Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.     

Influence of basement structures on the evolution of the major sedimentary basins of Brazil: A case of tectonic heritage

The present study deals with the correlation between the geotectonic features of the basement and the internal structure, shape, geologic evolution, etc. of the major sedimentary basins of the South American platform. The Paraná, Parnaíba and Amazonas basins occupy an area of the order of 3.6 × 10⁶ km², and their sedimentary cratonic sequences were deposited from Silurian to Triassic times. Subsidence rates are estimated around 15 m/Ma in the main depocenters.A geologic study was carried out along the basement features in the surroundings of such basins in order to identify the major structural, geotectonic and geochronological discontinuities. The extension of these basement characteristics towards the interior of the basins are examined. Basement core samples from deep wells were investigated through petrological and geochronological analyses, and pre-existing geophysical and structural maps of those basins were taken again into consideration.It can be concluded that many of the identified basement discontinuities display a direct influence on the depositional history of the basins as well as on their internal subdivisions and external outlines. Basement structures generated during the late Precambrian Brasiliano Cycle turned out to be particularly important.The Paraná and Parnaíba basins are considered to represent cratonic basins, located on rigid lithosphere, tectonically stabilized in the latest Precambrian/early Palaeozoic, and their subsidence is attributed to the establishement of some initial rifted grabens. The Amazonas basin is more complex and includes three large sub-basins with distinct evolutions, each located on a different tectonic segment of the basement.     

Denudation and retreat of the Serra do Mar escarpment in southern Brazil derived from in situ‐produced 10Be concentration in river sediment

The Serra do Mar escarpment, located along the southeastern coast of Brazil, is a high‐elevation passive margin escarpment. This escarpment evolved from the denudation of granites, migmatites and gneisses. The granites outcrop in the form of a ridge along the escarpment crest, due to its differential erosion (‘sugarloaf’ hills) from the surrounding lithologies. Several studies suggest that the passive margin escarpments are actively retreating toward the interior of the continent. However, no prior study has calculated the long‐term denudation rates of Serra do Mar to test this hypothesis. In this study, we measured the in situ‐produced ¹⁰Be concentration in fluvial sediments to quantify the catchment‐wide long‐term denudation rates of the Serra do Mar escarpment in southern Brazil. We sampled the fluvial sediments from ten watersheds that drain both sides of the escarpment. The average long‐term denudation rate of the oceanic side is between 2.1‐ and 2.6‐fold higher than the rate of the continental side: 26.04 ± 1.88 mm ka^‐1 (integrating over between 15.8 ka^‐1 and 46.6 ka^‐1) and 11.10 ± 0.37 mm ka^‐1 (integrating over between 52.9 ka^‐1 and 85.4 ka^‐1), respectively. These rates indicate that the coastal base level is controlling the escarpment retreat toward the continental high lands, which is consistent with observations made at other high‐elevation passive margins around the globe. The results also demonstrate the differential erosion along the Serra do Mar escarpment in southern Brazil during the Quaternary, where drainages over granites had lower average denudation rates in comparison with those over migmatites and gneisses. Moreover, the results demonstrate that the ocean‐facing catchments have been eroded more intensely than those facing the continent. The results also reveal that drainage over the granites decreases the average denudation rates of the ocean‐facing catchments and the ‘sugarloaf’ hills therefore are natural barriers that slowly retreat once they are exhumed. Copyright © 2013 John Wiley & Sons, Ltd.     

Brazilian spatial dynamics in the long term (1872–2000): “path dependency” or “reversal of fortune”?

This paper analyzes the spatial dynamics of Brazilian regional inequalities between 1872 and 2000 using contemporary tools. The first part of the paper provides new estimates of income per capita in 1872 by municipality using census and electoral information on income by occupation. The level of analysis is the Minimum Comparable Areas 1872–2000 developed by Reis et al. (áreas mínimas comparáveis para os períodos intercensitários de 1872 a 2000, 2007). These areas are the least aggregation of adjacent municipalities required to allow consistent geographic area comparisons between census years. In the second section of the paper, Exploratory Spatial Data Analysis, Markov chains and stochastic kernel techniques (spatially conditioned) are applied to the dataset. The results suggest that, in broad terms, the spatial pattern of income distribution in Brazil during that period of time has remained stable.     

Crust and Upper Mantle Structure in the Caribbean Region by Group Velocity Tomography and Regionalization

An overview of the crust and upper mantle structure of Central America and the Caribbean region is presented as a result of the processing of more than 200 seismograms recorded by digital broadband stations from SSSN and GSN seismic networks. Group velocity dispersion curves are obtained in the period range from 10s to 40s by FTAN analysis of the fundamental mode of the Rayleigh waves; the error of these measurements varies from 0.06 and 0.09 km/s. From the dispersion curve, seven tomographic maps at different periods and with average spatial resolution of 500 km are obtained. Using the logical combinatorial classification techniques, eight main groups of dispersion curves are determined from the tomographic maps and eleven main regions, each one characterized by one kind of dispersion curves, are identified. The average dispersion curves obtained for each region are extended to 150s by adding data from a larger-scale tomographic study (Vdovin et al., 1999) and inverted using a nonlinear procedure. A set of models of the S-wave velocity vs. depth in the crust and upper mantle is found as a result of the inversion process. In six regions we identify a typically oceanic crust and upper mantle structure, while in the other two the models are consistent with the presence of a continental structure. Two regions, located over the major geological zones of the accretionary crust of the Caribbean region, are characterized by a peculiar crust and upper mantle structure, indicating the presence of lithospheric roots reaching, at least, about 200 km of depth.     

Nutrient dynamics in Mediterranean temporary streams: A case study in Pardiela catchment (Degebe River, Portugal)

Most of the streams in the Mediterranean region are temporary, following predictable seasonal of flooding and drying, with a transition from lotic conditions to shallow lentic conditions. The goal of our study was to assess the nitrogen and phosphorus dynamics in channel-bed processes of temporary streams between floods. Results show that, during winter, temperatures ranged between 9.5 and 11.2 °C and oxygen concentration ranged from 8.0 to 9.5 mg L⁻¹, whereas, during summer, temperatures varied between 21.2 and 26.8 °C and oxygen between 1.2 and 5.3 mg L⁻¹, with oxygen depletion in the pools during the night. The nitrate concentrations were far more abundant during winter (February), while ammonium concentration increased after stream fragmentation into pools (especially in July when oxygen depletion conditions favoured ammonification). Results on sediment profiles showed that the most active sediment layers for NH₄-N are the top 2–3 cm, corresponding to the sediment depositional sites of the stream. Phosphate concentrations had larger variability, yet concentrations decreased from winter to spring and increased again in summer, when the shallow water pools were formed. Sediment profiles at the sediment depositional sites showed that PO₄-P was more dynamic in the first 6 cm.

In Mediterranean temporary streams, nutrient dynamics vary seasonally, as the system transits from lotic conditions to shallow lentic conditions, evidencing the regeneration of nutrients from organic and inorganic matter during the flow cessation period.     

Is the cutting of oil contaminated marshes an efficient clean-up technique in a subtropical estuary?

Cutting and removal of oil-impacted marsh plants are still used worldwide as a clean-up and recovery technique. To experimentally test the efficacy of cutting and removing marsh plants under subtropical conditions, we simulated an oil spill (Bunker MF-180) in Spartina alterniflora marshes and compared the responses of plant height, biomass, density of culms and number of flowering plants in high and low energy areas in Paranaguá Bay (S Brazil) for about 9 months. Cutting and removal were inefficient in promoting or accelerating the recovery of the impacted areas. Cut or uncut impacted marshes fully recovered within 6 months, both in low and high energy areas. Plant cutting should be practiced only when there is an effective risk of contamination of groundwater near urban areas, when obvious aesthetical issues are involved in areas of touristic interest or when there are real short-term conservation risks to threatened species.     

Influence of earthquake ground‐motion duration on damage estimation: application to steel moment resisting frames

This paper presents an analytical study evaluating the influence of ground motion duration on structural damage of 3‐story, 9‐story, and 20‐story SAC steel moment resisting frame buildings designed for downtown Seattle, WA, USA, using pre‐Northridge codes. Two‐dimensional nonlinear finite element models of the buildings are used to estimate the damage induced by the ground motions. A set of 44 ground motions is used to study the combined effect of spectral acceleration and ground motion significant duration on drift and damage measures. In addition, 10 spectrally equivalent short‐duration shallow crustal ground motions and long‐duration subduction zone records are selected to isolate duration effect and assess its effect on the response. For each ground motion pair, incremental dynamic analyses are performed at at least 20 intensity levels and response measures such as peak interstory drift ratio and energy dissipated are tracked. These response measures are combined into two damage metrics that account for the ductility and energy dissipation. Results indicate that the duration of the ground motion influences, above all, the combined damage measures, although some effect on drift‐based response measures is also observed for larger levels of drift. These results indicate that because the current assessment methodologies do not capture the effects of ground motion duration, both performance‐based and code‐based assessment methodologies should be revised to consider damage measures that are sensitive to duration. Copyright © 2016 John Wiley & Sons, Ltd     

Salinity and periodic inundation controls on the soil‐plant‐atmosphere continuum of gray mangroves

Salinity and periodic inundation are both known to have a major role in shaping the ecohydrology of mangroves through their controls on water uptake, photosynthesis, stomatal conductance, gas exchanges, and nutrient availability. Salinity, in particular, can be considered one of the main abiotic regulating factors for halophytes and salt‐tolerant species, due to its influence on water use patterns and growth rate. Ecohydrological literature has rarely focused on the effects of salinity on plant transpiration, based on the fact that the terrestrial plants mostly thrive in low‐saline, unsaturated soils where the role of osmotic potential can be considered negligible. However, the effect of salinity cannot be neglected in the case of tidal species like mangroves, which have to cope with hyperosmotic conditions and waterlogging. We introduce here a first‐order ecohydrological model of the soil/plant‐atmosphere continuum of Avicennia marina—also known as gray mangrove—a highly salt‐tolerant pioneer species able to adapt to hyperarid intertidal zones and characterized by unique morphological and ecophysiological traits. The A. marina's soil‐plant‐atmosphere continuum takes explicitly into account the role of water head, osmotic water potential, and water salinity in governing plant water fluxes. A. marina's transpiration is thus modeled as a function of salinity based on a simple parameterization of salt exclusion mechanisms at the root level and a modified Jarvis' expression accounting for the effects of salinity on stomatal conductance. Consistently with previous studies investigating the physiology of mangroves in response to different environmental drivers, our results highlight the major influence of salinity on mangrove transpiration when contrasted with other potential stressors such as waterlogging and water stress.