Metamorphic decarbonation, silicate weathering and the long-term carbon cycle

The seawater ⁸⁷Sr/⁸⁶Sr curve implies a 50–100 Myr episodicity in weathering rate which requires a corresponding variation in CO₂ degassing from the solid earth to the atmosphere. It is proposed that this is caused by orogenesis, which both produces CO₂ as a result of metamorphic decarbonation reactions, and consumes extra CO₂ as a consequence of erosion-enhanced weathering. Global climate on the geological time-scale is therefore contTolled by the difference between the relatively large and variable orogenic-moderated degassing and weathering CO₂ fluxes.     

Oil, water, ice and light

The boehaviour and ultimate effect and fate of oil in the marine environment in the polar region depend on a large number of factors. From a chemical point of view the most important ones to consider are the intrinsic chemical properties of the oil, the consequences of oil/water interactions, the influence of ice on physical and chemical processes, and the interactions between oil and light when the influx of solar energy shows great seasonal changes. This paper reviews the main aspects of these issues.     

Obtaining basic simulation data for a heterogeneous field with stratified marine soils

Thinly stratified sedimentary deposits in a heterogeneous field were investigated to obtain basic physical data for the simulation of water flow. A procedure is described which translates a thinly stratified soil profile into a number of functional layers using functional hydrological properties. A functional layer is defined as a combination of one or more soil horizons and should (i) be recognizable during a soil survey using an auger and (ii) show significantly different functional hydrological properties when compared with another functional layer. This procedure gave three easily recognizable functional layers. Sets of hydrological characteristics of these three functional layers were obtained by physical measurements of the soil and by estimation, using textural data for classification into a standard Dutch series. The performance of several combinations of these sets was tested by comparing simulated and measured soil matric potentials for seven plots during one year. The best simulation results were obtained if measured soil hydraulic characteristics were used for relatively homogeneous functional layers and if the soil hydraulic characteristics were estimated at each location for the most heterogeneous layer.     

Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

HYDROLOGIC SERIES CHARACTERISTICSANALYSIS OF THE MAJOR RIVERS AROUNDTHE TAKLIMAKAN DESERT

I.IN~crIOXLocatedinthecoddlepatofTallmBasin,withanareaof33.76X104klnZ,theTaldirnakan~isinthehinterlandofEurasia.Blockedbythehighmountainsaround,vapourofoceancanhardlyreachthedesert.APartfromthis,asthedeSertisinthesinkingcompensationareaoftheascensionalaircurrentaamstheQinghal-XIZangPlateau,itSprecipitationisrareandtheevaporationcapacityisintensealltheyearround.Allthesecontributetotheformationsofthetypifydrydesertclimate.Theacidityindexofthedesertandthearoundregionisashighasmorethan50,w…     

Nutrient (P, N) dynamics in the southwestern Kattegat, Scandinavia: sedimentation and resuspension effects

 The yearly nutrient supply from land and atmosphere to the study area in SW Kattegat is 10 900 tons of N and 365 tons of P. This is only few percent of the supply from adjacent marine areas, as the yearly transport through the study area is 218 000 tons of N and 18 250 tons of P. Yearly net deposition makes up 1340 tons of N (on average 2.5 g m^–2 yr^–1) and 477 ton of P (on average 0.9 g m^–2 yr^–1). Shallow-water parts of the study area have no net deposition because of frequent (>35% of the year) resuspension. Resuspension frequency in deep water is <1% of the year. Resuspension rates, as averages for the study area, are 10–17 times higher than net deposition rates. Because of resuspension, shallow-water sediments are coarse lag deposits with small amounts of organic matter (1.1%) and nutrients (0.04% N and 0.02% P). Deep-water sediments, in contrast, are fine grained with high levels of organic matter (11.7%) and nutrients (0.43% N and 0.15% P). Laboratory studies showed that resuspension changes the diffusive sediment water fluxes of nutrients, oxygen consumption, and penetration into the sediment. Fluxes of dissolved reactive phosphate from sediment to water after resuspension were negative in organic-rich sediments (13.2% organic matter) with low porosity (56) and close to zero in coarse sediments with a low organic matter content (2.3%) and high porosity (73). Fluxes of inorganic N after resuspension were reduced to 70% and 0–20% in relation to the rates before resuspension, respectively. Received: 10 July 1995 · Accepted: 19 January 1996