The junction of Fensch and Moselle rivers,France; mineralogy and composition of river materials

The Moselle river flows in the north-east of France, from Vosges Mountains to neighboring countries Luxembourg and Germany. One of its tributaries, the Fensch river, drains a highly industrialized watershed, strongly impacted by mining, smelting and surfacing activities. The objective of this work, part of a general research program on Moselle watershed (Zone Atelier Moselle) was to assess the impact of the polluted Fensch river on the global quality of the Moselle river. For that purpose, water, sediments and suspended particulate matter were sampled in both rivers, upstream and downstream the junction. Four main sampling campaigns were carried out, in winter during a flood event and in spring at low water level. On a first step, mineralogical analyses (XRD and FTIR) and chemical analyses (ICP-MS, ICP-AES), were performed on sediments, suspended particulate matters and filtered waters. Major and trace elements concentrations were obtained on two different granulometric fractions (0–2 mm and 0–50 μm) revealing the enrichment in heavy metals of fine particles. From one collecting campaign to another, seasonal variations could be evidenced on suspended matter composition even though major minerals (calcite, quartz and kaolinite) were always present. Furthermore, spatial variations were evidenced for Fensch and Moselle downstream sediments. Thus, very fine-grained sediments, poorly crystallized, displaying at the same time higher metal concentrations and higher organic matter content than in Fensch river material, were collected downstream, in a low hydrodynamic conditions zone, assumed as a preferential sedimentary zone or even as a placer. Strong correlations could be revealed between iron content and contaminant concentrations, confirming the origin of polluted material.     

Garnet reequilibration and growth in the eclogite facies and geodynamical evolution near peak metamorphic conditions

Caledonian eclogite-facies metamorphism partially reworking Grenvillian granulite-facies anorthosite allows us to study the processes of garnet reequilibration at high pressure and to reconstruct the evolution of the unit near metamorphic peak conditions. Our results indicate that eclogite-facies metamorphism happened in two successive phases: first, inherited granulitic garnet was fractured and reequilibrated from their boundaries (crystal or fracture rims); then eclogite-facies minerals were crystallised in the fractures as overgrowths on inherited garnets. The reequilibration of inherited garnets is achieved through Fe²⁺Mg⁻¹ exchange, whereas eclogite-facies garnets crystallised during the subsequent phase are notably richer in Ca than un- and re-equilibrated granulitic garnet. Pseudosection construction shows that this lack in Ca reequilibration cannot be related to variations in thermodynamic conditions (a _H2O, reacting system composition) between the two phases. From the compilation of the available data, the reequilibration of granulitic garnet seems to be controlled by the inefficient intra- and inter-granular transport properties of Ca compared to Fe²⁺ and Mg. While these kinetic factors confine garnet reequilibration to Fe²⁺Mg⁻¹ exchange, the extent of reequilibration along this exchange vector is controlled by partitioning with adjacent omphacite. On the contrary to the diffusional reequilibration of granulitic garnet that lasted for several My according to our modelling of the diffusional relaxation, the strong compositional gradients between eclogite-facies and reequilibrated garnets, which are almost unaffected by diffusional reequilibration, provide evidence that rapid exhumation followed the crystallisation of eclogite-facies minerals. We propose that the movement reversal itself, from burial to exhumation, and associated deformation and fluid flow, triggered this crystallisation event. The resulting evolution near metamorphic peak conditions is therefore strongly asymmetrical: on the one hand, the prograde diffusional relaxation profiles indicate slow movement during the last stages of burial, whereas the unaffected retrograde overgrowth indicates fast exhumation rates.     

Response of littoral chironomid communities and organic matter to late glacial lake—level,vegetation and climate changes at Lago dell’Accesa (Tuscany,Italy)

This study focuses on the response of lacustrine littoral chironomid communities to late glacial changes in limnological, environmental and climate conditions in the Mediterranean context. Late glacial chironomid (Diptera: Chironomidae) assemblages, organic petrography and geochemistry were analysed in a sediment core from the littoral zone of Lago dell’Accesa (Tuscany, Italy), where the lake-level fluctuations and the vegetation history have been previously reconstructed. Comparison of the chironomid stratigraphy to other proxies (pollen assemblages, organic petrography and geochemistry, lake-level) and regional climate reconstruction suggested the predominant influence of lake-level changes on the littoral chironomid fauna. The main lowering events that occurred during the Oldest and the Younger Dryas were followed by higher proportions of taxa typical of littoral habitats. A complementary study of organic matter suggested the indirect impact of lake-level on the chironomids through changes in humic status and habitat characteristics, such as the type of substrate and aquatic macrophyte development. Several chironomid taxa, such as Glyptotendipes, Microtendipes and Cricotopus type patens, were identified as possible indicators of low lake-level in the late glacial records. Nevertheless, this study suggested that parallel analyses of organic matter and chironomid assemblages may be needed to circumvent misinterpretation of littoral chironomid assemblage stratigraphy. There was a weak response of the chironomid assemblages to small lake-level lowerings that corresponded to the Older Dryas and Preboreal oscillations. A higher level of determination, e.g. to the species group level, may be necessary to increase the sensibility of the indicators to lake-level changes.     

Origin and stratigraphy of phreatomagmatic deposits at the Pleistocene Sinker Butte Volcano, Western Snake River Plain, Idaho

Sinker Butte is the erosional remnant of a very large basaltic tuff cone of middle Pleistocene age located at the southern edge of the western Snake River Plain. Phreatomagmatic tephras are exposed in complete sections up to 100 m thick in the walls of the Snake River Canyon, creating an unusual opportunity to study the deposits produced by this volcano through its entire sequence of explosive eruptions. The main objectives of the study were to determine the overall evolution of the Sinker Butte volcano while focusing particularly on the tephras produced by its phreatomagmatic eruptions. Toward this end, twenty-three detailed stratigraphic sections ranging from 20 to 100 m thick were examined and measured in canyon walls exposing tephras deposited around 180° of the circumference of the volcano.Three main rock units are recognized in canyon walls at Sinker Butte: a lower sequence composed of numerous thin basaltic lava flows, an intermediate sequence of phreatomagmatic tephras, and a capping sequence of welded basaltic spatter and more lava flows. We subdivide the phreatomagmatic deposits into two main parts, a series of reworked, mostly subaqueously deposited tephras and a more voluminous sequence of overlying subaerial surge and fall deposits. Most of the reworked deposits are gray in color and exhibit features such as channel scour and fill, planar-stratification, high and low angle cross-stratification, trough cross-stratification, and Bouma-turbidite sequences consistent with their being deposited in shallow standing water or in braided streams. The overlying subaerial deposits are commonly brown or orange in color due to palagonitization. They display a wide variety of bedding types and sedimentary structures consistent with deposition by base surges, wet to dry pyroclastic fall events, and water saturated debris flows.Proximal sections through the subaerial tephras exhibit large regressive cross-strata, planar bedding, and bomb sags suggesting deposition by wet base surges and tephra fallout. Medial and distal deposits consist of a thick sequence of well-bedded tephras; however, the cross-stratified base-surge deposits are thinner and interbedded within the fallout deposits. The average wavelength and amplitude of the cross strata continue to decrease with distance from the vent. These bedded surge and fall deposits grade upward into dominantly fall deposits containing 75–95% juvenile vesiculated clasts and localized layers of welded spatter, indicating a greatly reduced water-melt ratio. Overlying these “dryer” deposits are massive tuff breccias that were probably deposited as water saturated debris flows (lahars). The first appearance of rounded river gravels in these massive tuff breccias indicates downward coring of the diatreme and entrainment of country rock from lower in the stratigraphic section. The “wetter” nature of these deposits suggests a renewed source of external water. The massive deposits grade upward into wet fallout tephras and the phreatomagmatic sequence ends with a dry scoria fall deposit overlain by welded spatter and lava flows.Field observations and two new ⁴⁰Ar–³⁹Ar incremental heating dates suggest the succession of lavas and tephra deposits exposed in this part of the Snake River canyon may all have been erupted from a closely related complex of vents at Sinker Butte. We propose that initial eruptions of lava flows built a small shield edifice that dammed or disrupted the flow of the ancestral Snake River. The shift from effusive to explosive eruptions occurred when the surface water or rising ground water gained access to the vent. As the river cut a new channel around the lava dam, water levels dropped and the volcano returned to an effusive style of eruption.     

The Cloud Ice Mountain Experiment (CIME) 1998: experiment overview and modelling of the microphysical processes during the seeding by isentropic gas expansion

The second field campaign of the Cloud Ice Mountain Experiment (CIME) project took place in February 1998 on the mountain Puy de Dôme in the centre of France. The content of residual aerosol particles, of H₂O₂ and NH₃ in cloud droplets was evaluated by evaporating the drops larger than 5 μm in a Counterflow Virtual Impactor (CVI) and by measuring the residual particle concentration and the released gas content. The same trace species were studied behind a round jet impactor for the complementary interstitial aerosol particles smaller than 5 μm diameter. In a second step of experiments, the ambient supercooled cloud was converted to a mixed phase cloud by seeding the cloud with ice particles by the gas release from pressurised gas bottles. A comparison between the physical and chemical characteristics of liquid drops and ice particles allows a study of the fate of the trace constituents during the presence of ice crystals in the cloud.In the present paper, an overview is given of the CIME 98 experiment and the instrumentation deployed. The meteorological situation during the experiment was analysed with the help of a cloud scale model. The microphysics processes and the behaviour of the scavenged aerosol particles before and during seeding are analysed with the detailed microphysical model ExMix. The simulation results agreed well with the observations and confirmed the assumption that the Bergeron–Findeisen process was dominating during seeding and was influencing the partitioning of aerosol particles between drops and ice crystals. The results of the CIME 98 experiment give an insight on microphysical changes, redistribution of aerosol particles and cloud chemistry during the Bergeron–Findeisen process when acting also in natural clouds.     

Grain-size-sensitive flow and shear-stress enhancement at the brittle–ductile transition of the continental crust

Localized shear zones along low-angle normal faults have been identified in regions of extension at the brittle-ductile transition of the continental crust. The possibility of the strain localizing at a depth of 10 km is interpreted here as a consequence of an increase in the equivalent shear stress applied to the flow of the lower crust. This enhancement of the flow stress is seen as a prerequisite for the triggering of brittle deformation mechanisms leading to strain localization. The lower crust rheology used to examine this stress increase is strain-rate, temperature and grain-size dependent, due to the coupling of dislocation and diffusion creep. The model structure proposed consists of a top layer, the upper crust, gliding rigidly above a bottom layer, the lower crust, which deforms in simple shear. During a short time interval (1400 years), the equivalent shear stress is found to increase by a factor of up to 3 (67 MPa for anorthite and 17 MPa for quartz). For anorthite, this stress could explain the activation of a Mohr-Coulomb failure with a friction coefficient of 0.2, which is reasonable at the depth of 10 km. Dislocation creep is activated during a rapid change in the prescribed velocity, whereas diffusion creep dominates if the velocity is held constant, highlighting the importance of grain-size sensitivity for lower crustal rheology.     

A physical model for shear-wave velocity prediction1

The clay-sand mixture model of Xu and White is shown to simulate observed relationships between S-wave velocity (or transit time), porosity and clay content. In general, neither S-wave velocity nor S-wave transit time is a linear function of porosity and clay content. For practical purposes, clay content is approximated by shale volume in well-log applications. In principle, the model can predict S-wave velocity from lithology and any pair of P-wave velocity, porosity and shale volume. Although the predictions should be the same if all measurements are error free, comparison of predictions with laboratory and logging measurements show that predictions using P-wave velocity are the most reliable. The robust relationship between S- and P-wave velocities is due to the fact that both are similarly affected by porosity, clay content and lithology. Moreover, errors in the measured P-wave velocity are normally smaller than those in porosity and shale volume, both of which are subject to errors introduced by imperfect models and imperfect parameters when estimated from logs. Because the model evaluates the bulk and shear moduli of the dry rock frame by a combination of Kuster and Toksöz’ theory and differential effective medium theory, using pore aspect ratios to characterize the compliances of the sand and clay components, the relationship between P- and S-wave velocities is explicit and consistent. Consequently the model sidesteps problems and assumptions that arise from the lack of knowledge of these moduli when applying Gassmann's theory to this relationship, making it a very flexible tool for investigating how the v_P-v_s relationship is affected by lithology, porosity, clay content and water saturation. Numerical results from the model are confirmed by laboratory and logging data and demonstrate, for example, how the presence of gas has a more pronounced effect on P-wave velocity in shaly sands than in less compliant cleaner sandstones.     

A comparative allometric study of the morphometry of the gills of an alkalinity adapted cichlid fish,Oreochromis alcalicus grahami,of Lake Magadi,Kenya

A morphometric analysis of the gills ofOreochromis alcalicus grahami has been carried out on specimens from ecologically distinct lagoons and a water-holding tank of Lake Magadi, a highly alkaline salt lake situated in a volcanically active region of the southern part of the Great Rift Valley in Kenya. The data were compared with those fromOreochromis niloticus, a close relative that lives in fresh water and with data from other fresh water and marine fish. Our primary goal was to identify the possible adaptive features which enable the fish to survive in an environment characterized by severely fluctuating levels of oxygen, a condition exacerbated by factors such as high temperature, alkalinity and osmolarity. The specimens ofO. a. grahami from the south-western lagoons of the lake had gills better adapted for gas exchange with a body mass specific diffusing capacity for oxygen which was about 2 times greater than that of the gills of the specimens from the fish spring lagoons and 2.5 times that of those from the water-holding tanks. Some parameters of the gills ofO. a. grahami, e.g. the gill filament length and number of gill filaments are significantly greater than those ofO. niloticus but the number of secondary lamellae, area of secondary lamellae and the diffusing capacity of the gills are similar in the two species. Compared with most other fish, the gills ofO. a. grahami appear to be particularly well adapted for gas exchange especially by having a thin water-blood barrier. Perhaps in no other extant fish have the gills had to be so exquisitely designed to meet environmental extremes and regulate complex and at times conflicting functions such as gas exchange, iono-regulation, acid-base balance and nitrogenous waste excretion as inO. a. grahami     

Geochemistry of waters in the Valley of Ten Thousand Smokes region, Alaska

Meteoric waters from cold springs and streams outside of the 1912 eruptive deposits filling the Valley of Ten Thousand Smokes (VTTS) and in the upper parts of the two major rivers draining the 1912 deposits have similar chemical trends. Thermal springs issue in the mid-valley area along a 300-m lateral section of ash-flow tuff, and range in temperature from 21 to 29.8°C in early summer and from 15 to 17°C in mid-summer. Concentrations of major and minor chemical constituents in the thermal waters are nearly identical regardless of temperature. Waters in the downvalley parts of the rivers draining the 1912 deposits are mainly mixtures of cold meteoric waters and thermal waters of which the mid-valley thermal spring waters are representative. The weathering reactions of cold waters with the 1912 deposits appear to have stabilized and add only subordinate amounts of chemical constituents to the rivers relative to those contributed by the thermal waters. Isotopic data indicate that the mid-valley thermal spring waters are meteoric, but data is inconclusive regarding the heat source. The thermal waters could be either from a shallow part of a hydrothermal system beneath the 1912 vent region or from an incompletely cooled, welded tuff lens deep in the 1912 ash-flow sheet of the upper River Lethe area.Bicarbonate-sulfate waters resulting from interaction of near-surface waters and the cooling 1953–1968 southwest Trident plug issue from thermal springs south of Katmai Pass and near Mageik Creek, although the Mageik Creek spring waters are from a well-established, more deeply circulating hydrothermal system. Katmai caldera lake waters are a result of acid gases from vigorous drowned fumaroles dissolving in lake waters composed of snowmelt and precipitation.