Impacts of temperature anomalies on mortality of benthic organisms in the Adriatic Sea

Recurrent climate‐induced mass mortality episodes have been recorded in the Mediterranean Sea over the past 15 years, affecting rocky benthic communities. In this study, we provide for the first time a report on the annual mortality events of benthic sessile invertebrates occurring in the eastern part of the Adriatic Sea. Over the course of 14 consecutive years, we studied the sea temperature gradient to a depth of 40 m and found an abnormal summer warming trend and an increased frequency of above‐average temperatures. Mortality events were recorded in the summers of 10 observed years, in particular in 2009, when the highest mortality rates were recorded. Late in summer 2009, extensive mass mortality of sessile invertebrates was observed in the entire Eastern Adriatic Sea. We performed an analysis of selected target benthic species associated with mass mortality events with inter‐regional differences in hydrological and temperature conditions. We were able to characterize the mortality event by studying five areas covering the northern, central and southern regions of the Eastern Adriatic Sea. The degree of impact on each study area was quantified at 28 sites by estimating the proportion of affected target species. According to the obtained data, the northern sites (Cres area) were the least affected, whereas sites in the Central and Southern Adriatic [Tela??ica and Lastovo Nature Parks, Mljet National Park (NP)] displayed the highest impact. In summer 2009, sea surface temperatures reached values of 28 °C in the Cres area and 30 °C in Mljet NP. These thermal conditions were concomitant with moderate to severe mass mortalities of benthic populations. Mass mortality events reached depths of 45 m in most parts of the affected areas. Amongst studied species, the scleractinian coral and gorgonian populations suffered the most extensive damage during the mass mortality events.     

Modeling compositional compressible two-phase flow in porous media by the concept of the global pressure

We derive a new formulation for the compositional compressible two-phase flow in porous media. We consider a liquid–gas system with two components: water and hydrogen. The formulation considers gravity, capillary effects, and diffusivity of each component. The main feature of this formulation is the introduction of the global pressure variable that partially decouples the system equations. To formulate the final system, and in order to avoid primary unknowns changing between one-phase and two-phase zones, a second persistent variable is introduced: the total hydrogen mass density. The derived system is written in terms of the global pressure and the total hydrogen mass density. The system is capable of modeling the flows in both one and two-phase zones with no changes of the primary unknowns. The mathematical structure is well defined: the system consists of two nonlinear parabolic equations, the global pressure equation, and the total hydrogen mass density equation. The derived formulation is fully equivalent to the original one. Numerical simulations show ability of this new formulation to model efficiently the phase appearance and disappearance.     

The influence of building materials on salt formation in rural environments

Blocks of limestone and sandstone used in walls of the Manasija Monastery complex showed damage caused by the efflorescence and subflorescence of different salts in a low-pollution rural environment. In addition to common salts such as thenardite, thermonatrite, trona and gypsum, a small amount of eugsterite and darapskite was also present. Although these sodium and sodium–calcium salts formed where cement mortar was used for repairs, the lithological type and chemical composition of the substrate also had an influence on the development of distinct salts. The interaction between limestone and sandstone (substrates) and a solution rich in sodium (without calcium) was successfully simulated in the laboratory. The presence of gypsum and sodium–calcium sulphate, as experimental products, solely on the limestones indicated that, in addition to the cement-mortar solution, part of the calcium required for the formation of calcium and double sodium–calcium salts could occur from this substrate.     

An analysis of the FIR/RADIO continuum correlation in the small Magellanic cloud

The local correlation between far-infrared (FIR) emission and radio-continuum (RC) emission for the Small Magellanic Cloud (SMC) is investigated over scales from 3 kpc to 0.01 kpc. Here, we report good FIR/RC correlation down to ～15 pc. The reciprocal slope of the FIR/RC emission correlation (RC/FIR) in the SMC is shown to be greatest in the most active star forming regions with a power law slope of ～1.14 indicating that the RC emission increases faster than the FIR emission. The slope of the other regions and the SMC are much flatter and in the range of 0.63–0.85. The slopes tend to follow the thermal fractions of the regions which range from 0.5 to 0.95. The thermal fraction of the RC emission alone can provide the expected FIR/RC correlation. The results are consistent with a common source for ultraviolet (UV) photons heating dust and Cosmic Ray electrons (CRe^?s) diffusing away from the star forming regions. Since the CRe^?s appear to escape the SMC so readily, the results here may not provide support for coupling between the local gas density and the magnetic field intensity.     

The 3-D model characteristics of a Cb cloud which moves along a valley

Summary The three-dimensional cloud-resolving mesoscale model is used to simulate an individual Cb cloud in condition of real orography. We have conducted our numerical experiments over an area known as hail bearing clouds source. Once formed such clouds regenerate and propagate along the valley if the shallow layer of strong wind shear exists. The orographic effects on model Cb cloud are recognized through comparison of simulated cloud characteristics with those calculated for the flat terrain. Sensitivity experiments with respect to the wind shear layer depth are also conducted.Our results demonstrate the model capability to simulate well some observational Cb cloud characteristics. It is shown that the river valley is of essential importance for Cb cloud development. The most prominent features of the model cloud in this case are as follows: fast propagation along the river valley; considerable depth of the cold air nose with pronounced pulsation mechanism and intense cell regeneration at the leading edge of cold air outflow. Model and observed radar reflectivities in the vertical cross-section are in agreement. Some characteristics of surface cumulative rain precipitation are also well reproduced by the model. In contrast with the real orography case, the model cloud is more intense and it propagates freely in lateral direction for the flat terrain. The cell regeneration associated with forced updraft above the cold air nose is not pronounced in contrast with earlier considerations. Reflectivity pattern near the ground, having mainly bat-like wings, encircles much larger area with altitude compared to the case of real orography. Finally, the model cloud characteristics depend strongly on shear layer.Received June 2002; revised August 22, 2002; accepted October 1, 2002 Published online: April 10, 2003     

Evaluating the transferability of monthly water balance models under changing climate conditions

ABSTRACT

Monthly water balance models (MWBMs) are often used for making flow projections under climate change. As such, these models should provide accurate flow simulations; however, they are seldom evaluated in this regard. This paper presents a comprehensive framework intended for the evaluation of the applicability of MWBMs under changing climatic conditions. The framework consists of analyses of consistency in model performance, parameter estimates and simulated water balance components, and a subjective assessment of model transferability. Four MWBMs – abcd, Budyko, GR2M and WASMOD – are used to simulate runoff in the Wimmera catchment affected by the Millennium drought. Although abcd and Budyko slightly outperformed GR2M and WASMOD, none of the models performed well in transfer to the driest period. The greatest variability is detected in simulated groundwater storage and baseflow; thus, these model components should be improved and/or enhanced calibration strategies should be employed to advance the transferability of MWBMs under changing climate.     

Photocatalytic Degradation of Dye C.I. Direct Blue 78 Using TiO2 Nanoparticles Immobilized on Recycled Wool‐Based Nonwoven Material

This paper discusses the possibility of immobilization of TiO₂ nanoparticles onto recycled wool‐based nonwoven material, which can be utilized for removal of dyes from wastewater. The photocatalytic activity of TiO₂ nanoparticles deposited on the nonwoven material was evaluated in the aqueous solution of direct dye C.I. Direct Blue 78 under the UV illumination. Nonwoven material modified with TiO₂ nanoparticles provides complete removal of dye from the solution already after 4–6 h of UV illumination. However, photodegradation of the dye adsorbed on the nonwoven material was obtained within 24 h of UV illumination. The rate of dye adsorption and photodegradation depends on the amount of deposited TiO₂ nanoparticles. The increase of initial dye concentration induced decrease in photocatalytic efficiency of immobilized TiO₂ nanoparticles. The highest photodegradation rate was achieved in acidic conditions. Elevated temperatures positively affected the removal of dye from solution. Photocatalytic activity of TiO₂ nanoparticles deposited on nonwoven material was preserved after three photodegradation cycles.     

Diagenesis of diatomite from the Kolubara Coal Basin,Baroševac,Serbia

Diatomite associated with the Kolubara Coal Basin was studied to better understand early stage silica diagenesis of shallow water deposits. The Kolubara Basin consists of Neogene siliciclastic rocks, diatomite, marlstone and rare carbonates. Palaeozoic metamorphic and Mesozoic sedimentary and igneous basement rocks are transgressively overlain by Upper Miocene sandstone, siltstone, shale and mudstone. This Upper Miocene section is transgressively overlain by the Pontian section, which contains diatomite and coal beds. White and grey diatomite forms beds 0.7-2.2 m thick that are continuous over an area of about 2 km². Siliceous rocks vary in composition from diatomite (81-89 per cent SiO₂) to diatom-bearing shale (58-60 per cent SiO₂). Siliceous deposits are laminated in places, with the laminae defined by variations in clay minerals, organic matter and diatoms. Diatomite shows only incipient diagenesis characterized by the fragmentation of diatom frustules, the minor to moderate corrosion of frustules and the formation of minor amounts of opal-A' (X-ray amorphous inorganic opal) cement. The low degree of diagenesis results from the young age of the deposits, low burial temperatures and possibly also from the presence of abundant organic matter and the dissolution of kaolinite. The presence of only weak diagenesis is also reflected by the characteristically poor consolidation of the rocks and low rank of the associated coal.