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101.
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103.
Byproduct Formation During the Reduction of TCE by Zero-Valence Iron and Palladized Iron 总被引:4,自引:0,他引:4
Liyuan Liang Nic Korte J.D. Goodlaxson Jay Clausen Quintus Fernando Rosy Muftikian 《Ground Water Monitoring & Remediation》1997,17(1):122-127
Trichloroethene (TCE) was reduced with zero-valence iron and palladized iron in zero-head-space extractors. Progress of the reaction in these batch studies was monitored with purge-and-trap gas chromatography and a flame ionization detector. When a 5 ppm initial concentration of TCF. reacts with zero-valence iron, approximately 140 ppb of vinyl chloride persists for as long as 73 days. The concentration of vinyl chloride (approximately If) ppb) remaining with palladized iron is approximately an order of magnitude less than when zero-valence iron is the reductant. These data suggest that volatile byproducts may be under-represented in oilier published data regarding reduction with zero-valence metals. These results also demonstrate that the reduction of TCE with palladized iron (0.05 percent palladium) is more than an order of magnitude faster than with zero-valence iron. Wilh a 5:1 solution-to-solid ratio the TCE half-life with zero-valence iron is 7.41 hours. but is only 0.59 hours with the palladized iron. 相似文献
104.
进入21世纪以来,信息技术得到飞速发展,使得信息获取途径日益呈现出多元化特性,强烈地冲击了传统的地震科技信息工作依赖馆藏文献提供为主的信息管理和服务模式.同时也更凸显了地震科技信息工作在信息开发利用与服务上的种种缺陷.变革中的社会信息环境,迫使我们重新审视和思考网络环境下地震科技信息管理与服务等诸多问题,加强地震科技信息工作创新的研究与思考. 相似文献
105.
未定名矿物(Bi38CrO60)的矿物学研究 总被引:2,自引:0,他引:2
人工合成立方晶体Bi38CrO60在自然界首次发现于中国陕西省洛南县驾鹿金矿床中,暂称之为未定名矿物.其共生和伴生矿物有黄铁矿、自然金、碲金矿、含氧金矿物等.常呈不规则粒状集合体,偶见立方体微晶(粒径小于0.05 mm),棕黑色,金属光泽;HV=232.78 kg/mm2 ,HM=4.15;D=14.10(3)g/cm3,Dx=14.08(2)g/cm3,n=3.14(3).EPM8100探针分析Bi2O3为98.854%、CrO3为1.111%,合计99.965%,化学式为Bi38.009Cr0.995O60;CAMEBAX-SX51探针分析Bi2O3为98.862%,CrO3为1.112%,合计99.974%,化学式为Bi38.008Cr0.996O60.均可写为Bi38CrO60.X射线粉晶分析主要强度线d(I)(hkl)分别为0.321 5(100),(310);0.272 11(72),(321);0.171 45(40),(530);0.169 6(30),(600);0.165 1(30),(611);0.160 8(30),(620);0.294 11(25),(222);0.359 6(22),(220);0.217 1(20),(332);0.150 3(20),(631),等轴晶系,可能的空间群为Im3m;a=1.018 1(1)nm,c/a=1,晶胞体积v=1.055 29(1)nm3,z=1.1-Kp/Kc=0.019.Cr6 ,Bi3 ,O2-.未定名矿物和人工晶体的化学成分与X射线粉晶数据基本一致. 相似文献
106.
中国南方海相含油气保存单元的层次划分与综合评价 总被引:1,自引:0,他引:1
以最近十年中国南方的海相新区油气勘探评价成果为依托 ,以油气成藏和整体封闭保存体系评价为核心 ,在渝东—湘鄂西、中下扬子和滇黔桂三大区域划分出 9个有利区块 5 1个含油气保存单元 ,并将其归纳为四个层次。综合评价认为 ,方西和石柱保存单元具有较好的整体封存体系 ,属持续性含油气保存单元 ,为首选勘探目标 ;江汉盆地南部、句容—海安区块、南鄱阳坳陷、楚雄盆地东北部具备或基本具备整体封存条件 ,属于沉积重建型含油气保存单元 ,通过精细勘探可望获得商业性油气流 ;楚雄盆地西北部、南盘江坳陷、十万大山盆地和渝东—湘鄂西地区利川复向斜由于晚期强烈构造改造而仅存在部分封存体系 ,需要攻关探索 ;思茅、渝东—湘鄂西地区的花果坪和桑植—石门地区已失去整体封闭保存条件 ,仅局部存在封存体系 ,地质条件高度复杂 ,勘探风险甚高。 相似文献
107.
Rb-Sr isochron age of fluid inclusions in quartz from the Fuwan super-large silver deposit is 68 - 6 Ma, the silver deposit is characterized by high μ values (10.67 - 10.95 ), which are much higher than those of the ore-hosted Paleozoic strata and are close to those of ores hosted in the Proterozoic metamorphic basement in western Guangdong Province. Based on the Pb isotopic characteristics, coupled with much high background silver contents (200-1000ng/g) in the Proterozoic basement and relatively low silver contents in the Paleozoic strata in the region of the Sanshui Basin, it is concluded that the ore-forming material of the super-large silver deposit came mainly from the old basement. The super-large silver deposit related genetically to the intense volcanic activities during the Upper Cretaceous to Eogene. The formation of the Fuwan super-large silver deposit is controlled by the following favorable geological conditions : ( 1 ) The intersection of deep faults and contemporaneous faults at the margin of the Sanshui Basin led to the formation of an excellent structure as passageway for ore fluids; (2) The special ore-hosted rock association forms a ore gathering-trap structure that favors the precipitation of ore; (3) The silver-rich old basement, multi-stage mineralization and multi-episode volcanic activities which constitute a geothermal convection system. 相似文献
108.
21世纪中国地质灾害防治形势与减灾战略思考 总被引:9,自引:0,他引:9
张樑 《中国地质灾害与防治学报》2004,15(2):16-21
文章论述了21世纪中国地质灾害减灾面临的形势是既存在许多有利条件又存在多方面困难而面临严重挑战。提出21世纪地质灾害减灾战略:1.建立地质灾害防治安全维护体系;2.优先安排西部地区地质灾害防治工程,实施地质灾害风险管理;3.建立矿山地质灾害防治监督管理体系;4.城市地质灾害防治与土地利用相结合;5.加强我国地质环境监测与网站建设;6.针对地质灾害区域分布规律,采取分区减灾对策;7.加大地质灾害防治投入力度。 相似文献
109.
Two models are tested on a shake‐table. One of the models is a normal reinforced concrete megaframe structure and the other is a multifunctional vibration‐absorption reinforced concrete megaframe structure in which the laminated rubber bearings are placed between the major frame and the minor frames. Two earthquake motions (the El Centro wave and the Taft wave) are used during the test. This paper presents the dynamic characteristic, the seismic responses and the failure mechanism of these two models under varying peak acceleration levels for each of the earthquake motions. The test results demonstrate that the aseismic behavior of a multifunctional vibration‐absorption reinforced concrete megaframe structure is much better than that of a normal reinforced concrete megaframe structure. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
110.
This study investigates an electric‐type active mass driver (AMD) system for structural vibration control. Composed primarily of an electric servomotor and a ball screw, the electrical AMD system is free from noise problems, oil leakage, and labor‐intensive maintenance that commonly are associated with hydraulic AMD systems. The desired stroke amplification of the mass and the power demand of the servomotor can be adjusted via the ball screw pitch, which in turn affects the effectiveness and efficiency of the system. Meanwhile, an instantaneous optimal direct output feedback control algorithm is adopted. Numerical simulation is performed using a five‐story steel frame as the object structure under the conditions of the 1940 El Centro earthquake. The AMD system proves to be effective and efficient within a certain range of the ball screw pitch. The reductions of the peak responses can reach as high as 70% if properly designed. Requiring only the velocity measurement of the top floor for on‐line feedback control, the proposed control algorithm is recommended for practical implementation. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献