EPR investigation of the methyl radical,the hydrogen atom and carbon oxide radicals in Maxixe-type beryl

The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1 signal typical for the CH₃ radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g _// = 2.00263, g _⊥ = 2.00249 and A_// = 2.288 mT, A_⊥ = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A ₀ = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g _// = 2.00265, g _⊥ = 2.00625 and A_// = 0.895 mT, A_⊥ = 0.885 mT, could come from a HCO₃ radical. One narrow and easily saturated signal with g _// = 2.00227 and g _⊥ = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g _// = 2.0017 and g _⊥ = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise from a carbon dioxide radical, which rotates around its symmetry axis.     

The Swedish Geotechnical Society’s methodology for risk management: a tool for engineers in their everyday work

The Swedish Geotechnical Society has adopted a general methodology for risk management in geotechnical engineering projects to reduce the costs related to negative outcomes of geotechnical risks. This technical note highlights the main features of the methodology and strives to inspire the international geotechnical community to apply sensible risk management methods. In the authors’ opinion, a successful geotechnical risk management needs to be structured, be tailored to the project, and permeate the engineers’ everyday work. Then, sufficient quality can be achieved in the project with larger probability.     

Nonlinear random wave-induced drag force on a vegetation field

This paper provides a practical method by which the drag force on a vegetation field beneath nonlinear random waves can be estimated. This is achieved by using a simple drag formula together with an empirical drag coefficient given by Mendez et al. (Mendez, F.J., Losada, I.J., Losada, M.A., 1999. Hydrodynamics induced by wind waves in a vegetation field. J. Geophys. Res. 104 (C8), 18383–18396). Effects of nonlinear waves are included by using Stokes second order wave theory where the basic harmonic motion is assumed to be a stationary Gaussian narrow–band random process. An example of calculation is also presented.     

Simulation of normal distributed smooth fields by Karhunen-Loéve expansion in combination with kriging

Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.     

Wave-induced steady streaming,mass transport and net sediment transport in rough turbulent ocean bottom boundary layers

The interaction between two important mechanisms which causes streaming has been investigated by numerical simulations of the seabed boundary layer beneath both sinusoidal waves and Stokes second order waves, as well as horizontally uniform bottom boundary layers with asymmetric forcing. These two mechanisms are streaming caused by turbulence asymmetry in successive wave half-cycles (beneath asymmetric forcing), and streaming caused by the presence of a vertical wave velocity within the seabed boundary layer as earlier explained by Longuet-Higgins. The effect of wave asymmetry, wave length to water depth ratio, and bottom roughness have been investigated for realistic physical situations. The streaming induced sediment dynamics near the ocean bottom has been investigated; both the resulting suspended load and bedload are presented. Finally, the mass transport (wave-averaged Lagrangian velocity) has been studied for a range of wave conditions. The streaming velocities beneath sinusoidal waves (Longuet-Higgins streaming) is always in the direction of wave propagation, while the streaming velocities in horizontally uniform boundary layers with asymmetric forcing are always negative. Thus the effect of asymmetry in second order Stokes waves is either to reduce the streaming velocity in the direction of wave propagation, or, for long waves relative to the water depth, to induce a streaming velocity against the direction of wave propagation. It appears that the Longuet-Higgins streaming decreases as the wave length increases for a given water depth, and the effect of wave asymmetry can dominate, leading to a steady streaming against the wave propagation. Furthermore, the asymmetry of second order Stokes waves reduces the mass transport (wave-averaged Lagrangian velocity) as compared with sinusoidal waves. The boundary layer streaming leads to a wave-averaged transport of suspended sediments and bedload in the direction of wave propagation.     

High‐pressure phase transitions of α‐quartz under nonhydrostatic dynamic conditions: A reconnaissance study at PETRA III

Hypervelocity collisions of solid bodies occur frequently in the solar system and affect rocks by shock waves and dynamic loading. A range of shock metamorphic effects and high‐pressure polymorphs in rock‐forming minerals are known from meteorites and terrestrial impact craters. Here, we investigate the formation of high‐pressure polymorphs of α‐quartz under dynamic and nonhydrostatic conditions and compare these disequilibrium states with those predicted by phase diagrams derived from static experiments under equilibrium conditions. We create highly dynamic conditions utilizing a mDAC and study the phase transformations in α‐quartz in situ by synchrotron powder X‐ray diffraction. Phase transitions of α‐quartz are studied at pressures up to 66.1 and different loading rates. At compression rates between 0.14 and 1.96 GPa s^?1, experiments reveal that α‐quartz is amorphized and partially converted to stishovite between 20.7 GPa and 28.0 GPa. Therefore, coesite is not formed as would be expected from equilibrium conditions. With the increasing compression rate, a slight increase in the transition pressure occurs. The experiments show that dynamic compression causes an instantaneous formation of structures consisting only of SiO₆ octahedra rather than the rearrangement of the SiO₄ tetrahedra to form a coesite. Although shock compression rates are orders of magnitude faster, a similar mechanism could operate in impact events.     

A discrete particle representation of hillslope hydrology: hypothesis testing in reproducing a tracer experiment at Gårdsjön,Sweden

Despite the long history of the continuum equation approach in hydrology, it is not a necessary approach to the formulation of a physically based representation of hillslope hydrology. The Multiple Interacting Pathways (MIPs) model is a discrete realization that allows hillslope response and transport to be simultaneously explored in a way that reflects the potential occurrence of preferential flows and lengths of pathways. The MIPs model uses random particle tracking methods to represent the flow of water within the subsurface alongside velocity distributions that acknowledge preferential flows and transition probability matrices, which control flow pathways. An initial realization of this model is presented here in application to a tracer experiment carried out in Gårdsjön, Sweden. The model is used as an exploratory tool, testing several hypotheses in relation to this experiment. Copyright © 2011 John Wiley & Sons, Ltd.     

Experimental impact cratering: A summary of the major results of the MEMIN research unit

This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.     

Global climate policy and deep decarbonization of energy-intensive industries

If we are to limit global warming to 2 °C, all sectors in all countries must reduce their emissions of GHGs to zero not later than 2060–2080. Zero-emission options have been less explored and are less developed in the energy-intensive basic materials industries than in other sectors. Current climate policies have not yet motivated major efforts to decarbonize this sector, and it has been largely protected from climate policy due to the perceived risks of carbon leakage and a focus on short-term reduction targets to 2020. We argue that the future global climate policy regime must develop along three interlinked and strategic lines to facilitate a deep decarbonization of energy-intensive industries. First, the principle of common but differentiated responsibility must be reinterpreted to allow for a dialogue on fairness and the right to development in relation to industry. Second, a greater focus on the development, deployment and transfer of technology in this sector is called for. Third, the potential conflicts between current free trade regimes and motivated industrial policies for deep decarbonization must be resolved. One way forward is to revisit the idea of sectoral approaches with a broader scope, including not only emission reductions, but recognizing the full complexity of low-carbon transitions in energy-intensive industries. A new approach could engage industrial stakeholders, support technology research, development and demonstration and facilitate deployment through reducing the risk for investors. The Paris Agreement allows the idea of sectoral approaches to be revisited in the interests of reaching our common climate goals.

Policy relevance

Deep decarbonization of energy-intensive industries will be necessary to meet the 2 °C target. This requires major innovation efforts over a long period. Energy-intensive industries face unique challenges from both innovation and technical perspectives due to the large scale of facilities, the character of their global markets and the potentially high mitigation costs. This article addresses these challenges and discusses ways in which the global climate policy framework should be developed after the Paris Agreement to better support transformative change in the energy-intensive industries.