Rapid, high-precision potentiometric titration of alkalinity in ocean and sediment pore waters

A system for rapid, high precision potentiometric determination of alkalinity in sea water and sediment pore water is presented. Two titration units were used: a 40 ml unit for seawater and a small volume unit for sediment pore water. Titration time was normally less than 10 minutes per sample, including sample exchange. With a 40 ml sample volume, the relative standard deviation of the alkalinity obtained in the laboratory was 0.05% and at sea 0.1 %. The small-volume system (0.5–1.5 ml) gave a precision of 0.07%. Five titration points, in two groups after the second equivalence point, were used to evaluate the equivalence volume. Results from equilibrium calculations and computer simulated alkalinity titrations show that it was possible to use a non-modified Gran function [(V₀ +v)^*10^(E/Z)] and still achieve good accuracy and precision.     

Wood dynamics in upland streams under different disturbance regimes

This paper presents reach scale large wood (LW) budgets of 12 upland streams in the Okanagan Basin of British Columbia. The study included 100 m long reaches at three wildfire sites and three undisturbed sites in the Interior Douglas‐fir (IDF) biogeoclimatic zone, and three recent Mountain Pine Beetle (MPB) infestation sites and three undisturbed sites in the Montane Spruce (MS) zone. Detailed information on wood recruitment, output and storage were obtained from repeated annual surveys. Recruitment from the riparian zone was found to dominate wood inputs, with fluvial import of secondary importance. In undisturbed streams, wood exhumation was found to be of tertiary importance, but was not observed in disturbed streams. Relative wood length was found to be a strong predictor of wood stability, with wood length to channel width and wood diameter to channel depth ratios of 1:1 forming an approximate maximum threshold of wood mobility. Volumetric decomposition was, on average, a third of the value of fluvial export, and the average residence time of wood in the channels was 20 years. In undisturbed reaches, wood storage indicated a slow depletion of wood from the channels. In the disturbed reaches, wildfire was found to significantly increase annual wood recruitment by more than an order of magnitude over undisturbed or control streams. MPB had not significantly increased LW recruitment, but is expected to increase over the coming decades. Storage rates at the disturbed streams indicated a net accumulation of wood over the study period. Copyright © 2012 John Wiley & Sons, Ltd.     

Stability,morphology and surface grain size patterns of channel bifurcation in gravel–cobble bedded anabranching rivers

This study presents the first detailed field‐based analysis of the morphology of bifurcations within anabranching cobble–gravel rivers. Bifurcations divide the flow of water and sediment into downstream anabranches, thereby influencing the characteristics of the anabranches and the longevity of river islands. The history, morphology, bed grain size, and flow vectors at five bifurcations on the Renous River, New Brunswick, Canada, were studied in detail. The angles of bifurcations within five anabranching rivers in the Miramichi basin were investigated. The average bifurcation angle was 47°, within the range of values cited for braided river bifurcations. Bifurcation angle decreased when anabranches were of similar length. Shields stresses in channels upstream of bifurcations were lower than reported values for braided rivers. Stable bifurcations displayed lower Shields stresses than unstable bifurcations, contrary to experimental results from braided river bifurcations. Bifurcations in anabranching rivers are stabilized by vegetation that slows channel migration and helps to maintain a uniform upstream flow field. The morphology of stable bifurcations enhances their stability. A large bar, shaped like a shallow ramp that increases in elevation to floodplain level, forms at stable bifurcations. Floodplains at stable bifurcations accrete upstream at rates between 0·9 and 2·5 m a^?1. Bars may also form within the entrance of an anabranch downstream of the bifurcation node. These bars are associated with bifurcation instability, forming after a period of stability or an avulsion. Channel abandonment occurs when a bar completely blocks the entrance to one anabranch. The stability of channels upstream of bifurcations and the location of bars at bifurcations influence bifurcation stability and the maintenance of river anabranching in the long term. Copyright © 2006 John Wiley & Sons, Ltd.     

Why are offices where they are? The search for factors determining the location of company headquarters

Cases are presented which illustrate three differenct ways in which the locations of corporate headquarters were established. The office is in a particular city or urban center because 1) the firm was founded there, the founder apparently making no assesment of the advantages of the place in comparison with other places, 2) the palce was considered the most appropriate for manufacturing or for some other operative activity, or 3) it met the requirements of the specific activities of the head office. Factors influencing the selection of head office locations are suggested, as well as factors conserving the locational pattern of such offices, i.e. obstacles to moves.     

Benthic trophic status and nutrient fluxes in shallow-water sediments

Proliferation of fast-growing ephemeral macroalgae in shallow-water embayments constitutes a large-scale environmental change of coastal marine ecosystems. Since inorganic nutrients essential for the initiation and maintenance of macroalgal growth may be supplied from the underlying sediment, we investigated the coupling between benthic inorganic nutrient (mainly N and P) fluxes and sediment properties in 6 bays representing a wide gradient of sediment characteristics (grain size, organic matter content, solid phase C and N). The initial characterization of bays was made in June and also included measurements of oxygen flux and microphytobenthic and macrofaunal biomass. In September, still within the growth season of the macroalgae, complementary experiments with sediment-water incubations for benthic flux measurements of oxygen and nutrients focused on trophic status (balance between auto- and heterotrophy) as a controlling factor for rates of measured benthic nutrient fluxes. Generally, sediments rendered autotrophic by microphytobenthic photosynthesis removed nutrients from the overlying water, while heterotrophic sediments supplied nutrients to the overlying bottom water. Estimations of the green-algal nutrient demand suggested that late in the growth season, net heterotrophic sediments could cover 20% of the N-demand and 70% of the P demand. As the benthic trophic status is a functional variable more closely coupled to nutrient fluxes than the comparably conservative structural parameter organic matter content, we suggest that the trophic status is a more viable parameter to classify sediments and predict benthic nutrient fluxes in shallow-water environments.     

Uptake of atmospheric carbon dioxide in Arctic shelf seas: evaluation of the relative importance of processes that influence pCO2 in water transported over the Bering–Chukchi Sea shelf

The uptake of atmospheric carbon dioxide in the water transported over the Bering–Chukchi shelves has been assessed from the change in carbon-related chemical constituents. The calculated uptake of atmospheric CO₂ from the time that the water enters the Bering Sea shelf until it reaches the northern Chukchi Sea shelf slope (1 year) was estimated to be 86±22 g C m⁻² in the upper 100 m. Combining the average uptake per m³ with a volume flow of 0.83×10⁶ m³ s⁻¹ through the Bering Strait yields a flux of 22×10¹² g C year⁻¹. We have also estimated the relative contribution from cooling, biology, freshening, CaCO₃ dissolution, and denitrification for the modification of the seawater pCO₂ over the shelf. The latter three had negligible impact on pCO₂ compared to biology and cooling. Biology was found to be almost twice as important as cooling for lowering the pCO₂ in the water on the Bering–Chukchi shelves. Those results were compared with earlier surveys made in the Barents Sea, where the uptake of atmospheric CO₂ was about half that estimated in the Bering–Chukchi Seas. Cooling and biology were of nearly equal significance in the Barents Sea in driving the flux of CO₂ into the ocean. The differences between the two regions are discussed. The loss of inorganic carbon due to primary production was estimated from the change in phosphate concentration in the water column. A larger loss of nitrate relative to phosphate compared to the classical ΔN/ΔP ratio of 16 was found. This excess loss was about 30% of the initial nitrate concentration and could possibly be explained by denitrification in the sediment of the Bering and Chukchi Seas.     

Phenols in hydrothermal petroleums and sediment bitumen from Guaymas Basin, Gulf of California

The aliphatic, aromatic and polar (NSO) fractions of seabed petroleums and sediment bitumen extracts from the Guaymas Basin hydrothermal system have been analyzed by gas chromatography and gas chromatography-mass spectrometry (free and silylated). The oils were collected from the interiors and exteriors of high temperature hydrothermal vents and represent hydrothermal pyrolyzates that have migrated to the seafloor by hydrothermal fluid circulation. The downcore sediments are representative of both thermally unaltered and thermally altered sediments. The survey has revealed the presence of oxygenated compounds in samples with a high degree of thermal maturity. Phenols are one class of oxygenated compounds found in these samples. A group of methyl-, dimethyl- and trimethyl-isoprenoidyl phenols (C27-C29) is present in all of the seabed NSO fractions, with the methyl- and dimethyl-isoprenoidyl phenols occurring as major components, and a trimethyl-isoprenoidyl phenol as a minor component. A homologous series of n-alkylphenols (C13-C33) has also been found in the seabed petroleums. These phenols are most likely derived from the hydrothermal alteration of sedimentary organic matter. The n-alkylphenols are probably synthesized under hydrothermal conditions, but the isoprenoidyl phenols are probably hydrothermal alteration products of natural product precursors. The suites of phenols do not appear to be useful tracers of high temperature hydrothermal processes.     

“Bush Doctors and Wild Medicine”: The Scale of Trade in Cape Town's Informal Economy of Wild-Harvested Medicine and Traditional Healing

South Africa's organically emerged cultural business of traditional healing is almost exclusively reliant on wild-harvested resources extracted from wilderness areas or open-access commons. The wild medicine business has been described for much of South Africa, although is little understood in Cape Town, the urban centerpiece of the Cape Floristic Region (CFR). A census of different traditional healer typologies in five typical working-class residential areas (representing ～71,500 residents) was conducted to assess the nature and extent of traditional medicine harvesting and trade. Extrapolating these findings for the city reveals a local industry of more than 15,000 practitioners collectively conducting trade worth US $15.6 million per year. More than 40% of the volume of traditional medicines traded in the city is harvested from the CFR. Future conservation approaches must consider that the business of traditional healing and dispensing wild-harvested medicines is both economically important and culturally entrenched.     

Long-term landscape development of the Coloradofjella plateau, central Spitsbergen, Svalbard

The development and age of the present geomorphology and superficial material of the Coloradofjella plateau, Spitsbergen, have been investigated through field surveying and laboratory sediment analyses. The focus was specifically on the role of glacial erosion and periglacial processes. The summit plain is deeply incised with large V-shaped valleys. Extensive networks of ice wedge polygons indicate that the fine-grained regolith is at least a few metres thick. An abundance of coarse-grained gabbroid erratics, clearly derived from sources further to the east, are distributed over parts of the summit plain. A vertical-walled dolerite dyke protruding up to 4 m above the adjacent surface shows no sign of glacial erosion. Our findings confirm that the present bedrock geomorphology and regolith in the summit plain survived at least the Late Weichselian glaciation. This is best explained by the ice sheet having been cold-based throughout its existence on the summit plain. Cold-based conditions imply that permafrost survived the last glacial cover. Based on the geomorphic evidence and estimates of Late Cenozoic erosion, we suggest that the present summit plains roughly represent the remains of a preglacial surface.