First application of MC2-AQ to multiscale air quality modelling over Europe

A three-dimensional air quality model (MC2-AQ) developed for studying oxidant chemistry on regional to urban scales over North America was adapted and implemented for European conditions. The modelling system is based on the Canadian Mesoscale Compressible Community (MC2) Model, a non-hydrostatic meteorological model, to which modules permitting on-line calculations of chemical transformations, anthropogenic and biogenic emissions, and deposition were added. The transport of chemical species is done on the same grid and with the same advection, convection, and diffusion schemes as are used for the meteorological fields. The developed model is highly flexible and was adapted to different scales by allowing for self-nesting. In this paper we present model results for a high-ozone episode, June 18–26, 2000, over Europe. The modelling system was able to reproduce general characteristics (growth, extent, and dissipation) of the pollution episode. Accumulation of ozone precursors during weak wind and high-temperature synoptic conditions was essential for episode formation. Subsequent episode development and advancement across Europe was driven by frontal systems. A stationary front associated with a low-pressure system over Ukraine prevented the further eastward transport of the polluted air mass. The episode was terminated after the passage of a cold front advecting relatively clean Atlantic air mass.     

Numerical investigation into the application of response conditioned waves for long-term nonlinear fatigue analyses of rigid hulls

Previous studies of response conditioned wave methods have been focused on their applicability to the prediction of extreme nonlinear wave-induced load effects. The results showed that theses methods can be used to accurately and efficiently predict the nonlinear short-term probability distributions for rigid hull responses. This has led us to investigate how response conditioned wave methods can be used for long-term nonlinear fatigue analyses, and with which accuracy this can be done. In this paper we present the results from our investigation. The studies were performed using a container vessel with a length between perpendiculars of 281 m. Calculations were done with a nonlinear strip theory method in which the hull of the vessel was assumed to be rigid. The most likely response wave (MLRW) method was used to condition the waves. Only head seas were considered. We found that the MLRW method under-predicted the long-term fatigue damage by 3%. The method, however, required a simulation time that was approximately three orders of magnitude less than that required for a conventional long-term nonlinear analysis based on random irregular waves. A preliminary investigation showed that due to lacking springing and whipping contributions the MLRW method under-predicted the fatigue damage for a flexible hull by approximately 50%. Several comments about a more accurate extension of the proposed method to flexible hulls are included.     

Analysis of Vertical Turbulent Heat Flux Limit in Stable Conditions with a Local Equilibrium, Turbulence Closure Model

Assuming that the vertical turbulent heat flux vanishes at extremely stable conditions, one should expect its maximal absolute value to occur somewhere at moderate stability, between a neutral and extremely stable equilibrium. Consequently, in some situations duality of solutions may be encountered (e.g. two different values of temperature difference associated with the same values of heat flux and wind speed). A quantitative analysis of this feature with a local equilibrium Reynolds-stress model is presented. The fixed-wind / fixed-shear maximum has been identified both in the bulk and in single-point flux–gradient relationships (that is, in the vertical temperature gradient and wind-shear parameter domain). The value of the Richardson number corresponding to this maximum is derived from the model equations. To study the possible feedback in strongly stable conditions, weak and intense cooling scenarios have been simulated with a one-dimensional numerical, high-resolution atmospheric boundary-layer model. Despite the rapid cooling, flow decoupling at the surface has not been observed; instead, a stability-limited heat flux is maintained, with a gradual increase of the Richardson number towards the top of the turbulent layer, with some signs of oscillatory behaviour at intermediate heights. Vertical changes of wind shear and the Brunt–Väisälä frequency display a remarkably non-monotonic character, with some signs of a gradually developing instability.     

Surface-Layer Flux–Gradient Relationships over Inclined Terrain Derived from a Local Equilibrium,Turbulence Closure Model

Derivation of surface-layer flux–gradient relationships from a local-equilibrium, turbulence-closure model for a forced flow over inclined terrain is presented. Results are shown as a generalization of Monin–Obukhov universal functions respesenting non-dimensional wind and temperature gradients.     

Arctic catchment as a sensitive indicator of the environmental changes: distribution and migration of metals (Svalbard)

Arctic regions experience metal pollution, despite their remote location, and the distribution and migration of those metals determine their potential impact on the local environment. Here, a High-Arctic catchment (Revelva, Svalbard) located remotely from human-induced pollution sources is studied with respect to the distribution and migration of chosen trace elements (Ag, Al, As, B, Ba, Bi, Ca, Cd, Co, Cr, Cu, Cs, Mo, Ni, Pb, Sb, Se, Sr, Tl, U, V and Zn) in surface waters. The metal concentrations fluctuated in 2010–2012 between 0.01 and 354 μg L^?1, the highest mean-weighted concentration noted for Sr (42.5 μg L^?1). The concentrations in the river water were likely influenced by both natural and human-activity-related processes. These factors can produce substances of the same chemical composition (e.g. carbon dioxide, sulphur dioxide and metals may be emitted both by a volcanic eruption and by industrial sources). Therefore, chemometric techniques were used in the current paper to distinguish the multiple sources of pollution in the Revelva catchment. The authors were seeking to determine whether there is indeed evidence for contamination, sufficient to cause environmental damage in polar region. As a result, it was shown that the long-range transport could play an important role in shaping the metal concentration profile of this Arctic tundra environment, capturing both the influence of volcanic eruptions within the region and the human activity in a range of distances from the study site.     

Mellor-Yamada simplified second-order closure models: Analysis and application of the generalized von Karman local similarity hypothesis

Mellor-Yamada's superequilibrium Level 2 and Level 1 models are analyzed using the Monin-Obukhov theory framework. Yamada's (1975) analysis is supplemented by a discussion of the realizability requirements posed on model constants and by the inclusion of the master-length scale problem. The generalized von Kármán local similarity hypothesis (Laikhtman, 1979) is examined as an alternative closure hypothesis for second-order models. A systematic method of model examination is used. First, a family of models, consisting of Level 1 and Level 2 Reynolds-stress equation sets and different length-scale hypotheses (Prandtl's, generalized von Kármán's), is built. Next, asymptotic characteristics of individual models are investigated and compared with similarity predictions. Monin-Obukhov universal functions for turbulent energy, space scale and temperature variance, derived from the models, are compared with experimental surface-layer data. Generally, models employing the stability-dependent generalized von Karman hypothesis perform better than those that use the conventional Prandtl mixing-length concept. The choice amongst the von Kármán type models is still ambiguous. However, the Level 1 model with a stability-dependent generalized von Kármán length scale seems to be the best of those considered.