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121.
Government agencies striving to make geospatial information systems interoperable and cost‐effective often appear to function as a self‐regulating network shaped only by internal trust and reciprocity. However, recent public management research suggests that external steering of a network, exercised by authoritative bodies through hierarchical means, may invigorate cross‐agency coordination. The two case studies of federal geospatial coordination in Canada and the USA confirm this emerging theory of network–hierarchy dynamics. In these countries, the central budget agency (CBA) is influencing resource flows and accountabilities within a federal geospatial network of government agencies, which in turn affects how these agencies deliver ‘joined up’ services. The CBA relies upon three types of tools: the shaping of network governing structures, promotion of uptake of new management information systems, and the use of evaluation (scrutiny) to solidify accountabilities of the network. Since these tools cast a shadow of hierarchy upon the network, they may be viewed as counter to the voluntary ethos of networks. However, the case studies suggest that the CBA's actions appear to confer legitimacy to the network—resulting in a seeming contradiction—greater central control, more vigorous, distributed geospatial coordination.  相似文献   
122.
The extent of historical U mining impacts is well documented for the North Cave Hills region of Harding County, South Dakota, USA. While previous studies reported watershed sediment and surface water As and U concentrations up to 90× established background concentrations, it was unclear whether or how localized changes in sediment redox behavior may influence contaminant remobilization. Five pore-water equilibration samplers (peepers) were spatially and temporally deployed within the study area to evaluate seasonal solid–liquid As and U distributions as a function of sediment depth. Pore-water and solid phase As and U concentrations, Fe speciation, Eh and pH were measured to ascertain specific geochemical conditions responsible for As and U remobilization and transport behavior. At a mine overburden sedimentation pond adjacent to the mine sites, high total aqueous As and U concentrations (4920 and 674 μg/L, respectively) were found within surface water during summer sampling; however pond dredging prior to autumn sampling resulted in significantly lower aqueous As and U concentrations (579 and 108 μg/L, respectively); however, both As and U still exceeded regional background concentrations (20 and 18 μg/L, respectively). At a wetlands-dominated deposition zone approximately 2 km downstream of the sedimentation pond, pore-water geochemical conditions varied seasonally. Summer conditions promoted reducing conditions in pore water, resulting in active release of As(III) to the water column. Autumn conditions promoted oxidizing conditions, decreasing pore-water As (Aspw) 5× and increasing Upw 10×. Peak U pore-water concentrations (781 μg/L) were 3.5× greater than determined for the surface water (226 μg/L), and approximately 40× background concentrations. At the Bowman–Haley reservoir backwaters 45 km downstream from the mine sites, As and U pore-water concentrations increased significantly between the summer and autumn deployments, attributed to increased Fe reduction processes. Geochemical modeling suggests solid-phase Fe reduction promotes the liberation of pore-water As and U via suppressing the formation of thioarsenite. Intermittent hydrological processes facilitate As and U transport and deposition throughout the watershed, while biogeochemical-influenced redox changes cycle As and U between pore and surface water within localized environments.  相似文献   
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Abstract— Radar data enable us to estimate an asteroid's near‐surface bulk density, thus providing a joint constraint on near‐surface porosity and solid density. We investigate two different approaches to simplifying this joint constraint: estimating solid densities by assuming uniform porosities for all asteroids; and estimating porosities by assuming uniform mineralogy within each taxonomic class. Methods used to estimate asteroids' near‐surface solid densities from radar data have not previously been calibrated via independent estimates. Recent spacecraft results on the chondritic nature of 433 Eros now permit such a check, and also support porosity estimation for S‐class objects. We use radar albedos and polarization ratios estimated for 36 main‐belt asteroids and nine near‐Earth asteroids to estimate near‐surface solid densities using two methods, one of which is similar to the uncalibrated algorithms used in previous studies, the other of which treats Eros as a calibrator. We also derive porosities for the same sample by assigning solid densities for each taxonomic class in advance. Density‐estimation results obtained for Eros itself are consistent with the uncalibrated method being valid in the mean; those derived for the full sample imply that uncalibrated solid densities are, at most, a few tens of percent too large on average. However, some derived densities are extremely low, whereas most porosity estimates are physically plausible. We discuss the relative merits of these two approaches.  相似文献   
125.
Data from a series of extended analytical sessions using a range of different zircon reference samples have been used to investigate the periodic derivation of abnormal 207Pb/206Pb ages during microbeam analysis%For the Canberra SHRIMP II, this phenomenon probably results from the presence of a signal at mass 204 that is alien to the Pb spectrum; isotopic fractionation is unlikely to be a significant contributor. In contrast, abnormal 207Pb/206Pb ages obtained from SHRIMP I at the same research centre require a different, but as yet unknown explanation. Assessment of the reasons for atypical 207Pb/206Pb measurements and the means of correcting for them should therefore be independently assessed for individual analytical instruments. The use of reference samples with very different ages is an effective way of doing this, because older reference samples are more useful for documenting isotopic fractionation, whereas younger ones are more sensitive indicators of isobaric interference.  相似文献   
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A time-domain formulation is proposed for the transient response analysis of general, three-dimensional structures resting on a homogeneous, elastic halfspace subjected to either external loads or seismic motions. The formulation consists of two parts: (a) the time domain formulation of the soil behaviour and (b) the coupling of the corresponding soil algorithms to the Finite Element Code ANSYS. As far as the structure is concerned, this coupling opens the way for the analysis of non-linear soil–structure interaction. The approach is based on halfspace Green's functions for displacements elicited by Heaviside time-dependent surface point loads. Hence, the spatial discretisation can be confined to the contact area between the foundation and the soil, i.e. no auxiliary grid beyond the foundation as for conventional boundary element formulations is required. The method is applied to analyse the dynamic response of a railway track due to a moving wheel set by demonstrating the influence of ‘through-the-soil coupling’.  相似文献   
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SCAP at UCL     
Mike Bode and Phil Charles present the minutes of the 11th meeting of the Standing Conference of Astronomy Professors on 3 July 2001.  相似文献   
130.
Physiological acclimation, genetic adaptation and genetic differentiation were examined in darter gobies (Gobionellus boleosoma) inhabiting a coastal marsh with a long history of PAH contamination. No acclimation was detected; a 2-week pre-exposure at the polluted site resulted in a decreased rather than an increased resistance in a subsequent laboratory exposure to polluted sediment. Similarly, fish collected from sites with elevated sediment PAH levels did not exhibit an increased resistance in bioassays with polluted sediment, confirming the lack of acclimation and indicating a lack of adaptation to the pollutants. No differences were detected in frequencies of allozyme genotypes when comparing gobies from the polluted area to those from a nearby control site, and overall levels of heterozygosity were similar in the two populations. While lack of UV-induced toxicity in the laboratory exposures could have played a role, at least four other factors may explain the apparent lack of adaptive responses and genetic differences. First, bioavailability of the contaminants to the darter goby could have been low, though other evidence contradicts this. Second, the contaminated marsh contains a large number of different chemicals and acclimation, adaptation and genetic differentiation are expected to be less likely when more contaminants are involved. Third, the hydrocarbon distribution at the contaminated marsh is very patchy, such that fish may avoid exposure to the highly-contaminated sediment. Fourth, gene flow may be sufficiently high in this mobile species to prevent local adaptation.  相似文献   
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