Paleoenvironmental implications of the guano phosphatic cementation on Dongdao Island in the South China Sea

The phosphatic cement in the bioclastic sediment sequence on the northeastern shore of Dongdao Island in the South China Sea was studied and its paleoenvironmental implications discussed. Petrological characteristics and major, trace, REE element data unequivocally supported the notion that phosphatization was closely associated with avian guano decomposition and leaching, whereas carbon and oxygen isotope results further revealed that meteoric water were involved in these processes. AMS ¹⁴C dates on the brown phosphate cements indicate that they were formed around 5700, 5000–5100 and 2900 yr BP, respectively. The multi-episodes of phosphatization very likely correspond to intermittent seabird occupation on this island — possibly reflecting Holocene sea-level oscillation and/or long term climate changes in the South China Sea that have controlled seabird habitat. The phosphate cementation, which occurs widely in tropical islands, may be another useful monitor for sea-level and/or paleoclimate changes.     

Ballasting outside port to prevent spread of butyltin from merchant ships

Most international discussions on ballast water management onboard ships have been virtually on the prevention of the transport of biotic alien species. This study focuses on how to improve this limited knowledge regarding the transport of butyltin compounds via ballasting. Butyltin compounds in ballast water, extracted from three sea-going merchant ships with similar voyage routes and berth ports but with different ballasting practices, were determined. Only monobutyltin (8–57 ng l^?1) and dibutyltin (10–32 ng l^?1) onboard two general cargo ships were detected in the ballast water taken outside the ports. In contrast, significant tributyltin (23–93 ng l^?1) was detected onboard the container ship in the ballast water pumped inside the loading/unloading ports. The comparison results from this study indicate that the risk of tributyltin transfer may be effectively prevented by ballasting outside the ports.     

Evidence for the 8,200 a <Emphasis Type="SmallCaps">b</Emphasis>.<Emphasis Type="SmallCaps">p</Emphasis>. cooling event in the middle Okinawa Trough

Based on new and existing data on oxygen isotopes, alkenone-surface seawater temperature trends, planktonic foraminifers, lithology, and clay mineral composition of piston cores, a distinct cooling event has been identified around 8,200 cal a b.p. in the middle Okinawa Trough, northwest Pacific. This corresponds to the 8,200 a b.p. cooling event recorded in many places of the Northern Hemisphere. During this event, the local temperature decreased by 1°C, and the δ¹⁸O value increased by 0.6‰. A strengthened Asian winter monsoon is the most probable cause for this event, which thus adds further credibility to the contention that we are dealing here with a global phenomenon.     

Geochemistry of pore waters from the Xisha Trough, northern South China Sea and their implications for gas hydrates

This paper reports all available geochemical data on sediments and pore waters from the Xisha Trough on the northern continental margin of the South China Sea. The methane concentrations in marine sediments display a downhole increasing trend and their carbon isotopic compositions (δ ¹³C = −25 to −51‰) indicate a thermogenic origin. Pore water Cl⁻ concentrations show a range from 537 to 730 mM, and the high Cl⁻ samples also have higher concentrations of Br⁻, Na⁺, K⁺, and Mg²⁺, implying mixing between normal seawater and brine in the basin. The SO₄ ²⁻ concentrations of pore waters vary from 19.9 to 36.8 mM, and show a downhole decreasing trend. Calculated SMI (sulfate-methane interfaces) depths and sulfate gradients are between 21 and 47 mbsf, and between −0.7 and −1.7 mM/m, respectively, which are similar to values in gas hydrate locations worldwide and suggest a high methane flux in the basin. Overall, the geochemical data, together with geological and geophysical evidence, such as the high sedimentation rates, high organic carbon contents, thick sediment piles, salt and mud diapirs, active faulting, abundant thermogenic gases, and occurrence of huge bottom simulating reflector (BSR), are suggestive of a favorable condition for occurrence of gas hydrates in this region.     

Method for evaluating the degrees of land use sustainability of mountainous county and its application in Yunnan Province,China

The evaluation of sustainable land use is the key issue in the field of studying the sustainable land utilization. In general analysis, the sustainable land use is evaluated respectively from its ecological sustainability, economic sustainability and social sustainability in China and other countries in recent years. Although this evaluation is an important work, it seems insufficient and hard to comprehensively reflect the whole degree of land use sustainability. Thus, to make up this deficiency, this paper brings forward the evaluation indexes, which make it possible to quantitatively reflect the whole degree of land use sustainability, namely, the concept of ＂degrees of overall land use sustainability＂ （Dos）, and research and measurement development of the method of and calculation in Dos. Taking the evaluation of the degree of land use sustainability in county regions of Yunnan Province as the actual example for analysis, results are basically as follows：
1） The degree of land use sustainability （Dos） is the ration index to organically and systematically integrate the degree of ecological friendliness （DeF）, the degree of economic viability （Dev） and the degree of social acceptability （Dsa）, able to comprehensively reflect the whole sustainability degree of regional land use
2） Based on the value of Dos, the grading system and standard for the sustainability of land use may be established and totally divided into five grades, namely, the high-degree sustainability, middle-degree sustainability, low-degree sustainability, conditional sustainability and non-sustainability. Meanwhile, the standard for distinguishing sustainability grades has also been confirmed so as to determine the nature of sustainability degrees in different grades. This makes the possibility for the combination of nature determination with ration in research result and provides with the scientific guideline and decision-making gist for better implementation of sustainable land use strategy.
3） The pract     

Preliminary comparison of trace metals in coastal aerosols between Qingdao and Liverpool

Aerosol samples were collected at two coastal suburban stations, Qingdao （China） in 1995-1996 and Liverpool （U.K.） in 1995, respectively. The samples were analyzed to determine the concentrations of trace metals （Cr, Zn, Cu, Co, Ni, Pb, V, and Cd） as well as A1, Fe and Mn. Data were examined to understand the difference of trace metals in aerosols between coastal zones downwind the developing area （near the Yellow Sea） and developed region （near the Irish Sea）. The results show that most elements at Qingdao have levels 4-5 times higher than those at Liverpool, particularly for the crust-dominated elements （e.g. Al, Fe and Mn）. Moreover, the aerosol composition at Qingdao is higher in spring than in summer, underlying the influence of westerlies and local emissions in combination, whereas seasonal change of aerosol composition is not significant at Liverpool. The enrichment factors for the crustal source elements （EFcrust） at Liverpool are much higher than those at Qingdao. The contributions from the pollutant source （Rp） for some trace metals like Cu, Pb, Zn and Cd are 〉90% at Qingdao and Liverpool, suggesting overwhelming anthropogenic contributions to these metals. The contributions from crustal source （Re） for trace metals tend to increase with higher aerosol levels and Al concentration at Qingdao, indicating a good correlation between the crust-dominated component and the air mass. At Liverpool, the Rc values for trace metals are positively correlated with Al concentrations instead of with aerosol mass, suggesting that Al in aerosols represents the crustal component even though the aerosols come from different sources.     

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