC) curve with the support reaction line. However, in order to be able to adopt this technique, it is necessary to know the radial displacement of the shaft wall at the point in which the support is to be installed. Using the equations of Vlachopoulos and Diederichs (Rock Mech Rock Eng 42:131–146, 2009) the reaction line of the support can be calculated. Numerical models developed with Flac 2D v.6.0 considering the Mohr–Coulomb criterion and an ideal elasto-plastic behavior simulating stepwise excavation and support installation were developed. The relation between applied internal stress and radial displacement of the wall shaft, obtained by the numerical simulation was compared with the CC curve obtained by the CCM and it showed a good match between the two methods. However, an iterative procedure has also been used to insert the reaction line in the CC graph. The result shows lower initial displacements (and therefore greater radial stress) when compared with the values obtained by numerical calculation with the axisymmetric model. It is therefore recommended the combined use of the CCM (analytical method) and the axisymmetric numerical model (step by step simulation) to obtain the values of the final load on the lining and the final plastic radius, necessary for the correct design of supporting structures on the shaft wall.     

Analysis of the Maierato landslide (Calabria,Southern Italy)

On 15 February 2010, a landslide of great dimensions occurred at Maierato (Calabria, Southern Italy) after a long rainy period. Although the zone was continuously affected by ground movements especially during the wet seasons, no monitoring system was installed before the occurrence of the landslide. However, many photos and two videos were taken during the failure process of the slope. In the present study, the available images are used to reconstruct the kinematics of the landslide. In addition, a finite element analysis is performed to define the main factors of triggering and to interpret the failure mechanism of the slope. This analysis is also based on the data from a site investigation carried out after the landslide to characterise the involved soils from a geotechnical viewpoint. The analysis also accounts for the strain-softening behaviour of some soils. The results have shown that the Maierato landslide was the reactivation of a pre-existing landslide body, which was caused by a significant increase in groundwater level.     

Millennial-scale shifts in microtidal ecosystems during the Holocene: dynamics and drivers of change from the Po Plain coastal record (NE Italy)

Framed into a robust stratigraphic context, multivariate analyses on the Holocene palaeobiological record (pollen, benthic foraminifers, ostracods) of the Po coastal plain (NE Italy) allowed the investigation of microtidal ecosystems variability and driving parameters along a 35-km-long land–sea transect. Millennial-scale ecosystem shifts are documented by coeval changes in the meiofauna, reflecting variations in organic matter–water depth (shallow-marine environments) and degree of confinement-salinity (back-barrier settings). In-phase shifts of vegetation communities track unsteady water-table levels and river dynamics in freshwater palustrine areas. Five environmental–ecological stages followed one another crossing four tipping points that mark changes in relative sea level (RSL), climate and/or fluvial regime. At the culmination of Mediterranean RSL rise, after the 8200 event, remarkable growth of peatlands took place in the Po estuary, while low accumulation rates typified the shelf. At the transgressive–regressive turnaround (~7000 cal a bp ), the estuary turned into a delta plain with tidally influenced interdistributary embayments. River flow regime oscillations after the Climate Optimum (post-5000 cal a bp ) favoured isolation of the bays and the development of brackish wetlands surrounded by wooded peatlands. The youngest threshold (~800 cal a bp ), which led to the establishment of the modern delta, reflects a major avulsion of the Po River.     

The dynamics of central Main Ethiopian Rift waters: Evidence from δD, δO and Sr/Sr ratios

Water samples from cold and geothermal boreholes, hot springs, lakes and rivers were analyzed for δD, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr compositions in order to investigate lake water–groundwater mixing processes, water–rock interactions, and to evaluate groundwater flow paths in the central Main Ethiopian Rift (MER) of the Ziway–Shala basin. Different ranges of isotopic values were recorded for different water types: hot springs show δ¹⁸O −3.36 to +3.69 and δD −15.85 to +24.23, deep Aluto-Langano geothermal wells show δ¹⁸O −4.65 to −1.24 and δD −12.39 to −9.31, groundwater wells show δ¹⁸O −3.99 to +5.14 and δD −19.69 to +32.27, whereas the lakes show δ¹⁸O and δD in the range +3.98 to +7.92 and +26.19 to +45.71, respectively. The intersection of the Local Meteoric Water Line (LMWL: δD = 7 δ¹⁸O + 11.2, R² = 0.94, n = 42) and the Local Evaporation Line (LEL: δD = 5.63δ¹⁸O + 8, n = 14, R² = 0.82) was used to estimate the average isotopic composition of recharge water into the basin (δD = −5.15 and δ¹⁸O = −2.34). These values are depleted if compared with the modern-day average precipitation, presumably indicating paleo-groundwater components recharged during previous humid climatic phases. The measured stable isotope values indicate that the geothermal wells, some of the hot springs and groundwater wells mainly consist of meteoric water. The Sr isotopic signatures in all waters are within the range of the Sr isotopic composition of the rift basalts and rhyolites. The variability of Sr isotopic data also pinpoints complex water–rock interaction and mixing processes in groundwater and surface water. The ⁸⁷Sr/⁸⁶Sr ratio ranges from 0.70445 to 0.70756 in the hot springs, from 0.70426 to 0.70537 in two deep geothermal wells, and from 0.70673 to 0.70721 in the rift lakes Ziway, Langano, Shala and Awasa. The radiogenic composition recorded by the lakes indicates that the input water was predominantly affected by progressive interaction with rhyolitic volcanics and lacustrine sediments.     

Nickel abundance in stony cosmic spherules: Constraining precursor material and formation mechanisms

Abstract– We report bulk and olivine compositions in 66 stony cosmic spherules (Na₂O < 0.76 wt%), 200–800 μm in size, from the Transantarctic Mountains, Antarctica. In porphyritic cosmic spherules, relict olivines that survived atmospheric entry heating are always Ni‐poor and similar in composition to the olivines in carbonaceous or unequilibrated ordinary chondrites (18 spherules), and equilibrated ordinary chondrites (one spherule). This is consistent with selective survival of high temperature, Mg‐rich olivines during atmospheric entry. Olivines that crystallized from the melts produced during atmospheric entry have NiO contents that increase with increasing NiO in the bulk spherule, and that range from values similar to those observed in chondritic olivines (NiO generally <0.5 wt%) to values characteristic of olivines in meteoritic ablation spheres (NiO > 2 wt%). Thus, NiO content in olivine cannot be used alone to distinguish meteoritic ablation spheres from cosmic spherules, and the volatile element contents have to be considered. We propose that the variation in NiO contents in cosmic spherules and their olivines is the result of variable content of Fe, Ni metal in the precursor. NiO contents in olivines and in cosmic spherules can thus be used to discuss their parent body. Ni‐poor spherules can be derived from C‐rich and/or metal‐poor precursors, either related to CM, CI, CR chondrites or to chondritic fragments dominated by silicates, regardless of the parent body. Ni‐rich spherules (NiO > 0.7 wt%) that represent 55% of the 47 barred‐olivine spherules we studied, were derived from the melting of C‐poor, metal‐rich precursors, compatible with ordinary chondrite or CO, CV, CK carbonaceous chondrite parentages.     

Gebel Kamil: The iron meteorite that formed the Kamil crater (Egypt)

Abstract– The 45 m in diameter Kamil impact crater was formed <5000 yr ago in the eastern Sahara, close to the southern border of modern Egypt. The original features of this structure, including thousands of fragments of the meteorite impactor, are extremely well preserved. With the exception of a single 83 kg regmaglypted individual, all specimens of Gebel Kamil (the iron meteorite that formed the Kamil crater) are explosion fragments weighing from <1 g to 34 kg. Gebel Kamil is an ungrouped Ni‐rich (about 20 wt% Ni) ataxite characterized by high Ge and Ga contents (approximately 120 μg g^?1 and approximately 50 μg g^?1, respectively) and by a very fine‐grained duplex plessite metal matrix. Accessory mineral phases in Gebel Kamil are schreibersite, troilite, daubréelite, and native copper. Meteorite fragments are cross‐cut by curvilinear shear bands formed during the explosive terrestrial impact. A systematic search around the crater revealed that meteorite fragments have a highly asymmetric distribution, with greater concentrations in the southeast sector and a broad maximum in meteorite concentration in the 125–160° N sector at about 200 m from the crater rim. The total mass of shrapnel specimens >10 g, inferred from the density map compiled in this study is 3400 kg. Field data indicate that the iron bolide approached the Earth’s crust from the northwest (305–340° N), travelling along a moderately oblique trajectory. Upon hypervelocity impact, the projectile was disrupted into thousands of fragments. Shattering was accompanied by some melting of the projectile and of the quartz‐arenite target rocks, which also suffered shock metamorphism.     

Magnetic classification of stony meteorites: 3. Achondrites

Abstract— A database of magnetic susceptibility measurements of stony achondrites (acapulcoite‐lodranite clan, winonaites, ureilites, angrites, aubrites, brachinites, howardite‐eucrite‐diogenite (HED) clan, and Martian meteorites, except lunar meteorites) is presented and compared to our previous work on chondrites. This database provides an exhaustive study of the amount of iron‐nickel magnetic phases (essentially metal and more rarely pyrrhotite and titanomagnetite) in these meteorites. Except for ureilites, achondrites appear much more heterogeneous than chondrites in metal content, both at the meteorite scale and at the parent body scale. We propose a model to explain the lack of or inefficient metal segregation in a low gravity context. The relationship between grain density and magnetic susceptibility is discussed. Saturation remanence appears quite weak in most metal‐bearing achondrites (HED and aubrites) compared to Martian meteorites. Ureilites are a notable exception and can carry a strong remanence, similar to most chondrites.