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111.
Robert Šajn Josip Halamić Zoran Peh Lidija Galović Jasminka Alijagić 《Journal of Geochemical Exploration》2011
The objectives of this study are as follows: (a) an assessment of the geochemical background signature of the Drava Valley before the industrial revolution; (b) an evaluation of anthropogenic geochemical influences on the alluvial plains and river terraces in the valley; and (c) a determination of the spatial distribution of trace elements in the alluvial soils of the Drava River downstream of the Austrian–Slovenian border to the confluence of Mura and Drava Rivers. 相似文献
112.
The geothermal waters of the first and the shallowest groundwater system of the Province of Vojvodina in northern Serbia, south part of the Pannonian Basin, are characterized by elevated temperatures (between 25 and 85 °C) and elevated gas content (above 1 Nm3/m3) with a high methane content (average about 94% of total gases). These methane-containing waters are particularly abundant in the Central part of the province between Danube and Tisa rivers. Dominant ions in these waters are sodium and bicarbonate, but the waters also contain significant amounts of calcium, magnesium, potassium, chloride, and ammonium. Components that are of balneological significance include iodine, bromine, fluorine, strontium, lithium, barium, and metasilicic and metaboric acids. Based on statistical analysis, a strong positive correlation is generally observed in about 9.2% cases. A slightly lower correlation appears in about 42.2%, and negative correlation coefficient appears in about 48.6% cases. The dendrogram of the cluster analysis built on the wells shows three main groups. There is the cluster of (Na+)aq, (Cl−)aq and (HCO3−)aq. The second aggregation is (NH4+)aq/(NH3)aq. The third group includes (Mg2+)aq, (Ca2+)aq, (Fe3+)aq, (Sr2+)aq, (Pb2+)aq, and (Zn2+)aq. 相似文献
113.
Stanislav Frančišković-Bilinski Mladen Juračić Darko Tibljaš 《Environmental Earth Sciences》2011,64(7):1755-1761
Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in
Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by
ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in
the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and
in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite
is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in
bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the
most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na,
B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with
sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments
in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the
restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic
matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the
Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples
at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was
also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta
correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below
toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as
a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically
introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles. 相似文献
114.
Dubravka Relić Dragana Đorđević Aleksandar Popović 《Environmental Earth Sciences》2011,63(6):1303-1317
We used elemental carbon, nitrogen, hydrogen and sulfur as well as ratios of hydrogen and nitrogen with total organic carbon
for investigation of source and conditions of organic matter in alluvial Danube sediments. We also determined the pseudo total
concentrations of metals presented as a sum of extracted concentration after five sequential extraction steps. The pseudo
total metal concentrations were found to be (mg kg−1) for Mn, 666; Fe, 25,852; Mg, 16,193; K, 2,063; Ni, 32.4; Zn, 72.2; Pb, 15.0; Cu, 26.0 and for Cr, 15.9. Correlation analysis
and two multivariate analysis methods (principal component and cluster analysis) were helpful in determining the associations
between the pseudo total extracted fractions of metals and with elemental carbon, hydrogen, nitrogen, sulfur, total inorganic
and organic carbon. These correlations will help us to identify substrates of trace metals in different oxic/anoxic conditions.
The correlation results of the trace metals and Fe, K, Mg and Mn suggest their adsorption, mainly onto Fe and Mn (hydro)oxides
and K alumosilicates, whereas correlations of metals with sulfur indicate that they were precipitated as Fe-sulfides. 相似文献
115.
John Davenport Daria Ezgeta-Balić Melita Peharda Sanda Skejić Živana Ninčević-Gladan Slavica Matijević 《Estuarine, Coastal and Shelf Science》2011
The endangered fan shell Pinna nobilis is a large bivalve mollusc (<120 cm shell length) endemic to the Mediterranean that lives one-third buried in soft substrata, generally in shallow coastal waters. We hypothesised that P. nobilis of different sizes would ingest different food sources, because small fan shells will inhale material from closer to the substratum than do large fan shells. We studied stomach contents and faeces of 18 fan shells, 6 small (mean 23.0 cm length), 6 medium-sized (mean 41.5 cm length) and 6 large (mean 62.7 cm length) living in a small area of a low-energy coastal detritic bottom characterised by mud, sand and macroalgae at Mali Ston Bay, Croatia. We found that all P. nobilis ingested copious quantities of undetermined detritus (probably at least 95% of ingested material), phytoplankton, micro and mesozooplankton and pollen grains. Large P. nobilis stomach contents showed a preponderance of water column calanoid copepods, while small fan shells had higher numbers of bivalve larvae. All fan shells took in high numbers of harpacticoid copepods that are benthonic, feeding on microbial communities of detritus and benthic vegetation. There was also a significant selection of phytoplankton species, some apparently occurring between inhalation and ingestion. The stomach contents of small P. nobilis had a higher organic matter content than either medium-sized or large fan shells; this indicated that small fan shells ingested detritus of higher organic content than did larger P. nobilis. As the faeces of all P. nobilis had similar organic matter content, this also indicates higher assimilation efficiencies in small fan shells. The demonstration of differential dietary selectivity by different sized animals has implications for future trophic studies of this endangered species. This study also provides the first demonstration of predation on zooplankton by P. nobilis. 相似文献
116.
Kirsten Linnow Michael Steiger Christine Lemster Hilde De Clercq Maja Jovanović 《Environmental Earth Sciences》2013,69(5):1609-1620
Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO3–Na2SO4 system including the formation of the double salt darapskite, Na3NO3SO4·H2O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na2SO4(III), Na2SO4(V) and darapskite. The experimental observations are discussed on the basis of the NaNO3–Na2SO4–H2O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures. 相似文献
117.
Nenad Tomašić Štefica Kampić Iva Juranović Cindrić Kristina Pikelj Mavro Lučić Danijela Mavrić Tajana Vučetić 《Central European Journal of Geosciences》2013,5(4):457-464
The adsorption properties in terms of cation exchange capacity and their relation to the soil and sediment constituents (clay minerals, Fe-, Mn-, and Al-oxyhydroxides, organic matter) were investigated in loess, soil-loess transition zone, and soil at four loess-soil sections in North-Western Croatia. Cation exchange capacity of the bulk samples, the samples after oxalate extraction of Fe, Mn and Al, and after removal of organic matter, as well as of the separated clay fraction, was determined using copper ethylenediamine. Cation exchange capacity (pH~7) of the bulk samples ranges from 5 to 12 cmol c /kg in soil, from 7 to 15 cmol c /kg in the soil-loess transition zone, and from 12 to 20 cmol c /kg in loess. Generally, CEC values increase with depth. Oxalate extraction of Fe, Mn, and Al, and removal of organic matter cause a CEC decrease of 3–38% and 8–55%, respectively, proving a considerable influence of these constituents to the bulk CEC values. In the separated clay fraction (<2 μm) CEC values are up to several times higher relative to those in the bulk samples. The measured CEC values of the bulk samples generally correspond to the clay mineral content identified. Also, a slight increase in muscovite/illite content with depth and the vermiculite occurrence in the loess horizon are concomitant with the CEC increase in deeper horizons, irrespective of the sample pretreatment. 相似文献
118.
The paper presents the testing of the possibility of determining the heights of GPS points in the homogeneous field in the
new Croatian Height Reference System (HVRS71) by using the method of height transformation. The testing was made in the area
of Zagreb. As part of the field works, normal orthometric heights of 27 GPS points were determined according to the new height
system, by transferring the benchmark heights using the geometric levelling method, thus obtaining GPS/levelling points of
known ellipsoidal and normal orthometric heights. The GPS/levelling points served as the basis for determining the transformation
models that enabled the computation of normal orthometric heights from ellipsoidal heights of any GPS point in the observed
area. The empirical data used for modelling were reduced undulation dN values of GPS/levelling points. As part of the dN modelling
with parametric functions, the approximation surfaces were obtained on the basis of three polynomials: FN310, FN312 and FN318.
The transformation models were also tested using non-parametric Watson and Loess algorithms. The FN318 and Loess models yielded
the best results. 相似文献
119.
The paper describes a finding of photoautotroph cyanobacteria Synechococcus in deep Adriatic waters during the spring of 2006. The maximum abundance in early May was positioned at 800 m, being of order
of the values referred for the surface waters in the Adriatic Sea. The deep abundance maximum has been associated to the fast
ventilation of deep Adriatic waters, usually occurring during wintertime strong cooling events. Two processes were detected:
(1) deep convection in the South Adriatic Pit (SAP) and (2) density current going downslope. The first process was responsible
for bringing the cyanobacteria down to 600-m depth in the area of convection, and the second one triggered the downslope transport
of the cyanobacteria to the SAP very bottom. The depletion rate of Synechoccocus cyanobacteria in an extremely hostile environment has been computed to equal about 1 month. 相似文献
120.