Hydrocarbon Generating Potential of Mineral—Bituminous Matrix in Source Rocks

Mineral-bituminous matrix(MBM) makes up a major part of source rocks,but its potential in hydrocarbon generation is uncertain,Mineral and organic (Maceral and kerogen) compositions,organic maturity and fluorescence of MBM are studied based on source rock samples from eastern Jiuquan(Jiudong)Basin.The results show that MBM is dominated by inorganic minerals and among the small percentage of organic components those of secondary origins are predominant over the primary species.This strongly indicates that the significance of MBM in hydrocarbon generation is limited.     

A multi-equation spatial econometric model,with application to EU manufacturing productivity growth

A multi-equation spatial econometric model is used to explain variations across EU regions in manufacturing productivity growth based on recent theoretical developments in urban economics and economic geography. The paper shows that temporal and spatial parameter homogeneity is an unrealistic assumption, contrary to what is typically assumed in the literature. Constraints are imposed on parameters across time periods and between core and peripheral regions of the EU, with the significant loss of fit providing overwhelming evidence of parameter heterogeneity, although the final model does highlight increasing returns to scale, which is a central feature of contemporary theory.      

Assessing landslide movements in volcanic islands using near-shore marine geophysical data: south Pico island,Azores

Marine geophysical data from around the submarine flanks of volcanic islands can potentially help to resolve whether large-scale instability of an edifice has been geologically recently active. We use geophysical data to investigate part of the coast of Pico Island of the Azores where, above sea-level, a major slump of Topo volcano has been interpreted previously from arcuate escarpments and a rugged irregular topography seaward of them. Multibeam echo-sounder data collected offshore of this feature show remarkably little evidence for slump fault movements in the island's submarine slope. Mid-slope benches, like those associated with the Hilina Slump of Kilauea, are absent. The high-resolution data extends onto the island's shelf, allowing us to evaluate evidence for continuing activity there. In particular, as the shelf's rock platform will have been last modified by surf erosion during the postglacial period of sea-level transgression, it provides a reference surface of intermediate age (7–19 ka) that can potentially reveal whether any movements occurred in pre-historic times. Where the arcuate escarpments are continued offshore, the modern seabed shows no bathymetric evidence for active faults where the shelf rock platform crops out in the multibeam data. Elsewhere, mobile shelf sediments could be disguising evidence for active faulting so we examined boomer profiles able to image the rock platform beneath them. The data reveal a platform that is steep (6.6°) compared with the dips of platforms that we have studied previously around the coast of adjacent Faial Island and steeper than the platform outside the proposed slump. This suggests that it was created by coastal erosion over a shorter period and hence is consistent with a younger age of the coastline. As with the multibeam data, where escarpments are continued offshore onto the shelf, the rock surface imaged with these boomer data also shows no clear evidence of major slump-related fault displacements. This study therefore illustrates how high-resolution boomer seismic and multibeam data could usefully contribute to hazard assessment of volcanic islands, by helping to evaluate areas with no historical movements. Explanations to reconcile the onshore and offshore data here are also put forward.     

准噶尔盆地沙湾凹陷二叠系凝析气藏相态识别及成因分析

近年来,我国中西部陆续发现了资源量较大的凝析气藏,准噶尔盆地沙湾凹陷周缘的多个凝析气藏也显示出深层勘探的潜力。针对沙湾凹陷凝析气藏的烃类流体特征和形成机制不清晰的科学问题,笔者等采用原油物性和地球化学分析测试,运用经验统计法来识别油气藏类型,分析油气相态特征及其来源。主要认识如下：① 沙湾凹陷二叠系主要存在带油环凝析气藏,中佳2- H井为典型带油环凝析气藏井,研究区存在风城组为烃源—断层垂向输导—温压控制的原生型和天然气气侵共同作用形成的次生型凝析气藏;② 结合P—V—T相图分析沙湾凹陷二叠系凝析气藏烃类流体C7+占比较小,挥发性油藏地层温度明显低于临界温度,地饱压差较小,黑油油藏地层流体的临界温度与临界凝析温度都较高且临界压力较小;③ 根据新光井区凝析气藏的气油比要高于13000 m3/m3,且新光1井凝析气藏属于无油环凝析气藏可判断新光1井为原生型凝析气藏;中佳2- H井凝析气藏正构烷烃损失率达到90%,且研究区存在混合来源气,证实该凝析气藏曾遭受气侵作用。笔者等提出的凝析气成因可为研究区下一步油气勘探提供参考,同时也可以为准噶尔盆地凝析气成藏的研究和资源评价提供方法支持。     

Coastal sea level variability in the US West Coast Ocean Forecast System (WCOFS)

Sea level variability along the US West Coast is analyzed using multi-year time series records from tide gauges and a high-resolution regional ocean model, the base of the West Coast Ocean Forecast System (WCOFS). One of the metrics utilized is the frequency of occurrences when model prediction is within 0.15 m from the observed sea level, F. A target level of F?=?90% is set by an operational agency. A combination of the tidal sea level from a shallow water inverse model, inverted barometer (IB) term computed using surface air pressure from a mesoscale atmospheric model, and low-pass filtered sea level from WCOFS representing the effect of coastal ocean dynamics (DYN) provides the most straightforward approach to reaching levels F>80%. The IB and DYN components each add between 5 and 15% to F. Given the importance of the DYN term bringing F closer to the operational requirement and its role as an indicator of the coastal ocean processes on scales from days to interannual, additional verification of the WCOFS subtidal sea level is provided in terms of the model-data correlation, standard deviation of the band-pass filtered (2–60 days) time series, the annual cycle amplitude, and alongshore sea level coherence in the range of 5–120-day periods. Model-data correlation in sea level increases from south to north along the US coast. The rms amplitude of model sea level variability in the 2–60-day band and its annual amplitude are weaker than observed north of 42 N, in the Pacific Northwest (PNW) coast region. The alongshore coherence amplitude and phase patterns are similar in the model and observations. Availability of the multi-year model solution allows computation and analysis of spatial maps of the coherence amplitude. For a reference location in the Southern California Bight, relatively short-period sea level motions (near 10 days) are incoherent with those north of the Santa Barbara Channel (in part, due to coastal trapped wave scattering and/or dissipation). At a range of periods around 60 days, the coastal sea level in Southern California is coherent with the sea surface height (SSH) variability over the shelf break in Oregon, Washington, and British Columbia, more than with the coastal SSH at the same latitudes.     

Gamma-ray bursts: optical afterglows in the deep Newtonian phase

Gamma-ray burst remnants become trans-relativistic typically in days to tens of days, and they enter the deep Newtonian phase in tens of days to months, during which the majority of shock-accelerated electrons will no longer be highly relativistic. However, a small portion of electrons are still accelerated to ultra-relativistic speeds and are capable of emitting synchrotron radiation. The distribution function for electrons is re-derived here so that synchrotron emission from these relativistic electrons can be calculated. Based on the revised model, optical afterglows from both isotropic fireballs and highly collimated jets are studied numerically, and compared to analytical results. In the beamed cases, it is found that, in addition to the steepening due to the edge effect and the lateral expansion effect, the light curves are universally characterized by a flattening during the deep Newtonian phase.     

The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

An analysis of climatic and human induced determinants of agricultural land use changes in Shupiyan area of Jammu and Kashmir state,India

The economy of the Jammu and Kashmir state depends mostly on traditional forms of occupation. Unaffected and unaltered by modern day industrial developments and changing times, the indigenous traditional occupations of farming, animal husbandry and horticulture forms the backbone of the state economy. But in the last few decades, Agriculture in the state as well as the study area is receiving a set back and Horticulture is flourishing leaps and bounds. The present study aims to analyze various determinants responsible for this change. Climatic as well as field data was thoroughly analyzed to comprehend the situation. A Mann–Kendall test was done on the climatic data to support the hypotheses. It was observed that initially changing climatic trends proved to be the triggering factor supporting this change, but in due course of time, the determinants took an economic and psychological turn. The perusal of Indian Meteorological Data reveals an increasing trend of annual mean maximum temperature from 16.78 °C in 1985 to 17.58 °C in 1995 and an increase from 5.30 °C to 7.00 °C in the annual mean minimum temperature, and as such acting as a triggering factor for the land use conversion. Further, the mean annual rainfall shows a decrease from 100.75 mm in 1981 to 79.43 mm in 1991. The greater economic returns from horticulture as well as the changing behavioral patterns of people over the time further cemented its growth. The farmers have since persisted with the horticulture activity as it has proven to be an economically a much better lucrative enterprise.     

Electrical and electromagnetic surveys to locate possible causes of water seepage to ground surface at a quarry open pit near Helwan city,Egypt

Water seepage to ground surface at a limestone quarry located at Wadi Garawy about 20 km south-east of Helwan city in Egypt posed a real threat to the mining activity at the quarry. The quarry area is known to be very dry for decades and away from water utilities and infrastructures that may cause water leaks to the quarry. Geophysical investigation including 1D Vertical Electrical Sounding (VES), 2D Electrical Resistivity Tomography (ERT) and 1D Transient Electromagnetic (TEM) surveys were conducted to characterize the rock sequence and locate what could be a possible source of water seepage to the quarry. The resistivity profiles generated from the VES and TEM surveys mapped the rock units in the area down to depths exceeded 100 m. The ERT profiles acquired from the quarrying zone close to the water seepage spot have imaged the top of groundwater level at few meters below the ground surface at the quarry open pit. The spot of groundwater seepage seemed to occur at an area of limestone dissolution that were filled by finer sediments. The finer sediments acted as a hydrological conduit that allowed an upward seepage of groundwater to ground surface under the capillary action effect.     

Uncertainty as the overlap of alternate conditional distributions

An important task in modern geostatistics is the assessment and quantification of resource and reserve uncertainty. This uncertainty is valuable support information for many management decisions. Uncertainty at specific locations and uncertainty in the global resource is of interest. There are many different methods to build models of uncertainty, including Kriging, Cokriging, and Inverse Distance. Each method leads to different results. A method is proposed to combine local uncertainties predicted by different models to obtain a combined measure of uncertainty that combines good features of each alternative. The new estimator is the overlap of alternate conditional distributions.