丹江口水库叶绿素a浓度的时空特征及影响因子分析

2017年5月—2019年10月,对"南水北调"中线水源水库——丹江口水库库区水体7个监测位点、0～20 m间4个水层的垂向叶绿素a (Chl.a)浓度与水质因子进行了季度性调查,以期了解不同位点、不同水层Chl.a分布的主要驱动因子.结果表明,丹江口水库各位点营养状态指数(TSI)均为中营养化状态.水体Chl.a浓度具有逐年增加的趋势,且极高值有逐渐增加的趋势.营养盐和Chl.a浓度均存在较大的空间异质性,入库区具有较高的总磷和氨氮浓度,汉江库区具有最高的Chl.a浓度,源头污染源控制和监测仍然是丹江口水库管理的重中之重.不同位点Chl.a浓度的驱动因子存在较大差异,汉江入库和大坝区Chl.a浓度分别受到硝态氮和p H的影响,而出水口大坝位点主要受到了水深、水温和氨氮的影响.丹江入库区Chl.a浓度受到了水深、氨氮、总磷和水温的影响,但丹江库区表现出了与其他生态区较大的区别,其Chl.a浓度主要受到水深和有机质输入的影响.因此,对丹江口水库各位点的管理,应该分不同生态区采取针对性的管理措施.本研究旨在为南水北调中线工程可持续的生态调度提供基础生态数据支持,为完善水库水源地的有效管理提供理论支撑.     

Water quality evaluation in Tidal River reaches of Liaohe River Estuary, China using a revised QUAL2K model

Rivers in the Liaohe River Estuary area have been seriously polluted by discharges of wastewater containing petroleum pollutants and nutrients. In this paper, The Enhanced Stream Water Quality Model (QUAL2K) and its revised model as well as One-dimensional Tide Mean Model (1D model) were applied to predict and assess the water quality of the tidal river reach of the Liaohe River Estuary. Dissolved oxygen (DO), biochemical oxygen demand (BOD₅), ammonia nitrogen (NH₃-N) and total phosphorus (TP) were chosen as water quality indices in the two model simulations. The modelled results show that the major reasons for degraded rivers remain petroleum and non-point source pollution. Tidal water also has a critical effect on the variation of water quality. The sensitivity analysis identifies that flow rate, point load and diffuse load are the most sensitive parameters for the four water quality indices in the revised QUAL2K simulation. Uncertainty analysis based on a Monte Carlo simulation gives the probability distribution of the four water quality indices at two locations (6.50 km and 44.84 km from the river mouth). The statistical outcomes indicate that the observed data fall within the 90% confidence intervals at all sites measured, and show that the revised QUAL2K gives better results in simulating the water quality of a tidal river.     

九州西侧海域129°E断面的流速和温盐结构特征

根据中、日合作黑潮调查研究期间（1987－1993年）在九州西侧海域获得的水文资料，计算了129°E断面的地转流速和流量。着重提出129°E断面北侧存在一支较稳定的西向流；分析这支西向流的去向，指出它是向对马暖流输送黑潮水的重要途径；给出了这支西向流及黑潮通过该断面的流速、流轴、流幅及流量的变化特征。     

中国近海浮游介形类大尺度生态研究 Ⅴ.浮游介形类群落生境地理位置的季节性变迁

综合分析黑潮、南海暖流、黄海冷水团、对马暖流、闽浙沿岸流、粤东沿岸流、季风和径流对中国近海影响的季节性差异,从而导致中国近海浮游介形类的群落生境地理位置随之进行季节性的变迁。本文选择差异甚大的夏、冬两季进行分析。     

鄂尔多斯盆地西南地区上三叠统延长组沉积相及石油地质意义

鄂尔多斯盆地三叠系延长组主要发育东北和西南两大沉积体系,东北的河流三角洲体系已为大量的勘探研究资料所证实,而西南体系因受勘探程度限制,目前研究不够。本文通过最新钻探成果,结合盆地西南部露头资料,确立盆地西南地区三叠系延长组为冲积扇-扇三角洲沉积体系,发育冲积扇、扇三角洲、湖泊（浊积）相。冲积扇以西南缘平凉崆峒山和汭水河剖面为代表,扇三角洲及湖泊（浊积）相为区内钻井剖面所证实。长6-长8为区内主力油层组,地层保存完整,钻探程度相对较高。扇三角洲前缘砂体类型以水下分流河道为主,局部发育河口坝,浊积体以厚层块状为主。长8亚期为扇三角洲前缘亚相最发育期,横向形成自西南向东北延伸的三支前缘砂体带,是石油聚集的重要区带;长7亚期随着湖盆沉降,周边抬升强烈,湖岸较陡,大量发育浊积体系;长6亚期湖退导致扇三角洲再次发育,但规模较长8亚期弱。扇三角洲前缘砂体单层厚度大,砂岩粒度较粗,颗粒分选及物性好,是石油富集的最有利相带。     

反相流动注射催化光度法测定废水中的亚硝酸根

采用反相流动注射技术与催化光度法相结合,用微机化流动注射分析仪准确控制反应时间,优化了实验条件,克服了催化光度法反应时间难以控制引起的方法精密度、准确度不高的弱点,拟定了测定痕量亚硝酸根的流动注射催化光度方法。分析速度第小时20次,NO2^- 质量浓度在0．00－2．00mg/L,回归方程斜率为0．155。方法直接测定电厂测水中NO2^-的结果与Griess法相符合,RSD＜5．0％（n=5）。     

三元插层材料的合成及其在聚丙烯老化中的应用

以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料,以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH),通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌,探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中,制备MgNiFe-LDH/PP复合材料,通过对材料的加速老化测其力学性能,研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明,当Mg2+:Ni2+:Fe3+=2:1:1,反应温度为140℃、陈化时间为24 h时,合成的MgNiFe-LDH为片状,形貌较为规整,颗粒粒径约为2μm;经加速老化后,填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP,当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变,可明显提高PP的抗老化性能。     

Extensive genetic divergence among Diptychus maculatus populations in northwest China

D. maculates is a kind of specialized Schizothoracinae fish has been locally listed as a protected animal in Xinjiang Province,China. Ili River located in north of Tianshan Mountain and Tarim River located in north of Qinghai-Tibetan Plateau were two main distribution areas of this fish. To investigate the genetic diversity and genetic structure of D. maculates,four populations from Tarim River system and two populations from Ili River system were collected in this study. A 570-bp sequence of the control region was obtained for 105 specimens. Twenty-four haplotypes were detected from six populations,only Kunes River population and Kashi River population shared haplotypes with each other. For all the populations examined,the haplotype diversity(h) was 0.904 8±0.012 6,nucleotide diversity(π) was 0.027 9±0.013 9,and the average number of pairwise nucleotide differences(k) was 15.878 3±7.139 1. The analysis of molecular variance(AMOVA) showed that 86.31% of the total genetic variation was apportioned among populations,and the variation within sampled populations was 13.69%. Genetic differences among sampled populations were highly significant. F st statistical test indicated that all populations were significantly divergent from each other(P 0.01). The largest F st value was between Yurungkash River population and Muzat River population,while the smallest F st value was between Kunes River population and Kashi River population. NJ phylogenetic tree of D-loop haplotypes revealed two main clades. The neutrality test and mismatch distribution analysis suggested that the fish had went through a recent population expansion. The uplift of Tianshan Mountain and movement of Qinghai-Tibetan Plateau might contribute to the wide genetic divergence of D. maculates in northwest China.     

Decrepitation Thermometry and Compositions of Fluid Inclusions of the Damoqujia Gold Deposit,Jiaodong Gold Province,China:Implications for Metallogeny and Exploration

The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃(2) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO2-4-K type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl--Na /Ca2 type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS- complex in the HTFS, and Au-Cl- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future.     

赣南营前岩体的年代学、地球化学、Sr-Nd-Hf同位素组成及其地质意义

赣南营前岩体由早期似斑状花岗闪长岩和晚期细粒黑云母花岗岩组成,在前者中普遍发育暗色基性包体。SHRIMP锆石U-Pb测年显示似斑状花岗闪长岩为172.2±3.1Ma,细粒黑云母花岗岩为168±3Ma,包体为167.6±3.3Ma。所有的岩石均为钙碱性系列,稀土元素显示LREE富集,HREE亏损,Eu负异常并不明显的特征,Nb-Ta负异常显示壳源物质的特征。晚期细粒黑云母花岗岩、早期似斑状花岗闪长岩、暗色包体的(87Sr/86Sr)i和εNd(t)值分别为0.70885～0.70965、0.71058～1.46393、0.70788～0.70923和-6.38～-5.31、-6.51～-5.17、-5.47～-4.31;锆石εHf(t)值分别为-12.4～-5.7、-9.2～-4.2、-9.4～+0.1。结合岩相学、地球化学研究,初步认为营前岩体的两期花岗质岩石源于地壳重熔,地幔底侵导致地壳熔融形成营前岩体,基性岩浆加入到未冷却的酸性岩浆中形成了目前所见到的暗色包体。结合区域上的研究资料,认为中侏罗世期间,沿"十杭"断裂带及与其相平行的一些深断裂发生了板块的撕裂,这些缝合带是岩石圈相对薄弱的地带,有利于幔源物质底侵上升以及壳幔相互作用。