Onshore climate change during the Late Triassic marine inundation of the Central European Basin

Sedimentological, pedological and palynological evidence reveal radically increasing onshore humidity during the Rhaetian marine invasion of central Europe along the north-eastern margin of the Central European Basin (southern Sweden). Pre-Rhaetian aridity favoured the formation of Carnian redbeds with calcrete, which were succeeded by Norian hematite-cemented conglomerates, arkoses, arkosic wackestones, and smectititic mudstones deposited on braidplains and in lakes. Superimposed autochthonous coals and gleysols indicate the Rhaetian onset of year-round humidity. Chemically mature sandstones, kaolinitic mudstones and luvisols also formed at this time, influenced by a permanent vegetation cover which lowered soil pH and strongly intensified chemical weathering. The Rhaetian deposits accumulated in floodplain lakes repeatedly subjected to sediment infill, plant colonization and palaeosol development. The humidity shift resembles that contemporaneously recorded in the North Sea region.     

Petrogenesis of ultramafic and mafic xenoliths from Mesozoic basanites in southern Sweden: constraints from mineral chemistry

Jurassic basanite necks occurring at the junction of two major fault zones in Scania contain ultramafic (peridotites, pyroxenites) and mafic xenoliths, which together indicate a diversity of upper mantle and lower crustal assemblages beneath this region. The peridotites can be subdivided into lherzolites, dunites and harzburgites. Most lherzolites are porphyroclastic, containing orthopyroxene and olivine porphyroclasts. They consist of Mg-rich silicates (Mg# = Mg/(Mg + Fe_tot) × 100; 88–94) and vermicular spinel. Calculated equilibration temperatures are lower in porphyroclastic lherzolites (975–1,007°C) than in equigranular lherzolite (1,079°C), indicating an origin from different parts of the upper mantle. According to the spinel composition the lherzolites represent residues of 8–13% fractional melting. They are similar in texture, mineralogy and major element composition to mantle xenoliths from Cenozoic Central European volcanic fields. Dunitic and harzburgitic peridotites are equigranular and only slightly deformed. Silicate minerals have lower to similar Mg# (83–92) as lherzolites and lack primary spinel. Resorbed patches in dunite and harzburgite xenoliths might be the remnants of metasomatic processes that changed the upper mantle composition. Pyroxenites are coarse, undeformed and have silicate minerals with partly lower Mg# than peridotites (70–91). Pyroxenitic oxides are pleonaste spinels. According to two-pyroxene thermometry pyroxenites show a large range of equilibration temperatures (919–1,280°C). In contrast, mafic xenoliths, which are mostly layered gabbronorites with pyroxene- and plagioclase-rich layers, have a narrow range of equilibration temperatures (828–890°C). These temperature ranges, together with geochemical evidence, indicate that pyroxenites and gabbroic xenoliths represent mafic intrusions within the Fennoscandian crust.     

Photochemical production of ammonium and transformation of dissolved organic matter in the Baltic Sea

The release of ammonium from the photochemical degradation of dissolved organic matter (DOM) has been proposed by earlier studies as a potentially important remineralisation pathway for refractory organic nitrogen. In this study the photochemical production of ammonium from Baltic Sea DOM was assessed in the laboratory. Filtered samples from the Bothnian Bay, the Gulf of Finland and the Arkona Sea were exposed to UVA light at environmentally relevant levels, and the developments in ammonium concentrations, light absorption, fluorescence and molecular size distribution were followed. The exposures resulted in a decrease in DOM absorption and loss of the larger sized fraction of DOM. Analysis of the fluorescence properties of DOM using parallel factor analysis (PARAFAC) identified 6 independent components. Five components decreased in intensity as a result of the UVA exposures. One component was produced as a result of the exposures and represents labile photoproducts derived from terrestrial DOM. The characteristics of DOM in samples from the Bothnian Bay and Gulf of Finland were similar and dominated by terrestrially derived material. The DOM from the Arkona Sea was more autochthonous in character. Photoammonification differed depending on the composition of DOM. Calculated photoammonification rates in surface waters varied between 121 and 382 μmol NH₄⁺ L^− 1 d^− 1. Estimated areal daily production rates ranged between 37 and 237 μmol NH₄⁺ m^− 2 d^− 1, which are comparable to atmospheric deposition rates and suggest that photochemical remineralisation of organic nitrogen may be a significant source of bioavailable nitrogen to surface waters during summer months with high irradiance and low inorganic nitrogen concentrations.     

Postglacial depositional environments and sedimentation rates in the Norwegian Channel off southern Norway

Based on seismic profiles, multibeam bathymetry and sediment cores, an improved understanding of the deglaciation/postglacial history of the southern part of the Norwegian Channel has been obtained. The Norwegian Channel Ice Stream started to recede from the shelf edge ca. 15.5 ka BP (¹⁴C ages are used throughout). Approximately 500–1000 years later the ice margin was located east of the deep Skagerrak trough. At that time, the Norwegian Channel off southern Norway had become a large fjord-like embayment, surrounded by the grounded ice sheet along the northern slope and possibly stagnant ice remnants at the southern flank. The Norwegian Channel off southern Norway has been the main sediment trap of the North Sea, and south of Egersund more than 200 m of sediments have been deposited since the start of the deglaciation. Five seismic units are mapped. The oldest unit E occurs in some of the deepest troughs, and was deposited immediately after the ice became buoyant. Unit D is acoustically massive and comprises mass-movement deposits in eastern Skagerrak and south of Egersund. Unit C (in the channel southwest of Lista/Egersund) is interpreted to comprise mainly bottom current deposits derived from palaeo-rivers, e.g. Elben. During deposition of unit C (ca. 14.5–13 ka BP), there was limited inflow of Atlantic water. A change in depositional environment at ca. 13 ka BP is related to an increased inflow of saline water and more open hydrographic circulation. Widely distributed, acoustically stratified clays of unit B were deposited ca. 13–10 ka BP. The Holocene Unit A shows a depositional pattern broadly similar to that of unit B.     

Flow of Canadian basin deep water in the Western Eurasian Basin of the Arctic Ocean

The LOMROG 2007 expedition targeted the previously unexplored southern part of the Lomonosov Ridge north of Greenland together with a section from the Morris Jesup Rise to Gakkel Ridge. The oceanographic data show that Canadian Basin Deep Water (CBDW) passes the Lomonosov Ridge in the area of the Intra Basin close to the North Pole and then continues along the ridge towards Greenland and further along its northernmost continental slope. The CBDW is clearly evident as a salinity maximum and oxygen minimum at a depth of about 2000 m. The cross-slope sections at the Amundsen Basin side of the Lomonosov Ridge and further south at the Morris Jesup Rise show a sharp frontal structure higher up in the water column between Makarov Basin water and Amundsen Basin water. The frontal structure continues upward into the Atlantic Water up to a depth of about 300 m. The observed water mass division at levels well above the ridge crest indicates a strong topographic steering of the flow and that different water masses tend to pass the ridge guided by ridge-crossing isobaths at local topographic heights and depressions. A rough scaling analysis shows that the extremely steep and sharply turning bathymetry of the Morris Jesup Rise may force the boundary current to separate and generate deep eddies.     

Fluxes and Concentrations of Non-Conserved Scalars in the Atmospheric Surface Layer

We have carried out a theoretical study of the simplest possible, second-order, chemical destruction process in the atmospheric surface layer. The model describes the destruction of two gases emanating from the surface with the same molecular flux. Although this situation seems artificial with no counterpart in the real atmosphere, the results shed light on some fundamental problems. For example, it is possible to specify boundary conditions, with the concentrations and the fluxes at a given height away from the surface, which lead to unrealistic solutions with infinite surface fluxes. A method to describe and separate the consistent solutions for this process was developed. It is in general of particular interest from an experimental point of view since it is not possible to measure fluxes right at the surface: if a measurement of flux and concentration in a given height requires infinite surface fluxes there is something wrong with the data. We expect that such problems will be inherent in more complex reactions schemes, such as the NO-NO₂-O₃ triad. Just as in first-order destruction processes, the Damköhler ratio will enter the turbulent diffusivity, but where this ratio is concentration independent for first-order processes, the present second-order model implies that the Damköhler ratio is proportional to the concentration. In the study of first-order processes it was found that the Damköhler correction to the turbulent diffusivity is of minor importance from an experimental point of view. We arrive at the same conclusion in this particularly simple study of second-order destruction. In other words, this work may be considered a further development of a previous study of the first-order destruction of a passive scalar. The model and the method we develop to solve the corresponding nonlinear differential equations are considered a preliminary study for developing tools to deal with more complicated atmospheric processes. Also, the results obtained may serve as a “calibration case” for more elaborate simulations.     

Coronal magnetic structure at a solar sector boundary

The persistent large-scale coronal magnetic structure associated with a sector boundary appears to consist of a magnetic arcade loop structure extending from one solar polar region to the other in approximately the north-south direction. This structure was inferred from computed coronal magnetic field maps for days on which a stable magnetic sector boundary was near central meridian, based on an interplanetary sector boundary observed to recur during much of 1968 and 1969.     

Radiocarbon dating of subfossil Scots pine (Pinus sylvestris L.) in the southern Swedish Scandes

Wood samples from above the present-day pine limit were collected from within a limited area in central Sweden. New dates from an intensively investigated part of that area all fall within the period 8550 ± 110 to 4270 ± 90 ¹⁴C years B. P. No evidence at present exists to suggest that any drastic change, or fluctuations, in the pine tree-limit, took place within that period. Some dates support the view that the present-day altitude of the pine tree-limit was established during the historic period and perhaps is still declining.     

The effect of copper-treated net pens on farmed salmon (Salmo salar) and other marine organisms and sediments

Samples of Atlantic salmon (Salmo salar), saithe (Pollacius virens), blue mussel (Mytilus edulis), brown seaweed (Ascophyllum nodosum) and sediment were collected from six different fish farms. Five of the farms used net pens treated with copper-containing coatings, whereas one farm did not use copper-containing coating (this was used as a reference location). Samples of muscle, liver and gills of Atlantic salmon and saithe, blue mussel and brown seaweed were freeze dried, homogenised, wet digested and analysed for copper by flame atomic absorption spectrometry. The results showed no significant differences in copper concentrations among the samples from the different locations. The copper contents of some of the samples appeared to be in the upper part of the normal concentration range. From a nutritional point of view, the use of copper-coatings on net pens did not affect the quality of the seafood products either within, or around the net pen.