Sedimentary record of redox-sensitive elements (U, Mn, Mo) in a transitory anoxic basin (the Thau lagoon, France)

In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H₂S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H₂S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.     

Institutional ambiguity in implementing the European Union Marine Strategy Framework Directive

This article addresses the institutional ambiguity that exists between the European, Regional and Member State levels in the implementation of the Marine Strategy Framework Directive (MSFD). The two main reasons for the emergence of institutional ambiguity are (1) the MSFD being a framework directive and (2) Member States are required to coordinate the implementation of the MFSD through the Regional Sea Conventions. Institutional ambiguity refers to the interference zone between different institutional settings that come together in new policy practices. New rules of the game are needed to bring these institutional settings together and the room to manoeuvre for the actors who negotiate these rules is a defining feature of institutional ambiguity. This article analyses the institutional ambiguity associated with MSFD implementation on the European and regional level for four European Seas: the North Sea, the Baltic Sea, the Mediterranean Sea and the Black Sea. The results indicate different levels of institutional ambiguity in each of the four regions, with the lowest level of ambiguity in the Baltic Sea and the highest in the Mediterranean Sea. Institutional ambiguity also exists on the European level, as coordination efforts have not resulted in clear directions for the implementation of the MSFD as yet. The level of institutional ambiguity is influenced by the relative number of EU member states bordering the particular sea and whether they consider implementation of the MFSD to be urgent. Member States bordering the Mediterranean and the Black Seas lack the support of Regional Sea Conventions in addition to receiving limited direction from the European level.     

Significance of a combined approach for replacement stones in the heritage buildings’ conservation frame

Stone substitution is a conventional operation during heritage buildings’ restoration, but becomes problematic for architects and restorers when the quarry is mined out. The compatibility of the substitution stones with the original ones has been for long mainly based on the aesthetical aspect, this resulting too often in a patchwork of original and substitution stones with different patina after several years because of differences of properties. In this study, the objective is to show how substitution stones can be selected by combining aesthetic criteria and stones properties that are relevant for analyzing their compatibility. A couple of French limestones with their potential substitution stones were selected for the study. Our results showed that potential substitution stones selected on their aesthetic criteria require to be rejected because of their differences of physical properties. On the other hand, our results showed also the possibility to select substitution stones with satisfactory aesthetic aspect and properties that enable to expect a satisfactory compatibility with the original stone.     

Geochemical diversity in S processes mediated by culture-adapted and environmental-enrichments of Acidithiobacillus spp.

Coupled S speciation and acid generation resulting from S processing associated with five different microbial treatments, all primarily Acidithiobacillus spp. (i.e. autotrophic S-oxidizers) were evaluated in batch laboratory experiments. Microbial treatments included two culture-adapted strains, Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans, their consortia and two environmental enrichments from a mine tailings lake that were determined to be >95% Acidithiobacillus spp., by whole-cell fluorescent hybridization. Using batch experiments simulating acidic mine waters with no carbon amendments, acid generation, and S speciation associated with the oxidation of three S substrates (thiosulfate, tetrathionate, and elemental S) were evaluated. Aseptic controls showed no observable pH decrease over the experimental time course (1 month) for all three S compounds examined. In contrast, pH decreased in all microbial treatments from starting pH values of 4 to 2 or less for all three S substrates. Results show a non-linear relationship between the pH dynamics of the batch cultures and their corresponding sulfate concentrations, and indicate how known microbial S processing pathways have opposite impacts, ultimately on pH dynamics. Associated geochemical modeling indicated negligible abiogenic processes contributing to the observed results, indicating strong microbial control of acid generation extending over pH ranges from 4 to less than 2. However, the observed acid generation rates and associated S speciation were both microbial treatment and substrate-specific. Results reveal a number of novel insights regarding microbial catalysis of S oxidation: (1) metabolic diversity in S processing, as evidenced by the observed geochemical signatures in S chemical speciation and rates of acid generation amongst phylogenetically similar organisms (to the genus level); (2) consortial impacts differ from those of individual strain members; (3) environmental enrichments of Acidithiobacillus spp. catalyze different S reaction arrays than pure strain Acidithiobacillus spp.; and (4) microbial catalysis of S reactions involves significant disproportionation tied to substantial H⁺ consumption, with the formation of as yet, poorly characterized intermediate S species, most likely polythionates and polysulfane monosulfonic acids that are thought to be involved in microbial S storage mechanisms.     

New high resolution observations of the solar diameter from space and ground with the microsatellite program PICARD

The PICARD microsatellite mission will provide 2 to 6 years simultaneous measurements of the solar diameter, differential rotation and solar constant to investigate the nature of their relations and variabilities. The 100 kg satellite has a 40 kg payload consisting of 3 instruments which will provide an absolute measure (better than 10 milliarcsec) of the diameter and the solar shape, a measure of total solar irradiance, and UV and visible flux in selected wavelength bands. Now in Phase B, PICARD is expected to be launched before mid-2003. The engineering model of the diameter telescope will be used on ground simultaneously with the satellite to investigate the atmospheric bias and state on the possible accuracy of the ground measurements carried up to now. We review the scientific goals linked to the diameter measurement, present the payload, and give a brief overview of the program aspects.     

Early Devensian (MIS 5d–5b) occupation at Dartford,southeast England

A deeply buried horizon containing mint‐condition flint artefacts was discovered in 2006 during archaeological investigations in advance of major roadworks near Dartford, Kent, in southeast England. The context of the artefacts and the freshness of their condition suggest this horizon represents a buried occupation surface. Optically stimulated luminescence dating places this horizon in the period Marine Isotope Stage 5d–5b, early in the British Devensian glaciation. This paper describes details of the artefacts, their context and dates, and outlines how this apparent occupation fits in with the wider pattern of Neanderthal settlement in Britain and northwest Europe in the later Pleistocene. Copyright © 2010 John Wiley & Sons, Ltd.