A Revisited Purification of Li for ‘Na Breakthrough’ and its Isotopic Determination by MC‐ICP‐MS

The accurate and precise determination of Li isotopic composition by MC‐ICP‐MS suffers from the poor performance of traditional column chromatography. Previously established chromatographic processes cannot completely remove Na in complex geological samples, which is currently interpreted to be a result of Na breakthrough. In this study, Na breakthrough during single‐column purification was found to differ between simply artificial Na‐containing sample solutions, where a little Na residue was found, and silicate rocks, where a large amount of breakthrough occurred. A revised two‐step column purification for Li using 0.5 and 0.3 mol l^?1 HCl as eluents was designed to remove the Na. This modified method achieves high‐efficiency Li purification from Na and consequently avoiding high Na/Li ratio interference for subsequent MC‐ICP‐MS analyses. The proposed method was validated by the analysis of a series of reference materials, including Li₂CO₃ (IRMM‐016, ‐0.10‰), basalt (BCR‐2: 2.68‰; BHVO‐2: 4.39‰), andesite (AGV‐2: 6.46‰; RGM‐2: 2.59‰), granodiorite (GSP‐2: ?0.87‰) and seawater (CASS‐5, 30.88‰). This work reports early Na appearance prior to the elution curves in chromatography and emphasises its influence for subsequent Li isotope measurement. Based on the findings, the established two‐step method would be more secure than single‐column chemistry for Li purification.     

断层输导下储集层排驱压力对油气成藏影响作用

利用油气成藏物理模拟方法,从排驱压力角度研究了断层输导下的油气藏形成过程。研究表明,储集层排驱压力控制与断层侧向配置不同储盖组合的成藏次序,即排驱压力小的储盖组合优先成藏,排驱压力较大的储盖组合次之,这种控制作用与储盖组合的空间相对位置无关;排驱压力影响不同储盖组合的含油或含气饱和度,排驱压力越小,含油或含气饱和度越高,这种影响作用会因储集层空间相对位置的不同而有所差异;断层与储集层的对接与否是储盖组合成藏的先决条件,与断层对接具备成藏的可能性,而未与断层对接则难以成藏。研究结论可用于勘探实践中对断层输导下多套储盖组合试油层位进行评价优选。     

Advances in Oxygenation Theory and Technology in Deep Lakes

Deep lakes always maintain vertical thermal stratification due to their physical structure. The thermocline prevents the transfer of oxygen from epilimnion to hypolimnion, leading to the formation of anoxic conditions in deeper water, the enhanced release of endogenous pollutants and the deterioration of water quality. Oxygenation is an effective measure to improve the water quality of deep lakes and mitigate the release of endogenous pollutants via the increase of the oxygen level in water. This paper provided an overview of the method and theory of oxygenation in deep lakes. Advantages and limitations of different methods of oxygenation, including artificial destratification, airlift aerators, Speece cone and bubble plume diffusers, were discussed. In addition, challenges and prospects of oxygenation were assessed based on the analyzing of typical examples of oxygenation in deep lakes and the difference in oxygenation system used in deep lakes and shallow lakes.     

三峡水库运行初期的泥沙淤积特点

针对三峡蓄水运行后的泥沙淤积问题,基于实测资料,采用输沙率法和断面法分析了三峡水库运行初期的泥沙淤积特点.结果表明:三峡水库2003—2013年泥沙淤积总量为15.31亿t,平均排沙比为24.5%,均较论证阶段降低;库区泥沙淤积主要分布在常年回水区的宽谷和弯道河段,宽谷段全断面发生淤积、弯道断面流速较小一侧淤积、峡谷无累积性淤积;常年库区近坝段泥沙淤积速度逐年减小,而上段泥沙淤积速度则呈增大趋势;淤积物粒径沿程分选不明显,常年回水区淤积物中值粒径多在0.01 mm以下.库区峡谷段深泓线无明显变化、尚未出现泥沙淤积三角洲、库尾泥沙淤积上延和尾水抬高不明显,据此初步推断峡谷河段存在富余挟沙力而成为局部侵蚀基准面,整个库区将无统一平衡比降的趋势.     

文昌B凹陷差异伸展-走滑机制及控藏作用研究

为查明文昌B凹陷油气富集差异性的原因,基于断裂展布和形成期次、构造样式组合、构造演化和断层活动的差异等标志,建立了差异伸展-走滑机制,识别出19洼为伸展-强走滑、14洼为伸展-中等走滑、30洼为伸展-弱走滑。差异伸展-走滑作用控制了优质烃源岩的展布和供烃方向,控制输导体系类型和运移动力,提供物源通道和改造储层,还控制了圈闭类型和力学性质。进一步深化了走滑增压理论,基于先存断裂形态、伸展应力场右旋演化和应变差异,建立了走滑增压圈闭识别方法,识别出S型增压、右行左阶增压、斜交型增压3种走滑增压构造。研究表明,文昌B凹陷的油气富集受伸展-走滑构造背景、源-运时空配置关系所控制,强—中等走滑变形、发育优质中深湖源岩的文昌19洼和14洼是油气富集区。该研究成果成功推动了文昌凹陷近期的多个勘探发现。     

特提斯喜马拉雅带江孜地区古近纪地层源区分析——对造山带早期地壳加厚的制约

特提斯喜马拉雅北亚带江孜地区上古新统-下始新统甲查拉组记录了喜马拉雅碰撞造山带的早期地壳加厚和沉积历史。本文我们报道了甲查拉组详细的碎屑锆石U-Pb年龄和全岩Sm-Nd同位素数据。甲查拉组由青灰色厚层的岩屑砂岩夹泥岩组成,不整合覆盖在宗卓组之上,碎屑锆石主要的峰值介于350～80 Ma, 900～470 Ma以及1 300～950 Ma,次要的峰值介于2 800～1 500 Ma。全岩⁸⁷Sr/⁸⁶Sr介于0.707 505～0.713 174,¹⁴³Nd/¹⁴⁴Nd介于0.512 206～0.512 355,ε_Nd(0)介于-5.52～-8.43。甲查拉组物源区以再循环的日喀则弧前盆地和上三叠统郎杰学群为主,少量物质来自雅鲁藏布江缝合带。上述研究表明,甲查拉组沉积在周缘前陆盆地的背景下,且特提斯喜马拉雅北亚带在始新世期间经历了明显的地壳加厚。