Ice clathrate as a possible source of the atmospheres of the terrestrial planets

The presence and compositions of atmospheres on the terrestrial planets do not follow directly from condensation models which would have Earth accreting near 500°K. No single mechanism yet proposed adequately accounts for the abundances of noble gases and carbon and nitrogen in the atmospheres. We show that the composition of clathrates forming at low temperatures in cold regions of the nebula can be predicted. Addition of about 1 ppm clathrate material to the Earth can explain observed abundances of Ar, Kr, and Xe. Condensation and adsorption processes occuring at 400–500°K are necessary to explain the observed abundances of Ne, H₂O, C, and N. Possible sources of clathrates could be cometary bodies formed in the outer solar system.     

Chlorophyll modulation of mixed layer thermodynamics in a mixed-layer isopycnal General Circulation Model — An example from Arabian Sea and equatorial Pacific

Western tropical Indian Ocean, Arabian Sea, and the equatorial Pacific are known as regions of intense bio-chemical-physical interactions: the Arabian Sea has the largest phytoplankton bloom with seasonal signal, while the equatorial Pacific bloom is perennial with quasi-permanent upwelling. Here, we studied three dimensional ocean thermodynamics comparing recent ocean observation with ocean general circulation model (OPYC) experiment combined with remotely sensed chlorophyll pigment concentrations from the Coastal Zone Color Scanner (CZCS). Using solar radiation parameterization representing observations that a higher abundance of chlorophyll increases absorption of solar irradiance and heating rate in the upper ocean, we showed that the mixed layer thickness decreases more than they would be under clear water conditions. These changes in the model mixed layer were consistent with Joint Global Ocean Flux Study (JGOFS) observations during the 1994-1995 Arabian Sea experiment and epi-fluorescence microscopy (EFM) on samples collected during Equatorial Pacific Ocean Climate Study (EPOCS) in November, 1988. In the Arabian Sea, as the chlorophyll concentrations peak in October (3 mg/m³) after the summer plankton bloom induced by coastal upwelling, the chlorophyll induced biological heating enhanced the sea surface temperature (SST) by as much as 0.6‡C and sub-layer temperature decreases and sub-layer thickness increases. In the equatorial Pacific, modest concentrations of chlorophyll less than 0.3 mg/m³ is enough to introduce a meridional differential heating, which results in reducing the equatorial mixed layer thickness to more than 20 m. The anomalous meridional tilting of the mixed layer bottom enhances off equatorial westward geostrophic currents. Consequently, the equatorial undercurrent transports more water from west to east. We proposed that these numerical model experiments with use of satellite andin situ ocean observations are consistent under three dimensional ocean circulation theory combined with solar radiation transfer process.     

Data‐driven taxonomy matching of asteroid and meteorite

The matching of asteroids and meteorites is a significant step toward a better understanding of the origin, structure, and history of the solar system. We propose a data‐driven approach for investigating common taxonomic structure between asteroids and meteorites; C‐, S‐, and V‐type for the former, and carbonaceous chondrite, ordinary chondrite, and howardite‐eucrite‐diogenite (HED) meteorite for the latter. In the numerical experiments, by checking whether the taxonomy information of meteorites improves classification for asteroid data, we examine the existence of common structure over the two domains. For this purpose, we compare the resultant accuracies of two clustering methods which are with/without the guidance of meteorite data. We observe that the guidance of meteorite taxonomy improves the accuracy for classifying asteroids, either with the reflectance spectra or major chemical compositions of meteorites. This fact serves as a piece of evidence that there is a common taxonomic structure and links between meteorites and asteroids, supporting a long‐standing hypothesis.     

Trace elements in rims and interiors of Chainpur chondrules

Trace elements were measured in the rims and interiors of nine chondrules separated from the Chainpur LL-3 chondrite. Whole rock samples of Chainpur and samples of separated rims were also measured. Chondrule rims are moderately enriched in siderophile and volatile elements relative to the chondrule interiors. The enriched volatile elements include the lithophilic volatile element Zn. The moderate enrichment of volatiles in chondrule rims and the lack of severe depletion in chondrules can account for the complete volatile inventory in Chainpur. These results support a three-component model of chondrite formation in which metal plus sulfide, chondrules plus rims and matrix silicates are mixed to form chondrites.     

Magnetic petrology of the 1991–1995 dacite lava of Unzen volcano,Japan: Degree of oxidation and implications for the growth of lava domes

To understand the oxidation state and process of oxidation of lava domes, we carried out magnetic petrological analyses of lava samples obtained from domes and block-and-ash-flow deposits associated with the 1991–1995 eruption of Unzen volcano, Japan. As a result, we recognize three different types of magnetic petrology, each related to deuteric high-temperature oxidation during initial cooling. Type A oxides are characterized by homogenous titanomagnetite and titanohematite, indicating a low oxidation state and high titanomagnetite concentrations. Type B oxides are weakly exsolved and contain titanohematite laths and rutile lenses, indicating a higher oxidation state. Type C oxides, which represent the highest oxidation state, are completely exsolved and composed of Ti-poor titanomagnetite, titanohematite, rutile, and pseudobrookite, indicating high hematite concentrations. Some grains in Types A and B show indications of reduction, which was related to interaction with volcanic gases subsequent to high-temperature oxidation. In terms of geological occurrence, the oxidation processes probably differed for endogenous and exogenous domes. Endogenous dome lavas are oxidized concentrically and are classified into the three types according to their location within the dome: samples from the surface are strongly oxidized and classified as Type C, while the inner part is unoxidized and classified as Type A. Exogenous dome lavas are unoxidized and assigned to Type A. Some samples show signs of reduction, which may have occurred around fumaroles. We propose that location within the dome and the process of dome growth are the factors that control oxidation.     

Global synchroneity of a positive carbon isotope excursion at the Cenomanian/Turonian boundary: Validation by calcareous microfossil biostratigraphy of the Yezo Group, Hokkaido, Japan

Abstract Isotopic analyses of organic carbon from the mid-Cretaceous sequence in Hokkaido, Japan, revealed a 2‰ positive excursion of δ¹³C values at the biostratigraphically defined Cenomanian/Turonian (C/T) boundary recognized in the Yezo Group. The planktonic foraminiferal Whiteinella archaeocretacea Zone, which is known to bracket the Cenomanian/Turonian boundary elsewhere in the world, was recognized in the Oyubari area of central Hokkaido based on the distribution of commonly occurring planktonic foraminifera. In the Tappu area of northwestern Hokkaido, where diagnostic planktonic foraminifera are rare but calcareous nannoplankton occur commonly, the interval coeval with the W. archaeocretacea Zone can also be established by recognizing the conjoined last appearance levels of Corollithion kennedyi and Axopodorhabdus albianus, both calcareous nannoplankton species. Carbon isotope profiles exhibit a similar pattern with comparable peaks and troughs occurring in the same stratigraphic position in the sequences. A prominent, positive 2‰ shift of δ¹³C values, here called ‘δ¹³C spike’ occurs in the middle of the W. archaeocretacea Zone in the Oyubari area and just above the conjoined last appearances of the two above-mentioned nannoplankton taxa in the Tappu area. The Cenomanian/Turonian boundary can be drawn just above the peak position of the spike in both sections. The Rock Eval analyses and biomarker analyses of organic carbon indicate that organic carbon subjected to our isotope analyses is of terrestrial origin. Therefore, the observed 2%o shift should reflect changes in the isotopic composition of the atmospheric CO₂. A unique layer composed predominantly of sand-grain sized spumellarian Radiolaria is present immediately above the δ¹³C spike both in the Oyubari and Tappu areas, suggesting an increasing availability of both nutrients and silica in surface waters.     

The non-linear least-squares of condition equations

In this paper the author constructs general algorithms for the non-linear least squares of condition equations and shows the procedure of their application for the settlement of the problem of unfavorable condition equations in the adjustment of a quadrilateral.     

Aluminum-26 in meteorites—VII. Ureilites,their unique radiation history

Cosmogenic ²⁶A1 activities have been measured by γ-γ coincidence counting in the three ureilites which had not previously been studied. The values in dpm/kg are: Dingo Pup Donga, 38.4 ± 2.4; North Haig, 39.3 ± 4.8; Dyalpur, 55.8 ± 4.8. Five of the six known ureilites thus have lower ²⁶A1 contents, 63 per cent to 77 per cent, than the calculated saturation values, in marked contrast to most other stony meteorites. This cannot be attributed to short cosmic ray exposure ages. Nor do size and depth effects account for the narrow range of ²⁶A1 activities, because a nuclear particle track study indicates that preatmospheric radii were highly variable, from ≥ 40 cm for Goalpara to only a few cm for Dingo Pup Donga. By default, the most likely explanation is that the ureilites had much smaller or much larger orbits than all other stony meteorites.