Particulate matter geochemistry of a highly industrialized region in the Caribbean:Basis for future toxicological studies

Air pollution has become an important issue,especially in Caribbean urban areas,and,particulate matter(PM)emitted by different natural and anthropogenic sources causes environmental and health issues.In this work,we studied the concentrations of PM₁₀ and PM_2.5 sources in an industrial and port urban area in the Caribbean region of Colombia.PM samples were collected within 48-h periods between April and October 2018 by using a Partisol 2000 i-D sampler.Elemental geochemical characterization was performed by X-ray fluorescence(XRF)analysis.Further,ionic species and black carbon(BC)were quantified by ion chromatography and reflectance spectroscopy,respectively.Using the Positive Matrix Factorization(PMF)receptor model,the contributions of PM sources were quantified.The average concentration of PM₁₀ was 46.6±16.2μg/m³,with high concentrations of Cl and Ca.For PM_2.5,the average concentration was 12.0±3.2μg/m³,and the most abundant components were BC,S,and Cl.The receptor model identified five sources for PM₁₀ and PM_2.5.For both fractions,the contributions of marine sea spray,re-suspended soil,and vehicular traffic were observed.In addition,PM_2.5 included two mixed sources were found to be fuel oil combustion with fertilizer industry emissions,and secondary aerosol sources with building construction emissions.Further,PM₁₀ was found to also include building construction emissions with re-suspended soil,and metallurgical industry emissions.These obtained geochemical atmospheric results are important for the implementation of strategies for the continuous improvement of the air quality of the Caribbean region.     

Land use and land cover dynamics in Leiria City: relation between peri-urbanization processes and hydro-geomorphologic disasters

Natural Hazards - The objective of the present study is to evaluate the relation between the spatial and temporal dynamics of Land Use and Land Cover (LULC) and the hydro-geomorphological processes...     

Measurement of runoff and soil loss from two differently sized plots in a subtropical environment (Brazil)

Studies of soil erosion on small plots present upscaling problems. The results in the literature on the effect of slope length (i.e. scale) on runoff and soil erosion are contradictory. Furthermore, most studies that examine scale effects measured through erosion plots have been conducted in Mediterranean environments. The objective of this study was to assess the effects of plot size on runoff and soil loss in a subtropical environment. Other measurements were taken to appraise the topsoil property changes inside the plots. The soil was ploughed twice, the surface was leveled with a hoe and it was kept bare during the experiment. Data were collected from 10 paired plots, five plots measuring 10 m × 1 m and five plots measuring 1 m × 1 m, installed in the same pedo‐geomorphologic unit. Measurements were carried out from November 2008 to November 2009. During this period, 97 natural storms were registered. The results indicate that the small plots tended to have higher runoff (30% higher) compared to larger plots, especially during periods of greater rainfall volume, duration and intensity. The soil loss was similar in both the 1 m² plots (6·33 kg/m²) and the 10 m² plots (6·26 kg/m²). Moreover, the dynamics of the soil loss during the experiment was relatively similar across both plot sizes. The large plots tended to have a greater internal complexity. In these plots, the steps retreat were higher, the overland flow scars were more frequent, and points of rill initiation and protochannels emerged in several parts of the plots. The results of the small plots were comparable to the results obtained on the large plots, especially in relation to soil loss. These plots were useful for short‐term assessments of soil erosion. Copyright © 2011 John Wiley & Sons, Ltd.     

The role of snow melting upon landslides in the central Argentinean Andes

This paper focuses on the historical range of variability of landslide activity and its relation to climate in the Aconcagua Park, Argentina. Landslide frequency data are obtained through historic compilation, including the review of more than 85 data sources and personal interviews with members of the local community. Based on these records, the study analyzes major landslide triggering mechanisms and evaluates the role of climate. Slope instability in Aconcagua Park appears to be mainly forced by the melting of snow accumulated during the winter season, which in turn promotes soil saturation and landslide occurrence the following spring–summer (December–February). This finding is supported by a strong correlation between landslides and stream flows of Andean rivers. These peaks occur during warmer seasons, fed by snow and ice‐glacier melting. In contrast, the correlation between landslide frequency and precipitation (diary/accumulative/monthly/annual) is less certain; and the relationship of landslide to temperature records (mean annual temperature/mean temperature during November–February period) is weak. Copyright © 2012 John Wiley & Sons, Ltd.     

Soil discrimination using diffuse reflectance Vis–NIR spectroscopy in a local toposequence

Vis–NIR spectroscopy is nowadays presented as a possible routine method for soil sample analysis. However, there is still no consensus on which is the best multivariate statistical method to use. We propose to use principal component analysis to complete the spectral data treatment. The soil samples came from a pedological cover made up of red–yellow Latosols: 88 samples of 11 soil profiles on four toposequences were collected; clay, organic matter, silica, iron, aluminum and titanium total contents were determined; the contents of goethite, hematite, gibbsite, and kaolinite were calculated. Diffuse reflectance Vis–NIR spectroscopy at wavelengths from 400 to 2400 nm combined with principal component analysis (PCA) was sufficiently sensitive to discriminate different Latosols. Wavelengths of 700 nm and 2200 to 2300 nm were influenced by content ratios of organic matter and iron oxides (700 nm), and kaolinite and gibbsite absorption (2200 and 2300 nm). The spectral responses were affected not only by the content of these constituents, but also by the composition of the minerals, so that the same class of Latosol may have different or similar spectral responses. The role of microaggregation is discussed.     

Analyzing the commercial activities of a street network by ranking their nodes: a case study in Murcia,Spain

Urban researchers and planners are often interested in understanding how economic activities are distributed in urban regions, what forces influence their special pattern and how urban structure and functions are mutually dependent. In this paper, we want to show how an algorithm for ranking the nodes in a network can be used to understand and visualize certain commercial activities of a city. The first part of the method consists of collecting real information about different types of commercial activities at each location in the urban network of the city of Murcia, Spain. Four clearly differentiated commercial activities are studied, such as restaurants and bars, shops, banks and supermarkets or department stores, but obviously we can study other. The information collected is then quantified by means of a data matrix, which is used as the basis for the implementation of a PageRank algorithm which produces a ranking of all the nodes in the network, according to their significance within it. Finally, we visualize the resulting classification using a colour scale that helps us to represent the business network.     

Recent variations of supraglacial lakes on the Baltoro Glacier in the central Karakoram Himalaya and its possible teleconnections with the pacific decadal oscillation

This study discusses the formation and variations of supraglacial lakes on the Baltoro glacier system in the central Karakoram Himalaya during the last four decades. We mapped supraglacial lakes on the Baltoro Glacier from 1978 to 2014 using Landsat MSS, TM, ETM + and LCDM images. Most of the glacial lakes were formed or expanded during the late 1970s–2008. After 2008, the total number and the area of glacial lakes were found to be lesser compared to previous years. We tried to find any teleconnections exists between the glacial lake changes in this region and the pacific decadal oscillation (PDO), which entered its prolonged warm regime in the late 1970s and again to its cold regime in 2008, based on observational investigation. The decrease in the number and area of the supraglacial lakes after 2008 is hypothesised to be linked with the recent cold phase of PDO.     

Carbon and nitrogen stable isotopes in coastal benthic populations under multiple organic enrichment sources

In a dispersive coastal area under multiple organic enrichment sources, stable isotopes were used to trace organic sources of carbon and nitrogen in sediments and benthic macrofauna. The Bivalve Abra alba and the Polychaetes Nephtys sp. and Pectinaria (Lagis) koreni were reliable indicators of the input of terrestrial-derived organic matter into this coastal area, either originated in outfall sewage discharges or estuarine outflow. An isotopic depletion was observed up to 250 m from the outfall branches, much stronger in the biota than in the sediments. An enrichment of 2‰ in the sediments, and 2-6‰ in the species was noticed in sites located farther than 1500 m from the outfall. Depositivores and carnivores/omnivores gave the best picture of the extension of the sewage dispersion and incorporation into the food web.