多空隙组合地质单元渗流理论分析与试验

岩体通常是以孔隙岩石为基质并包含各种成因的裂隙和溶隙的复杂多空隙组合地质材料。为研究孔隙-裂隙-溶隙多空隙组合介质的渗流特性,在简要介绍多孔介质渗流Darcy定律、平板窄缝流Poiseuille定律和圆形管道流Darcy-Weibach理论的基础上,分析了几种孔隙-裂隙-溶隙组合情况的多空隙介质渗流特性,推导出相应组合的等效渗透系数KE,给出了描述多空隙组合介质KE的一般表达式,讨论了影响各种空隙组合KE的主要因素。以普通砖模拟岩石基质,通过砖身钻孔填充及砖间缝隙填充,试验模拟了岩溶岩体和裂隙岩体中溶孔和裂隙填充后的渗透情况。试验结果与所推求理论公式计算出的KE在同一量级且误差很小,很好地验证了所推导的多空隙组合介质渗透系数表达式的有效性。     

Iron isotopic analyses of geological reference materials on MC-ICP-MS with instrumental mass bias corrected by three independent methods

Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and ⁵⁷Fe–⁵⁸Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ⁵⁶Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ⁵⁶Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ⁵⁷Fe?=?0.534?±?0.010, 2SE).     

Magma type and genesis of the basic-ultrabasic layered intrusions in Panzhihua-Xichang area,Southwest China

The layered intrusions in the Panzhihua-Xichang area may be grouped into two types: basic rock masses represented by the Panzhihua rockbody and basic-ultrabasic rock masses represented by the Hongge rockbody. Their major difference lies in that the former has poorly developed ultramafic facies, while the latter is characterized by well developed mafic facies and ultramafic facies. There exists apparent rhythmic stratification in the rock masses, which can be basically divided into four grades in terms of superimposition relationship and multicycle characters. Both direct and indirect evidence suggest that the magma responsible for the layered intrusions in this area should be a transition-type alkaline olivine basalt magma derived directly from partial melting of the upper mantle. In rhythmic cycles of various grades, the magmatic evolution is characterized obviously by periodicity and early enrichment of Fe and Ti, which is evidently different from the evolution of the Skaergaard magma in which Fe and Ti are enriched at the late stage. The FCA diagram can be used to describe the unique evolutionary trend of magma in this area. It is demonstrated in this diagram that the enrichment of Fe and Ti is consistent with the increase of basicity. In the upper magmatic chamber, the evolutionary trend of magma is conditioned by the difference in pressure, and this enables magma to form different types of rock assemblage. In the Fo-Di-An system, when the pressure exceeds 5 x 18⁸ Pa, forsterite is incompatible with anorthite, and the rock facies sequence of Hongge type might form; when the pressure is lower than 5 x 10⁸ Pa, forsterite can coexist with anorthite, and the rock facies sequence of Panzhihua type is likely to form if the magma is relatively rich in Mg and Fe components.     

岩浆-流体过渡和阿尔泰三号伟晶岩脉之成因

本文对新疆阿尔泰可可托海的三号伟晶岩形成的物理化学条件、特别是流体-熔融包裹体进行了研究，证明岩浆的确可以分出热液，对于三号伟晶岩脉来说，这种热液组分主要是NaCl－CO2－H2O流体。     

辽东中生代晚期和古近纪玄武岩及深源捕虏晶--对岩石圈地幔性质的制约

辽东地区玄武岩的K-Ar定年结果表明,曲家屯玄武岩形成于晚白垩世,K-Ar年龄为81．58±2．46Ma;乱石山子玄武岩形成于古近纪,K-Ar年龄为58．36±1．64Ma。本区玄武岩含有丰富的橄榄石、单斜辉石和角闪石捕虏晶。乱石山子玄武岩中橄榄石捕虏晶的Mg^#值（79．5-88．5之间,平均值为84）较曲家屯玄武岩中橄榄石捕虏晶Mg^#值（77．0～79．8之间,平均值为78．4）偏高;单斜辉石捕虏晶为透辉石,其从核部到边部的Mg^#等变化趋势与橄榄石类似;斜方辉石捕虏晶为占铜辉石,其Mg^#值介于85．2-87．6之间,平均值为86．4。捕虏晶发育的环状裂隙、扭折带、矿物成分环带以及捕虏晶与主岩Mg^#值之间的不平衡均暗示它们为玄武质岩浆上升捕获的早期岩浆晶出矿物的堆晶体。玄武岩的岩石地球化学分析结果表明：（1）它们属于碱性系列,为碱性玄武岩,曲家屯玄武岩较乱石山子玄武岩贫硅、镁,富钙、铝,它们均具有原始岩浆的特征;（2）二者具有相似的稀土元素配分模式,但曲家屯玄武岩轻稀土元素总量更高,且轻重稀土元素分离程度高;（3）二者具有相似的Sr-Nd同位素组成,Isr和εNd（t）值分别介于0．7039～0．7045和＋1．60～＋3．69,反映了亏损的岩石圈地幔特征。     

用自组织人工神经网络分类,识别矿物

作者运用三维Ｔ．Ｋｏｈｏｎｅｎ自组织人工神经网络对我国沉积碳酸盐型锰矿中菱锰矿进行分类、识别。所选研究实例中，识别成功率达１００％．结果表明，该网络性能良好，可望成为矿物识别的有效手段。     

内蒙古乌拉山地区沙德盖岩体年代学、地球化学特征及成因探讨

沙德盖岩体位于华北克拉通北缘中段、哈达门沟大型金（钼）矿田范围内。首次利用锆石 SHRIMP U-Pb法对其定年,获得15个锆石颗粒²⁰⁶Pb/²³⁸U年龄的加权平均值（221.6±2.1） Ma（MSWD=1.6）,表明岩体侵位于印支中期。岩石地球化学特征表现为高硅（SiO₂质量分数为71.21%～73.67%）、富钾（K₂O/Na₂O为1.01～1.37）、富碱（K₂O+Na₂O为8.23%～9.96%）、弱过铝质（Al₂O₃为13.11%～14.31%）,里特曼指数σ=2.43～3.52,钙碱性-碱性;富集轻稀土（LREE/HREE为17.68～14.92,（La/Yb）|_N为22.85～16.58）和Eu略亏损（δEu=0.95～0.93）;微量元素亏损Nb、Ta、P、Ti、Sr,富集K、La、Ce、Hf等元素,具有A型花岗岩特征;(⁸⁷Sr/⁸⁶Sr)i=0.705 31～0.702 29,(¹⁴³Nd/¹⁴⁴Nd)_i=0.511 682～0.511 620,ε_Nd(t)=-13.1～-14.3,具有壳源特点;钕两阶段模式年龄T_2DM=2 061～2 160 Ma,在铅构造模式图上样品投点于地幔与下地壳之间。综合分析认为其形成于同碰撞向后碰撞构造体制转换,伸展构造和幔源基性岩浆的底侵导致早期古老基底地壳部分熔融,很可能是形成沙德盖岩体的主要动力机制。华北克拉通北缘印支期构造岩浆活动及成矿作用是普遍存在的。     

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。     

西藏甲玛-卡军果推-滑覆构造系特征

通过矿区填图和路线调查,结合室内研究,指出:①甲玛-卡军果推-滑覆构造系由印度-欧亚板块碰撞引发,具有递进变形、自盆地中心向边部推覆、新盖老等特点,强变形于50Ma±。②推覆体下盘为叶巴组构造岩系;推覆体由上侏罗统和下白垩统碳酸盐-碎屑沉积岩系构成,主体为轴面北倾的复式褶皱,自南而北分为前部带、中部带和后部带。滑覆构造系推覆形成的复背斜轴部高位岩块失稳向北滑覆形成,自南而北分为后部带、中部带和前部带。③导致矿区蚀变的主要岩浆活动发生于推覆强变形后的松弛期,上侵受近南北向基底断裂和推覆断裂联合控制,就位受控于前部带推-滑覆褶断系,其后发生多次构造-岩浆-成矿液叠加,造就甲玛铜多金属矿床。