Experimental investigation of hydrate formation in water-dominated pipeline and its influential factors

Blockage in water-dominated flow pipelines due to hydrate reformation has been suggested as a potential safety issue during the hydrate production. In this work, flow velocity-dependent hydrate formation features are investigated in a fluid circulation system with a total length of 39 m. A 9-m section pipe is transparent consisted of two complete rectangular loops. By means of pressurization with gas-saturated water, the system can gradually reach the equilibrium conditions. The result shows tha...     

2000—2015年中国高学历人才分布格局及其影响机制

基于2000年、2010年中国人口普查分地级及以上行政区数据和2015年中国各省份1%人口抽样调查数据,采用变异系数、泰尔系数、基尼系数测度中国高学历人才比重分布的空间不均衡程度,并采用面板数据Tobit随机效应模型,识别影响高学历人才比重空间分布的主要因素。结果表明:①中国的人才比重分布表现出极大的不均衡性,人才比重的高低与城市等级密切相关,主要表现在直辖市、省会城市、计划单列市等行政区吸引了大量人才,而普通地级城市人才比重相对较低;②10 a间人才比重的变异系数、基尼指数和泰尔指数均有所下降,表明人才比重分布的空间不均衡程度有所下降;③平均工资水平、生活成本、城市等级、每万人高校在校学生数、每万人医院卫生院床位数、人均科学事业、教育事业经费与人才比重呈正相关,中学生师比、万人互联网用户数与人才比重呈负相关,失业率、单位面积二氧化硫排放量、绿地率对人才比重没有影响。     

城市“腾笼换鸟”产业转型升级的困境与出路——基于北京市的调查研究

剖析北京"腾笼换鸟"产业转型升级的现状,在针对"新鸟"进笼"老鸟"去哪问题",老笼"空间结构合理优化问题",老鸟"涅槃"新鸟"培育问题",老鸟"和"新笼"承接问题的分析基础上,提出应完善京津冀产业链协作",腾笼换鸟"拓展区域联动发展空间;东西城合并成首都特区",腾笼换鸟"保护北京历史文化名城;切实发挥政府的职能作用",腾笼换鸟"提升企业内在动力机制;规划建设"微中心"小城镇",腾笼换鸟"促进北京人口有效疏解的建议。     

基于网络游记的城市旅游流网络结构演化研究——以北京市为例

采用网络游记文本数据,结合爬虫技术和社会网络分析方法,分析北京市"十二五"和"十三五"时期城市旅游客流网络结构的演变特征。结果表明:①城市旅游流网络结构存在不均衡性,城市历史文化遗产节点的的影响控制能力强,新兴旅游吸引物的集聚能力相对较弱,受不同类型节点的路径依赖效应的影响,这种差异存在动态扩大特征。②城市旅游流网络结构呈现显著的等级分层结构和节点分散分布特征,传统游憩场所是城市旅游流的核心节点,外围发育的旅游节点较分散且规模能级提升空间较大。③城市旅游流拥有显著的赋能效应、倒逼效应和联通效应。     

长江经济带开发区空间分布与产业集聚特征研究

采用最近邻指数、Ripley’s L函数、核密度估计等方法分析长江经济带开发区的空间分布与产业集聚特征,结果表明:①长江经济带开发区总体上呈东密西疏、东强西弱、东中西段分异的显著集聚分布特征;②基于主导产业划分的各类开发区在空间上均为集聚分布,集聚强度和规模随距离的增加基本都呈"先增加后减小"的规律,集聚形态各异,主要有"单核心""双核心""多核心"3种;③长江经济带东段地区主要以装备制造、通信电子、汽车制造、新材料、生物医药等资本技术密集型产业集聚为主,中、西段地区则集聚了化学工业、金属加工、食品制造、纺织服装等资本与劳动密集型产业。要加强经济带上中下游开发区之间的多维良性互动,注重绿色发展、创新发展与结构优化,进一步提升其对长江经济带高质量发展的引领与支撑作用。     

磁铁矿的穆斯堡尔谱研究

我们对大冶、马坑、大顶、黄沙坪、鞍山五个矿区的七个铁矿石样品中的磁铁矿作了室温~(57)Fe和~(119)Sn穆斯堡尔谱测定,并根据穆斯堡尔数据和化学分析推算出磁铁矿的非理想配比的分子结构式. 初步研究表明,不同的成矿条件和Zn、Mg等二价阳离子的类质同像替代的多少,明显地影响晶胞参数和穆斯堡尔参数.文中讨论了它们的变化规律性.     

Epithermal deposits in North Xinjiang, NW China

The North Xinjiang region (NW China) is an important part of the Central Asia Orogenic Belt, situated at the junction of Siberia, Tarim and Kazakhstan plates. It is an area characterized by multiple stages of Phanerozoic continental growth, during which several porphyry and epithermal systems were formed. The relationship of these mineral systems to the geodynamic evolution of the region has not yet been well understood. In this paper, we list the main geological characteristics of 21 significant epithermal precious and base metal deposits in North Xinjiang, and classify them into high-sulfidation and low-sulfidation styles, with the latter being predominant. We have selected seven epithermal deposits representing different styles formed under different tectonic regimes and discuss their geology and geochemistry in some detail. The deposit-scale geology and geochemistry of epithermal systems in North Xinjiang are essentially similar to those in other parts of the world. All epithermal deposits in North Xinjiang are hosted in volcanic rocks with ages ranging from Devonian to Triassic, with the Early Carboniferous volcanic sequences being the most important, followed by the Permian and Triassic. The Devonian–Early Carboniferous host rocks belong to the calc-alkaline series that developed in pre-collisional arc-back-arc basin systems; whereas the Permian–Triassic host volcanic rocks of shoshonite series formed in post-subduction regimes. Available isotopic ages of these epithermal systems cluster in two periods: Early Carboniferous (>320?Ma) and Late Carboniferous–Triassic (320–220?Ma), reflecting two metallogenic episodes that occurred during subduction-related accretion and post-subduction collision regimes, respectively. Accordingly, three groups of epithermal deposits in North Xinjiang can be recognized as (1) pre-collisional deposits without or with negligible collisional-related modification, (2) deposits formed in collision regime and (3) ore systems strongly overprinted by fluid flow in post-subduction collision regime.     

中国近海天然气水合物找矿前景

天然气水合物是一种新型能源，在海底沉积物和陆上永远冻土带中均有广泛分布。西太平洋是全球三大天然气水合物成矿带之一，在其中已发现许多水合物矿床或矿点。中国近海，包括南海、东海和台湾东部海域，具备良好的天然气水合物成矿条件和找矿前景，并已在这些海域中发现了一系列的找矿标志。南海的西沙海槽、台湾西南陆坡和台西南盆地、笔架南盆地及其东缘增生楔、东沙群岛东南坡、南部陆坡区，东海的冲绳海槽和台湾东北部海域是中国近海最有利的天然气水合物找矿远景区。     

新疆阿尔泰库威伟晶岩中绿柱石形成的物理化学条件

本文利用包裹体研究探讨了新疆阿尔泰库威伟晶岩中绿柱石形成时的物理化学条件。绿柱石中包裹体类型主要有二类：含硅酸盐子晶流体包裹体和不含硅酸盐子晶气液流体包裹体。含硅酸盐子晶流体包裹体代表岩浆－热液过渡阶段时的一种超临界流体相。结合显微镜观察和含硅酸盐子晶流体包裹体喇曼探针成分测定，得出绿柱石形成时体系中二氧化碳密度较高，ρｃｏ２＝０．６８￣０－．９６ｇ／ｃｍ＾３；盐度很低，ＮａＣｌ（ｗｔ％）＝３．２     

Zircon M127 – A Homogeneous Reference Material for SIMS U–Pb Geochronology Combined with Hafnium,Oxygen and,Potentially, Lithium Isotope Analysis

In this article, we document a detailed analytical characterisation of zircon M127, a homogeneous 12.7 carat gemstone from Ratnapura, Sri Lanka. Zircon M127 has TIMS‐determined mean U–Pb radiogenic isotopic ratios of 0.084743 ± 0.000027 for ²⁰⁶Pb/²³⁸U and 0.67676 ± 0.00023 for ²⁰⁷Pb/²³⁵U (weighted means, 2s uncertainties). Its ²⁰⁶Pb/²³⁸U age of 524.36 ± 0.16 Ma (95% confidence uncertainty) is concordant within the uncertainties of decay constants. The δ¹⁸O value (determined by laser fluorination) is 8.26 ± 0.06‰ VSMOW (2s), and the mean ¹⁷⁶Hf/¹⁷⁷Hf ratio (determined by solution ICP‐MS) is 0.282396 ± 0.000004 (2s). The SIMS‐determined δ⁷Li value is ?0.6 ± 0.9‰ (2s), with a mean mass fraction of 1.0 ± 0.1 μg g^?1 Li (2s). Zircon M127 contains ~ 923 μg g^?1 U. The moderate degree of radiation damage corresponds well with the time‐integrated self‐irradiation dose of 1.82 × 10¹⁸ alpha events per gram. This observation, and the (U–Th)/He age of 426 ± 7 Ma (2s), which is typical of unheated Sri Lankan zircon, enable us to exclude any thermal treatment. Zircon M127 is proposed as a reference material for the determination of zircon U–Pb ages by means of SIMS in combination with hafnium and stable isotope (oxygen and potentially also lithium) determination.