Comparison of coupled and uncoupled models in simulating Monsoon Intraseasonal Oscillation from CMIP6

The monsoon intraseasonal oscillation (MISO) is the dominant variability over the Indian Ocean during the Indian summer monsoon (ISM) season and is characterized by pronounced northward propagation. Previous studies have shown that general circulation models (GCMs) still have difficulty in simulating the northward-propagating MISO, and that the role of air-sea interaction in MISO is unclear. In this study, 14 atmosphere-ocean coupled GCMs (CGCMs) and the corresponding atmosphere-only GCMs (AGCMs) are selected from Phase 6 of the Coupled Model Intercomparison Project (CMIP6) to assess their performance in reproducing MISO and the associated vortex tilting mechanism. The results show that both CGCMs and AGCMs are able to well simulate the significant relationship between MISO and vortex tilting. However, 80% of CGCMs show better simulation skills for MISO than AGCMs in CMIP6. In AGCMs, the poor model fidelity in MISO is due to the failure simulation of vortex tilting. Moreover, it is found that failure to simulate the downward motion to the north of convection is responsible for the poor simulation of vortex tilting in AGCMs. In addition, it is observed that there is a significant relationship between the simulated sea surface temperature gradient and simulated vertical velocity shear in the meridional direction. These findings indicate that air-sea interaction may play a vital role in simulating vertical motions in tilting and MISO processes. This work offers us a specific target to improve the MISO simulation and further studies are needed to elucidate the physical processes of this air-sea interaction coupling with vortex tilting.     

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

Ecological risk assessment and ecological security pattern optimization in the middle reaches of the Yellow River based on ERI+MCR model

The middle reaches of the Yellow River represent an important area for the protection and development of the Yellow River Basin. Most of the area of the river basin is within the Loess Plateau, which establishes it as a fragile ecological environment. Firstly, using high-resolution data of land use in the watershed from the past 30 years, landscape ecological risk(LER) sample units are defined and an ecological risk index(ERI) model is constructed. Kriging interpolation is used to display the LE...     

利用验潮站数据进行三种潮汐模型的精度分析

采用全球分布的565个验潮站水位资料对NAO.99b,CSR4.0和TPXO7.2三种潮汐模型进行精度评估。结果表明:在全球海洋范围内,NAO.99b模型精度最高;在黄海海域,TPXO7.2模型的精度最高;在东海和南海海域,则是NAO.99b模型最优;在深海海域,三种模型精度差异不大;在浅海海域,采用同化方法的潮汐模型比采用经验方法的潮汐模型更有优势。     

Molecularly imprinted polymers for selective extraction of crystal violet from natural seawater coupled with high-performance liquid chromatographic determination

Molecularly imprinted polymers(MIPs) were prepared by the bulk polymerization using crystal violet as the template molecule, and the methacrylic acid and ethylene glycol dimetheacrylate as functional monomer and cross-linker, respectively. Systematic investigations of synthetic conditions were conducted. The surface morphology and recognition mechanism of the obtained polymers were studied using scanning electron microscope and spectrophotometric analysis. MIPs showed high affinity to template molecule and were successfully applied as special solid-phase extraction sorbent for selective extraction of crystal violet from natural seawater. An off-line molecularly imprinted solid-phase extraction(MISPE) method followed by high-performance liquid chromatography with diodearray detection for the analysis of crystal violet was also established. MISPE columns have good recoveries for crystal violet standard solutions and good linearity was obtained over the concentration range of 0-200 μg L-1(R2 0.99). Finally, two natural seawater samples were investigated. The recoveries of spiked seawater on the MISPE columns were from 44.47% to 62.34%, the relative standard deviation(n=3) being in the range of 2.89%-5.96%.     

东亚季风区近地面大气气溶胶中OCPs和PCBs纬度分布：以7Be为参照系

连续一年在北京、青岛、广州以每周3d的时间尺度同步采集近地面大气中气溶胶中7Be的测定数据以及在春、秋季节变换时期我国5个不同纬度城市大气气溶胶中7Be和典型持久性有机污染物（有机氯农药和多氯联苯1的同步观测数据,并对文献上发表的我国其他城市近地面大气中气溶胶中’Be年平均值数据进行了分析。通过对以上数据资料的总结和分析,观察到在东亚季风区近地表大气气溶胶中7Be浓度的年平均值呈现正态分布模式,并且在中纬度北纬40°N附近达到极大值。大气气溶胶中7Be在春、秋季节变换时期我国不同纬度城市的瞬时纬度分布仍呈现正态分布模式,但以30°N为最大值。在秋季大气颗粒相中HCHs和PCBs浓度最大值出现在30°N。气相中PCB-28所占百分比随纬度增高而增大,而颗粒相中PCB-28的纬度变化不大。蒸汽压较低的PCB-180在气相中的浓度基本上不随纬度变化,而颗粒相中PCB-180则基本上集中在纬度36。N左右,表明在东亚季风区大气中挥发性较低的POPs化合物具有某种纬度聚焦作用。以宇宙射线成因核素7Be作为大气环流的参照系,可以得出东亚季风区大气环流可影响持久性有机污染物纬度分布的结论。     

中国旅游业碳减排潜力的空间关联网络结构及其影响因素

基于2000—2018年中国省际面板数据,利用“自下而上”法和Super-SBM模型测度30个省（区、市）的旅游业碳减排潜力,借助修正的引力模型和社会网络分析方法探究其空间关联网络特征及影响因素。结果表明：①中国旅游业碳减排潜力的空间关联日趋紧密,网络密度和网络关联数呈增长态势,网络效率和网络等级度呈下降态势;②东部区域在空间关联网络中居于核心位置,对降低旅游业碳减排潜力所需要素的掌控与支配能力较强;西部区域在网络中居于边缘位置,难以影响和控制其他省（区、市）;③北京、天津、江苏和上海属于“净受益”板块,广东、浙江和福建属于“经纪人”板块,吉林、内蒙古等23省（区、市）属于“净溢出”板块;④空间邻接关系、经济发展水平差异、产业结构差异、技术创新水平差异和旅游业人数规模差异共同驱动着中国旅游业碳减排潜力空间关联网络结构的形成与演化。     

Effects of different operational modes on the flood‐induced turbidity current of a canyon‐shaped reservoir: case study on Liuxihe Reservoir,South China

Suspended matter is an important indicator of water quality in freshwater systems. The flood‐induced turbidity current plays a dominant role in the seasonal dynamic of suspended matter in the Liuxihe Reservoir (23°45′50″N; 113°46′52″E), a large, stratified reservoir at the Tropic of Cancer in southern China. Field measurements show that loading and distribution of suspended matter in the reservoir differ in typical wet, dry and medium years, as a result of different discharge volumes and water level variation patterns. Using historical data and the practical demand for water supply and flood control, we generalized two feasible reservoir operational modes: flood impounding mode (drawing down the reservoir to a low level before flood events to impound inflow during the flooding season) and moderate level change mode (drawing down the reservoir to a moderate level before flood events, then keeping the level within the flood control level during runoff events). To examine the effects of different operational modes and outlet depths on the reservoir's flood‐induced turbidity current, a numerical simulation model was applied in three types of hydrological conditions. The results show that the mode with moderate drawdown and recharge processes can decrease loading of suspended matter in spring and promote turbidity current release during flood events, and upper withdrawal can improve the effects of turbid water release. We suggest that more attention should be focused on water quality management in the reservoir operation stage, severe artificial water level fluctuation being avoided and selective withdrawal becoming an optional management measure. Copyright © 2012 John Wiley & Sons, Ltd.     

Till‐forming processes beneath parts of the Cordilleran Ice Sheet,British Columbia,Canada: macroscale and microscale evidence and a new statistical technique for analysing microstructure data

This paper presents the first integrated macroscale and microscale examination of subglacial till associated with the last‐glacial (Fraser Glaciation) Cordilleran Ice Sheet (CIS). A new statistical approach to quantifying till micromorphology (multivariate hierarchical cluster analysis for compositional data) is also described and implemented. Till macrostructures, macrofabrics and microstructures support previous assertions that primary till in this region formed through a combination of lodgement and deformation processes in a temperate subglacial environment. Macroscale observations suggest that subglacial environments below the CIS were probably influenced by topography, whereby poor drainage of the substrate in topographically constricted areas, or on slopes adverse to the ice‐flow direction at glacial maximum, facilitated ductile deformation of the glacier bed. Microscale observations suggest that subglacial till below the CIS experienced both ductile and brittle deformation, including grain rotation and squeeze flow of sediment between grains under moist conditions, and microshearing, grain stacking and grain fracturing under well‐drained conditions. Macroscale observations suggest that ductile deformation events were probably followed by brittle deformation events as the substrate subsequently drained. The prevalence of ductile‐type microstructures in most till exposures investigated in this study suggests that ductile deformation signatures can be preserved at the microscale after brittle deformation events that result in larger‐scale fractures and shear structures. It is likely that microscale ductile deformation can also occur within distributed shear zones during lodgement processes. Cluster analysis of microstructure data and qualitative observations made from thin sections suggest that the relative frequency of countable microstructures in this till is influenced by topography in relation to ice‐flow direction (bed drainage conditions) as well as by the frequency and distribution of voids in the till matrix and skeletal grain shapes.     

Scattering of elastic wave by a partially sealed cylindrical shell embedded in poroelastic medium

Scattering of an elastic wave by a cylindrical shell embedded in poroelastic medium is investigated theoretically with the assumption that the shell material is also a porous elastic medium. The porous medium is modellized via Biot's theory and the scattering by cylindrical shell is expressed by the definition of scattering matrix. The normal mode expansion technique is employed for analysing the scattering field, and the asymptotic solutions of displacements, stresses and pore pressure are derived. Two limiting cases‐scattering by a poroelastic cylinder in Biot medium and a elastic cylindrical shell in elastic medium are obtained from the general solutions. The dispersion curves of displacement amplitude at the interface of shell and medium is compared with the case of elastic shell. The scattering amplitude associated with the fast, slow and transverse waves are identified by numerical simulation. Furthermore, the influence of the poroelastic property of shell material on scattering amplitude is analysed. Copyright © 2005 John Wiley & Sons, Ltd.