Accurate U-Pb Age and Trace Element Determinations of Zircon by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry

Various zircons of Proterozoic to Oligocene ages (1060-31 Ma) were analysed by laser ablation-inductively coupled plasma-mass spectrometry. Calibration was performed using Harvard reference zircon 91500 or Australian National University reference zircon TEMORA 1 as external calibrant. The results agree with those obtained by SIMS within 2s error. Twenty-four trace and rare earth elements (P, Ti, Cr, Y, Nb, fourteen REE, Hf, Ta, Pb, Th and U) were analysed on four fragments of zircon 91500. NIST SRM 610 was used as the reference material and ²⁹Si was used as internal calibrant. Based on determinations of four fragments, this zircon shows significant intra-and inter-fragment variations in the range from 10% to 85% on a scale of 120 μm, with the variation of REE concentrations up to 38.7%, although the chondrite-normalised REE distributions are very similar. In contrast, the determined age values for zircon 91500 agree with TIMS data and are homogeneous within 8.7 Ma (2 s ). A two-stage ablation strategy was developed for optimising U-Pb age determinations with satisfactory trace element and REE results. The first cycle of ablation was used to collect data for age determination only, which was followed by continuous ablation on the same spot to determine REE and trace element concentrations. Based on this procedure, it was possible to measure zircon ages as low as 30.37 0.39 Ma (MSWD = 1.4; 2 s ). Other examples for older zircons are also given.     

Crustal structure of the southern Dabie ultrahigh-pressure orogen and Yangtze foreland from deep seismic reflection profiling

A new 140‐km‐long seismic reflection profile provides a high‐resolution crustal‐scale image of the southern Dabieshan high‐pressure (HP) metamorphic belt and the Yangtze foreland fold‐and‐thrust belt. The seismic image of the stacked section shows that the southern Dabieshan metamorphic terrane and Yangtze foreland belt are separated by a large north‐dipping fault. In the foreland the upper crust is dominated by a series of folds and thrusts formed during the collisional stage in the mid‐Triassic; it was reworked by crustal extension resulting in the formation of a late Jurassic and Cretaceous red‐bed basin. The southern Dabieshan profile shows stacked crustal slabs developed along the margin of the collisional orogenic belt. The Moho reflectors at 10–11 s (～30–33 km) are seismically prominent and segmented by a number of south‐verging thrusts that were probably developed by foreland‐directed thrusting of the deeply subducted continental crust during exhumation. The seismic reflection profile suggests that structures related to the Triassic–Jurassic subduction and exhumation of the Yangtze plate are preserved despite the severe crustal extension superimposed during the late Mesozoic and Cenozoic.     

Simulations of a coupled hydro-chemo-mechanical system in rocks

A coupled hydro-chemo-mechanical numerical model is developed for these coupled phenomena in many engineering fields. The model has been applied to predicting the response of a stressed rockmass column to an injected reactive fluid (reagent) flow. The response includes evolutions of porosity, permeability, reagent and mineral concentrations during dissolution. In the model, the progress of dissolution is defined by the change in porosity ratio and the porosity increases with dissolution assuming there is no precipitation. The numerical evolutions of porosity, permeability, reagent and mineral concentrations during dissolution are validated against steady state solutions. The model results show that these evolutions are regulated to a certain extent by the applied external loadings: an applied extensional stress enhances the progress of the dissolution process while an applied compression stress slows the progress of the dissolution process. This revised version was published online in July 2006 with corrections to the Cover Date.     

Pressure State in Deep Crust and Formation Depth of UHP Metamorphic Rocks

INTRODUCTIONSincethediscoveryofeclogiteswithcoesiteanddia mondinclusionsrelatedtothecontinent continentcollision orogenyenvironment,theultrahigh pressuremetamorphism(UHPM )intheDabie Suluhasarousedgreatinterestinmanygeologists (Liouetal .,1994 ;Xuetal.,1992 ) .Experimentalstudieshaveprovedthatsuchmineralsasdia mond ,coesiteandomphaciteoccurredat 2 - 5GPa (andatthecorrespondingtemperatures) (Stevenetal.,1982 ;MirwaldandMasonne ,1980 ) .However,itdoesnotmeanthatthemetamorphicrockscanbe…     

Cenozoic rifting and volcanism in eastern China: a mantle dynamic link to the Indo–Asian collision?

The Indo–Asian continental collision is known to have had a great impact on crustal deformation in south-central Asia, but its effects on the sublithospheric mantle remain uncertain. Studies of seismic anisotropy and volcanism have suggested that the collision may have driven significant lateral mantle flow under the Asian continent, similar to the observed lateral extrusion of Asian crustal blocks. Here we present supporting evidence from P-wave travel time seismic tomography and numerical modeling. The tomography shows continuous low-velocity asthenospheric mantle structures extending from the Tibetan plateau to eastern China, consistent with the notion of a collision-driven lateral mantle extrusion. Numerical simulations suggest that, at the presence of a low-viscosity asthenosphere, continued mass injection under the Indo–Asian collision zone over the past 50 My could have driven significant lateral extrusion of the asthenospheric mantle, leading to diffuse asthenospheric upwelling, rifting, and widespread Cenozoic volcanism in eastern China.     

The influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes in pyrolysates of selected terrestrial kerogens

Expulsion of petroleum from source rock is a complex part of the entire migration process. There exist fractional effects on chemical compositions in hydrocarbon expulsion. Does the carbon isotopic fractionation occur during expulsion and to what extent? Here the influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes from pyrolysates of selected terrestrial kerogens from Tuha basin and Fushun, Liaoning Province of China has been experimentally studied. The pyrogeneration-expulsion experiments were carried out under semi-closed system. The carbon isotopic compositions of individual n-alkanes were measured by GC-IRMS. The main conclusions are as follows. First, there is carbon isotopic fractionation associated with hydrocarbon expulsion from Type III kerogens in Tuha Basin. There exist differences of carbon isotopic compositions between the unexpelled n-alkanes and expelled n-alkanes from Tuha desmocollinite and Tuha mudstone. Second, there is almost no carbon isotopic fractionation associated with hydrocarbon expulsion from Type II kerogens in Fushun and Liaohe Basin. Third, carbon isotopic fractionation in hydrocarbon expulsion should be considered in making oil-source correlation of Type III kerogens at least in the Tuha Basin. Further studies need to be carried out to determine whether this is true in other basins. Fourth, oil and source at different maturity levels cannot be correlated directly for Type III kerogens since the carbon isotopic compositions of expelled hydrocarbons at different temperatures are different. The expelled hydrocarbons are usually lighter (depleted in ¹³C) than the hydrocarbons remaining in the source rock at the same maturity.     

基于等高线的DEM生成算法研究和实现

数字高程模型是近年来发展起来的为地理信息系统提供空间分析和辅助决策的数据基础。随着科学技术特别是计算机技术的迅速发展，DEM在数据获取方法、数据存储和数据处理速度等方面已经取得突破性进展。通过系统介绍生成DTM过程中等高线的离散化方法，DELAUNAY三角网的特性和基于等高线数据的TIN的建立，以及对产生的问题的一些解决方法。     

探索地理信息智能化处理技术

GIS自产生至今30多年来，世界各国都竞相开展GIS技术研究和应用开发，使其得到了迅速的发展，已形成较为完整的理论体系和大批实用系统，并已在社会各专业领域得到广泛应用并产生了巨大效益，目前，开始朝着产业化、集成化、智能化和社会化的方向发展。随着3S技术的集成应用，人们对GIS的运行效率及其深入的应用提出了更高的要求，地理信息智能化处理已成为地图学和GIS建设必须解决的问题，也是GIS发展的必然方向。在地理信息处理中采用人工智能技术，发展智能GIS或者专家GIS，是解决复杂地学问题的重要途径，也是目前GIS最吸引人的一个应用方向。目前在地理信息处理的许多领域都在使用人工智能技术，比如地图模式识别、地理数据的自动分类、地学专家系统、智能GIS、空间数据挖掘等。本文通过对当前地理信息智能化处理技术发展现状的阐述，旨在探索人工智能在地理信息处理中的应用前景。