Measuring and modelling temporal trends of 226Ra in waters of a Spanish estuary affected by the phosphate industry

The presence and temporal evolution (1990-2001) of (226)Ra in a tidal estuary affected by the phosphate industry has been investigated. Water samples collected in the course of four separate sampling campaigns were analysed for (226)Ra content using a gas flow proportional counter following Ba coprecipitation. Two (226)Ra sources have been identified: direct discharges from the industrial complex and run-off from a phosphogypsum pile. Although activity levels are similar, or even higher, than those found in other environments affected by the phosphate industry, there has been a general decrease in contamination since direct discharges ceased in 1998 due to new regulations from the EU. However, sediments are now acting as a source of Ra to the water column due to redissolution processes. A numerical model of the estuary has been developed to describe quantitatively the experimental results. The model solves the hydrodynamics and the dispersion equation of (226)Ra including interactions with sediments. Model results are, in general, in good agreement with observations.     

Simulation of green water flow on deck using non-linear dam breaking theory

Experiments carried out with models of floating production, storage and offloading platforms (FPSOs) showed that the flow of water over the deck edge, onto the deck resembled a suddenly released wall of water rather than a breaking wave. Therefore green water flow onto the deck was simulated using dam breaking theory, but the theory’s shallow-water assumptions may be limiting. In this paper a non-linear dam breaking problem is formulated. Equations of motion in the Lagrangian form are used and the solution is sought as an infinite series in time. Comparisons with the shallow water approximation are carried out.     

Evidence of NW extension of the North Anatolian Fault Zone in the Marmara Sea: a new interpretation of the Marmara Sea (Izmit) earthquake on 17 August 1999

Active faults aligning in NW–SE direction and forming flower structures of strike-slip faults were observed in shallow seismic data from the shelf offshore of Avcılar in the northern Marmara Sea. By following the parallel drainage pattern and scarps, these faults were traced as NW–SE-directed lineaments in the morphology of the northern onshore sector of the Marmara Sea (eastern Thrace Peninsula). Right-lateral displacements in two watersheds of drainage and on the coast of the Marmara Sea and Black Sea are associated with these lineaments. This right-lateral displacement along the course of these faults suggests a new, active strike-slip fault zone located at the NW extension of the northern boundary fault of the ?ınarcık Basin in the Marmara Sea. This new fault zone is interpreted as the NW extension of the northern branch of the North Anatolian Fault Zone (NAFZ), extending from the ?ınarcık Basin of the Marmara Sea to the Black Sea coast of the Thrace Peninsula, and passing through B üy ük ?ekmece and K ü ? ük ?ekmece lagoons. These data suggest that the rupture of the 17 August 1999 earthquake in the NAFZ may have extended through Avcılar. Indeed, Avcılar and İzmit, both located on the Marmara Sea coast along the rupture route, were strongly struck by the earthquake whereas the settlements between Avcılar and İzmit were much less affected. Therefore, this interpretation can explain the extraordinary damage in Avcılar, based on the newly discovered rupture of the NAFZ in the Marmara Sea. However, this suggestion needs to be confirmed by further seismological studies.     

About the relationship between acoustic fields and hydrological fields in the area of a mesoscale eddy in the Black Sea

This paper discusses the application of acoustic sounding with the purpose of identifying vortical features in the sea. Analysis of the results of a multidisciplinary acoustic/hydrological experiment conducted in the Black Sea has revealed a stable recurrent correlation between the amplitudinal variance of echo signals, on the one hand, and the peculiarities of water temperature fields, on the other. Given these characteristics, the peripheral and the central areas of a mesoscale eddy essentially differed. This allows us to apply acoustic sounding to identify mesoscale eddies in the sea. Translated by Vladimir A. Puchkin.     

On the sulphur chemistry of a super-anoxic fjord, Framvaren, South Norway

The concentrations of total carbonate (C_t), sulphate, sulphide, thiols and oxygen, the ratio between the stable sulphur isotopes ³⁴S and ³²S in sulphate and sulphide, and the density (used to calculate salinity) were determined on samples from the water column of Framvaren, a superanoxic fjord in southern Norway. From a depth of 18m (the oxic-anoxic boundary) the initial sulphate concentration, ([SO₄]_init), as calculated from salinity, is significantly higher than the sum of the measured sulphur species. This is attributed to a loss of sulphur from the water column. The amount of total carbonate produced, corrected for the initial concentration (C_t - 2.4 Sal/35) is found to be proportional to the amount of sulphate consumed, ([SO₄]_init - [SO₄]), according to the following relation C_t- 2.4 Sal/35 = 1.84 ([SO₄]_init - [SO₄]). Isotopic fractionation caused by bacterial sulphate reduction in the anoxic part of the water column produces sulphide with a δ³⁴S 40‰ lower than the δ³⁴S for sulphate at corresponding depths. The isotopic fractionation also results in δ³⁴S value for the remaining sulphate at depths below 80 m being considerably higher than the mean value for ocean water, which is close to + 20‰. The δ³⁴S values for sulphate at depths between 10 and 50 m were lower than + 20‰ which indicates oxidation of sulphide, which follows upon diffusion of sulphide from deeper parts of the water column and inflow of oxygenated seawater over the sill into the anoxic water of the fjord. A conclusive scenario of the Framvaren sulphur chemistry is presented.     

Fractal Dimension and Fractals in Ocean Engineering

- This paper discusses the application of fractal dimension and fractals in ocean engineering. To handle some ocean environment problems, the existing fractal method, in which the fractal dimension is a constant, can be used. For some complicated problems in ocean engineering, this paper presents the concept of the variable dimension fractals (D = f(r)), i. e., the fractal dimension D is the function of characteristic scale r instead of a constant. By using variable dimension fractals, several deformation and stress states of offshore structures are described.     

A case study of a modified gravity type cage and mooring system using numerical and physical models

A modified gravity-type cage, developed by SADCO Shelf Ltd., was examined using numerical and physical models to determine if the cage and mooring system is suitable for an exposed site south of the Isles of Shoals, NH. The 3000-m/sup 3/ SADCO Shelf Submersible Fish Cage has angled stays between the upper framework and the ballasted bottom rim (in addition to net) to resist the horizontal shear deformation. The mooring system consists of three legs-each made up of a taut vertical chain and an angled rope, both leading to deadweight anchors. Normalized response amplitudes (response amplitude operators) were found for motion response in heave, surge and pitch, and load response in the anchor and bridle lines, in regular (single frequency) waves. In addition, a stochastic approach was taken to determine the motion and load transfer functions in random waves using a spectrum representative of seas at the selected site. In general, the system motion had a highly damped response, with no resonant peaks within the wave excitation range of 0.05 to 0.45 Hz. The anchor line force response was at all frequencies below 5 kN per meter of wave amplitude. The physical model tests showed consistently more conservative (larger) results compared to those for the numerical model.     

An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

Atmospheric forcing of the eastern tropical Pacific: A review

The increase in marine, land surface, atmospheric and satellite data during recent decades has led to an improved understanding of the air–sea interaction processes in the eastern tropical Pacific. This is also thanks to extensive diagnoses from conceptual and coupled ocean–atmosphere numerical models. In this paper, mean fields of atmospheric variables, such as incoming solar radiation, sea level pressure, winds, wind stress curl, precipitation, evaporation, and surface energy fluxes, are derived from global atmospheric data sets in order to examine the dominant features of the low level atmospheric circulations of the region. The seasonal march of the atmospheric circulations is presented to depict the role of radiative forcing on atmospheric perturbations, especially those dominating the atmosphere at low levels.In the tropics, the trade winds constitute an important north–south energy and moisture exchange mechanism (as part of the low level branch of the Hadley circulation), that determines to a large extent the precipitation distribution in the region, i.e., that associated with the Inter-Tropical Convergence Zone (ITCZ). Monsoonal circulations also play an important role in determining the warm season precipitation distribution over the eastern tropical Pacific through a large variety of air–sea–land interaction mechanisms. Westward traveling waves, tropical cyclones, low latitude cold air intrusions, and other synoptic and mesoscale perturbations associated with the ITCZ are also important elements that modulate the annual rainfall cycle. The low-level jets of the Gulf of California, the Intra-Americas Sea (Gulf of Mexico and Caribbean Sea) and Chocó, Colombia are prominent features of the eastern tropical Pacific low-level circulations related to sub-regional and regional scale precipitation patterns. Observations show that the Intra-Americas Low-Level Jet intensity varies with El Niño/Southern Oscillation (ENSO) phases, however its origin and role in the westward propagation and development of disturbances that may hit the eastern tropical Pacific, such as easterly waves and tropical cyclones, are still unclear. Changes in the intensity of the trade winds in the Caribbean Sea and the Gulf of Mexico (associated with eastern tropical Pacific wind jets) exert an important control on precipitation by means of wind–topography interactions. Gaps in the mountains of southern Mexico and Central America allow strong wind jets to pass over the continent imprinting a unique signal in sea surface temperatures and ocean dynamics of the eastern tropical Pacific.The warm pools of the Americas constitute an important source of moisture for the North American Monsoon System. The northeastern tropical Pacific is a region of intense cyclogenetic activity, just west of the coast of Mesoamerica. Over the oceanic regions, large-scale properties of key variables such as precipitation, moisture, surface energy fluxes and wind stress curl are still uncertain, which inhibits a more comprehensive view of the region and stresses the importance of regional field experiments. Progress has been substantial in the understanding of the ocean and atmospheric dynamics of the eastern tropical Pacific, however, recent observational evidence such as that of a shallow meridional circulation cell in that region, in contrast to the classic concept of the Hadley-type deep meridional circulation, suggests that more in situ observations to validate theories are still necessary.This paper is part of a comprehensive review of the oceanography of the eastern tropical Pacific Ocean.