Rapid, high-precision potentiometric titration of alkalinity in ocean and sediment pore waters

A system for rapid, high precision potentiometric determination of alkalinity in sea water and sediment pore water is presented. Two titration units were used: a 40 ml unit for seawater and a small volume unit for sediment pore water. Titration time was normally less than 10 minutes per sample, including sample exchange. With a 40 ml sample volume, the relative standard deviation of the alkalinity obtained in the laboratory was 0.05% and at sea 0.1 %. The small-volume system (0.5–1.5 ml) gave a precision of 0.07%. Five titration points, in two groups after the second equivalence point, were used to evaluate the equivalence volume. Results from equilibrium calculations and computer simulated alkalinity titrations show that it was possible to use a non-modified Gran function [(V₀ +v)^*10^(E/Z)] and still achieve good accuracy and precision.     

Rydberg matter in space: low-density condensed dark matter

Here Rydberg matter is proposed as a candidate for the missing dark matter or dark baryonic matter in the Universe. Spectroscopic and other experimental studies give valuable information on the properties of Rydberg matter, especially its very weak interaction with light caused by the very small overlap with low states, and because of the necessary two-electron transitions even for disturbed matter. Recently, the unidentified infrared (UIR) bands have been shown to agree well with calculations and experiments on Rydberg matter. This is the reason for the present, somewhat speculative, proposal that dark matter has, at least partially, the form of Rydberg matter. The UIR bands have also been observed directly in emission from Rydberg matter in the laboratory. The unique space-filling properties of Rydberg matter are described: a hydrogen atom in this matter occupies a volume  5×10¹²  times larger than in its ground state or in a hydrogen molecule.     

“Bush Doctors and Wild Medicine”: The Scale of Trade in Cape Town's Informal Economy of Wild-Harvested Medicine and Traditional Healing

South Africa's organically emerged cultural business of traditional healing is almost exclusively reliant on wild-harvested resources extracted from wilderness areas or open-access commons. The wild medicine business has been described for much of South Africa, although is little understood in Cape Town, the urban centerpiece of the Cape Floristic Region (CFR). A census of different traditional healer typologies in five typical working-class residential areas (representing ～71,500 residents) was conducted to assess the nature and extent of traditional medicine harvesting and trade. Extrapolating these findings for the city reveals a local industry of more than 15,000 practitioners collectively conducting trade worth US $15.6 million per year. More than 40% of the volume of traditional medicines traded in the city is harvested from the CFR. Future conservation approaches must consider that the business of traditional healing and dispensing wild-harvested medicines is both economically important and culturally entrenched.     

Wood dynamics in upland streams under different disturbance regimes

This paper presents reach scale large wood (LW) budgets of 12 upland streams in the Okanagan Basin of British Columbia. The study included 100 m long reaches at three wildfire sites and three undisturbed sites in the Interior Douglas‐fir (IDF) biogeoclimatic zone, and three recent Mountain Pine Beetle (MPB) infestation sites and three undisturbed sites in the Montane Spruce (MS) zone. Detailed information on wood recruitment, output and storage were obtained from repeated annual surveys. Recruitment from the riparian zone was found to dominate wood inputs, with fluvial import of secondary importance. In undisturbed streams, wood exhumation was found to be of tertiary importance, but was not observed in disturbed streams. Relative wood length was found to be a strong predictor of wood stability, with wood length to channel width and wood diameter to channel depth ratios of 1:1 forming an approximate maximum threshold of wood mobility. Volumetric decomposition was, on average, a third of the value of fluvial export, and the average residence time of wood in the channels was 20 years. In undisturbed reaches, wood storage indicated a slow depletion of wood from the channels. In the disturbed reaches, wildfire was found to significantly increase annual wood recruitment by more than an order of magnitude over undisturbed or control streams. MPB had not significantly increased LW recruitment, but is expected to increase over the coming decades. Storage rates at the disturbed streams indicated a net accumulation of wood over the study period. Copyright © 2012 John Wiley & Sons, Ltd.     

Composition and properties of glacigenic sediments in the southwestern Barents Sea

Abstract

The composition and properties of glacigenic sediments in the southwestern Barents Sea are described based on data from 33 shallow boreholes (< 143 m below seabed) and 11 seabed cores (<4.2m below seabed). The cores are tied into a regional seismostratigraphic framework, illustrating the relationships between different boreholes.

A massive, muddy diamicton (silty, sandy clay with scattered gravel) is found in nearly all cores. Average clay content (<2 pm) of this lithology is about 38%, but varies between about 25% and 50%. Short intervals of finely laminated, waterlain sediments or gravelly sand are cored in a few occasions. A high content of sand and gravel in the cores from near the Norwegian coast shows an influence of sediment input from the mainland, while material eroded from sedimentary rocks dominates farther offshore.

The data presented on physical properties include undisturbed and remolded undrained shear strength, natural water content, bulk density, compressional sound velocity (P waves), Atterberg consistency limits, effective preconsolidation pressure, and consolidation coefficient.

Prediction of overconsolidation from seismic mapping of erosional surfaces is confirmed by the borehole cores. High compaction is found both in Weichselian and older deposits, with a general increase in compaction toward the east as well as toward shallower water. Cores that are “underconsolidated” at their present burial depth are also reported.

The average compressional sound velocity is about 1780 m/s for the borehole cores, 1550 m/s for the seabed cores, and increases with increasing shear strength and consolidation. Both horizontal and vertical sound velocities are measured in several cores, and although the data have a considerable scatter, a slightly aniso‐tropic sound velocity is indicated.     

Long-term landscape development of the Coloradofjella plateau, central Spitsbergen, Svalbard

The development and age of the present geomorphology and superficial material of the Coloradofjella plateau, Spitsbergen, have been investigated through field surveying and laboratory sediment analyses. The focus was specifically on the role of glacial erosion and periglacial processes. The summit plain is deeply incised with large V-shaped valleys. Extensive networks of ice wedge polygons indicate that the fine-grained regolith is at least a few metres thick. An abundance of coarse-grained gabbroid erratics, clearly derived from sources further to the east, are distributed over parts of the summit plain. A vertical-walled dolerite dyke protruding up to 4 m above the adjacent surface shows no sign of glacial erosion. Our findings confirm that the present bedrock geomorphology and regolith in the summit plain survived at least the Late Weichselian glaciation. This is best explained by the ice sheet having been cold-based throughout its existence on the summit plain. Cold-based conditions imply that permafrost survived the last glacial cover. Based on the geomorphic evidence and estimates of Late Cenozoic erosion, we suggest that the present summit plains roughly represent the remains of a preglacial surface.     

Why are offices where they are? The search for factors determining the location of company headquarters

Cases are presented which illustrate three differenct ways in which the locations of corporate headquarters were established. The office is in a particular city or urban center because 1) the firm was founded there, the founder apparently making no assesment of the advantages of the place in comparison with other places, 2) the palce was considered the most appropriate for manufacturing or for some other operative activity, or 3) it met the requirements of the specific activities of the head office. Factors influencing the selection of head office locations are suggested, as well as factors conserving the locational pattern of such offices, i.e. obstacles to moves.     

Stability,morphology and surface grain size patterns of channel bifurcation in gravel–cobble bedded anabranching rivers

This study presents the first detailed field‐based analysis of the morphology of bifurcations within anabranching cobble–gravel rivers. Bifurcations divide the flow of water and sediment into downstream anabranches, thereby influencing the characteristics of the anabranches and the longevity of river islands. The history, morphology, bed grain size, and flow vectors at five bifurcations on the Renous River, New Brunswick, Canada, were studied in detail. The angles of bifurcations within five anabranching rivers in the Miramichi basin were investigated. The average bifurcation angle was 47°, within the range of values cited for braided river bifurcations. Bifurcation angle decreased when anabranches were of similar length. Shields stresses in channels upstream of bifurcations were lower than reported values for braided rivers. Stable bifurcations displayed lower Shields stresses than unstable bifurcations, contrary to experimental results from braided river bifurcations. Bifurcations in anabranching rivers are stabilized by vegetation that slows channel migration and helps to maintain a uniform upstream flow field. The morphology of stable bifurcations enhances their stability. A large bar, shaped like a shallow ramp that increases in elevation to floodplain level, forms at stable bifurcations. Floodplains at stable bifurcations accrete upstream at rates between 0·9 and 2·5 m a^?1. Bars may also form within the entrance of an anabranch downstream of the bifurcation node. These bars are associated with bifurcation instability, forming after a period of stability or an avulsion. Channel abandonment occurs when a bar completely blocks the entrance to one anabranch. The stability of channels upstream of bifurcations and the location of bars at bifurcations influence bifurcation stability and the maintenance of river anabranching in the long term. Copyright © 2006 John Wiley & Sons, Ltd.     

Benthic trophic status and nutrient fluxes in shallow-water sediments

Proliferation of fast-growing ephemeral macroalgae in shallow-water embayments constitutes a large-scale environmental change of coastal marine ecosystems. Since inorganic nutrients essential for the initiation and maintenance of macroalgal growth may be supplied from the underlying sediment, we investigated the coupling between benthic inorganic nutrient (mainly N and P) fluxes and sediment properties in 6 bays representing a wide gradient of sediment characteristics (grain size, organic matter content, solid phase C and N). The initial characterization of bays was made in June and also included measurements of oxygen flux and microphytobenthic and macrofaunal biomass. In September, still within the growth season of the macroalgae, complementary experiments with sediment-water incubations for benthic flux measurements of oxygen and nutrients focused on trophic status (balance between auto- and heterotrophy) as a controlling factor for rates of measured benthic nutrient fluxes. Generally, sediments rendered autotrophic by microphytobenthic photosynthesis removed nutrients from the overlying water, while heterotrophic sediments supplied nutrients to the overlying bottom water. Estimations of the green-algal nutrient demand suggested that late in the growth season, net heterotrophic sediments could cover 20% of the N-demand and 70% of the P demand. As the benthic trophic status is a functional variable more closely coupled to nutrient fluxes than the comparably conservative structural parameter organic matter content, we suggest that the trophic status is a more viable parameter to classify sediments and predict benthic nutrient fluxes in shallow-water environments.     

A Simple Model for the Vertical Transport of Reactive Species in the Convective Atmospheric Boundary Layer

We have developed a simple, steady-state, one-dimensional second-order closure model to obtain continuous profiles of turbulent fluxes and mean concentrations of non-conserved scalars in a convective boundary layer without shear. As a basic tool we first set up a model for conserved species with standard parameterizations. This leads to formulations for profiles of the turbulent diffusivity and the ratio of temperature-scalar covariance to the flux of the passive scalar. The model is then extended to solving, in terms of profiles of mean concentrations and fluxes, the NO _x –O₃ triad problem. The chemical reactions involve one first-order reaction, the destruction of NO₂ with decay time τ, and one second-order reaction, the destruction of NO and O₃ with the reaction constant k. Since the fluxes of the sum concentrations of NO _x = NO + NO₂ and O₃ + NO₂ turn out to be constant throughout the boundary layer, the problem reduces to solving two differential equations for the concentration and the flux of NO₂. The boundary conditions are the three surface fluxes and the fluxes at the top of the boundary layer, the last obtained from the entrainment velocity, and the concentration differences between the free troposphere and the top of the boundary layer. The equations are solved in a dimensionless form by using 1/(kτ) as the concentration unit, the depth h of the boundary layer as the length unit, the convective velocity scale w _* as the velocity unit, and the surface temperature flux divided by w _* as the temperature unit. Special care has been devoted to the inclusion of the scalar–scalar covariance between the concentrations of O₃ and NO. Sample calculations show that the fluxes of the reactive species deviate significantly from those of non-reactive species. Further, the diffusivities, defined by minus the flux divided by the concentration gradient may become negative for reactive species in contrast to those of non-reactive species, which in the present model are never negative.