A simplified automated chelometric method for the determination of sulfate in interstitial water and seawater

A method is described for the determination of sulfate in interstitial water and seawater. After BaSO₄ precipitation, the Ba²⁺ excess is titrated with EDTA using an amalgated silver electrode for end-point detection. An accuracy better than 0.5% is obtained using this method.     

东秦岭石窑沟斑岩钼矿床地质特征及辉钼矿Re-Os年龄

在东秦岭钼成矿带最近探明的石窑沟大型钼矿床位于近东西向马超营断裂带与北东向石窑沟-焦园断裂带的交汇部位,获得钼金属储量10余万吨,平均品位0.068%。钼矿化呈细脉-网脉状分布于花岗斑岩体及其围岩熊耳群火山岩中,与矿化有关的围岩蚀变有钾长石化、硅化、绢云母化、黄铁矿化等,具有斑岩型钼矿床的一些基本特点。在矿床中选取5件不同矿化类型的辉钼矿样品,采用ICP-MS法进行Re-Os同位素定年,获得模式年龄131.3±2.4～134.3±2.6Ma,等时线年龄135.2±1.8Ma(MSWD=0.18),形成于早白垩世,与豫西熊耳山地区雷门沟、鱼池岭等钼矿床形成时代相近。据辉钼矿Re含量(8.242×10-6～30.24×10-6)推测,矿床成矿物质主要来自于下地壳。矿床为东秦岭-大别山地区中生代第三期钼成矿作用产物,形成于早白垩世中国东部岩石圈伸展环境。     

Contribution à l'étude du pH et de la saturation en calcite dans l'estuaire du St‐Laurent (Canada)

Résumé

Des données analytiques récentes sur l'alcalinité des carbonates et le calcium dissous dans l'estuaire moyen du St‐Laurent nous ont permis d'appliquer un modèle thermodynamique simple au calcul du pH et de la concentration en ions carbonate dissous. Ces calculs montrent que le pH varie de façon non linéaire en fonction de la salinité et que le principal facteur de variabilité est la fluctuation de l'apport en carbone inorganique des eaux douces selon la saison. D'autre part le calcul de la concentration en ions carbonate dissous montre que le phénomène de sursaturation des eaux estuariennes en calcite apparaît toujours pour des chlorinités supérieures à 14.5‰, et se trouve pratiquement indépendant de la saison étudiée.     

Self-generated aperiodic behaviour in a simple climate model

Climatic variability arising from the coupling between ocean temperature and sea-ice extent is studied in a spatially distributed system. A spatial degree of freedom is crudely introduced by the coupling, through energy transfer, of two box models each of which describes a different space region. The evolution equations are cast into a normal form and some qualitative features of this general class of models are predicted. It is shown, both analytically and numerically, that internally generated complexity in the form of aperiodic behaviour can be a natural consequence of spatially distributed systems.     

Narrowing gaps between research and policy development in climate change adaptation work in the water resources and agriculture sectors of Cambodia

Narrowing research and policy, while challenging, is especially important in climate change adaptation work (CCA) due to the high uncertainties involved in planning for climate change. This article aims to seek stakeholders’ opinions regarding how research and policy development can be bridged within the Cambodian water resources and agriculture sectors. The study used institutional ethnography methods with informants from government organizations, local academia, and development partners (DPs). This article identifies a number of challenges, and barriers for narrowing research–policy development gaps, including: limited effectiveness of governmental policies and planning; lack of relevant information required to promote evidence-based planning and policy development; and communication barriers. Evidence-based planning is valued by government officials most when there is actual and effective implementation of policies and plans. In practice, this often implies that governmental policies and plans need be scoped and scaled down to meet the available budget, and thus be achievable. In the long term, it also means building the capacity for policy-relevant research on climate change adaptation within Cambodia. Engaging policy stakeholders in research process for co-producing adaptation knowledge, and introducing knowledge intermediaries are suggested by informants as means to narrowing gaps between research and policy development. The presence of the Cambodia's Prime Minister in research–policy dialogues is recommended as important for attracting the attention of high-level policy makers.

Policy relevance

As a least developed and highly climate-vulnerable country, Cambodia has received climate change funding to implement a number of climate adaptation initiatives. Cambodia is likely to receive more climate change finance in the future. This article aims to assist evidence-based planning, in particular, through policy-relevant research on CCA, so that resources for adaptation in Cambodia are used effectively and efficiently. This research also directly benefits the sustainable development of the country.     

ESR isochron dating analyses at Bau de l'Aubesier,Provence, France: Clues to U uptake in fossil teeth

At Bau de l'Aubesier, Provence, Mousterian artifacts and human teeth occur in inhomogeneous (“lumpy”) sedimentary deposits that include bone and tooth fragments and extensive burnt horizons. Electron spin resonance (ESR) isochron analyses of mammal teeth, which use multiple subsamples with different U concentrations, can measure the external dose rate experienced by the tooth regardless of reworking and sedimentary dose rate changes. Isochron analyses do depend on the U uptake model assumed, but can also identify teeth that have experienced secondary U uptake or leaching. Using 11 teeth from six archaeological layers, the isochrons demonstrate that at least three teeth have experienced secondary uptake. For eight teeth, the U uptake has apparently not followed strictly early (EU), linear (LU), or recent uptake (RU), but more closely approximates LU‐RU. Comparing volumetrically averaged sedimentary geochemistry with thermoluminescent dosimetry suggests that fossil tissues in the sediment have also experienced LU‐RU uptake. LU‐RU uptake can explain standard ESR ages that underestimate the true fossil age. © 2001 John Wiley & Sons, Inc.     

Relationship between point rainfall, average sampled rainfall and ground truth at the event scale in the Sahel

Geostatistical techniques are used to quantify the reference mean areal rainfall (ground truth) from sparse raingaugenetworks. Based on the EPSAT-Niger event cumulative rainfall, a linear relationship between the ground truth considered as the mean area rainfall estimated from the densely available raingauge network and the area rainfall estimated from sparse network are derived. Also, a linear relationship between the ground truth and point rainfall is established. As it was reported experimentally by some authors, the slope of these relationships is less than one. Based on the geostatistical framework, the slope and the ordinate at the origin can be estimated as a function of the spatial structure of the rainfall process. It is shown that the slope is smaller than one. For the special case of one gauge inside a fixed area or a Field Of View (FOV), an areal reduction factor is derived. It has a limit value which depends only on the size of the area and the spatial structure of the rainfall process. The relative variance error of estimating the FOV cumulative rainfall from point rainfall is also given.     

松辽盆地徐家围子营城组流纹岩地球化学特征及构造指示意义

松辽盆地徐家围子营城组发育一套以流纹岩为主的中酸性火山岩。岩石薄片观察和主量、微量元素研究发现,后期热液蚀变、区域埋深及低温水合作用对流纹岩的Si、K、Rb等元素含量产生一定影响; 流纹岩明显富集Rb、Th、U、Pb等强不相容元素,Ba、Sr、Ti、Eu、P 负异常,暗示其经历了斜长石、磷灰石和钛铁矿分离结晶作用。流纹岩的(⁸⁷Sr/⁸⁶Sr)_i(0.705265 ~ 0.711895)值变化范围较大,大多数ε_Nd(t)为正值(1.83 ~ 3.38),Pb同位素比值相对集中,(²⁰⁶Pb/²⁰⁴Pb)_i=18.09～18.32,(²⁰⁷Pb/²⁰⁴Pb)_i=15.50 ~ 15.54,(²⁰⁸Pb/²⁰⁴Pb)_i=37.80 ~ 38.10。研究表明,岩石的源区为大比例年轻成分与少量古老地壳的混合部分熔融,其演化过程中经历了不同程度的地壳混染。松辽盆地早白垩世火山岩为板内伸展环境喷发的产物,可能与太平洋板块俯冲导致的中国东部岩石圈减薄、软流圈上涌密切相关。