Persistent organic pollutants carried by synthetic polymers in the ocean environment

Thermoplastic resin pellets are melted and formed into an enormous number of inexpensive consumer goods, many of which are discarded after a relatively short period of use, dropped haphazardly onto watersheds and then make their way to the ocean where some get ingested by marine life. In 2003 and 2004 pre-production thermoplastic resin pellets and post-consumer plastic fragments were collected and analyzed for contamination for persistent organic pollutants (POPs). Samples were taken from the North Pacific Gyre, and selected sites in California, Hawaii, and from Guadalupe Island, Mexico. The total concentration of PCBs ranged from 27 to 980 ng/g; DDTs from 22 to 7100 ng/g and PAHs from 39 to 1200 ng/g, and aliphatic hydrocarbons from 1.1 to 8600 microg/g. Analytical methods were developed to extract, concentrate and identify POPs that may have accumulated on plastic fragments and plastic pellets. The results of this study confirm that plastic debris is a trap for POPs.     

Esterase activities and lipid peroxidation levels in offshore commercial species of the NW Mediterranean Sea

There is a lack of information on monitoring neurotoxicity in offshore commercial species. To help fill this gap, we sampled hake (Merluccius merluccius) and Norway lobster (Nephrops norvegicus) in fishing grounds off the coast of l’Ametlla de Mar (NW Mediterranean) in June 2005 at a depth of 100 m and 400 m. Additionally, at 400 m depth, two other fish species, Micromesistius poutassou and Phycis blennoides were included. Neurotoxicity markers such as Colinesterases (ChEs), namely acethyl- (AChE), butyryl- (BChE), propionyl- (PrChE) and carboxilesterase (CbE) were measured in muscle. Lipid peroxidation (LP), a marker of oxidative damage, was also included. The results are discussed in relation to the animal’s sex, size and fishing depth. A comparison of esterases and LP levels between muscle and liver of hake and between muscle and hepatopancreas of Norway Lobster was made.

AChE was dominant in muscle and CbE in hepatopancreas. No differences between fish species were seen for AChE. However, N. norvegicus, presented lower levels of ChEs and LP. A size-dependence in ChEs was seen for M. merluccius, with larger animals showing significantly lower activities (p < 0.05). Sex-dependence was seen in N. norvegicus for most esterases, except AChE, with males displaying higher activities (p < 0.05). A sampling-depth effect was also seen in the crustacea, with animals from 100 m generally presenting lower esterase activities and higher LP levels.     

裂变径迹热年代学

裂变径迹热年代学(Fission Track Thermochronology)是近十年发展起来的一门新的地质学分支学科,其研究对象是沉积盆地及其周缘地区的热作用事件,目的在于了解特定范围的生烃史及大地的造演化,为油气勘探和基础地质研究服务。 裂变径迹本来是同位素地质学的一个概念。矿物或岩石中的铀原子(~(238)U)在地质年代中会不断自发产生核裂变,一般可形成两块碎片,朝相反方向辐射,总能量可达162Mev。这种带电的高能质点在快速穿过矿物晶格时,会使邻近原子电离化。这种电离化的正离子在库仑排斥力的作用下,挤向两边的晶格,从而在晶格中留下了线状连续缺损。这就是裂变径迹。60年代中期,裂变径迹技术开始应用于地质年代测定和地球化学研究中,并且很快在铀矿床成因、矿石和岩石形成年代及地热等领域取得了令人满意的效果。     

Effect of adsorbed iron on thermoluminescence and electron spin resonance spectra of Ca-Fe-exchanged montmorillonite

The electron spin resonance (ESR) spectra and the natural and gamma-induced thermoluminescence (TL) glow curves of a series of variably cation-exchanged Fe-Ca-clays prepared from SWy-1 montmorillonite were examined. The ESR signal (g = 2) intensity associated with the surface Fe was found to increase linearly with surface Fe content up to a nominal concentration of 50% exchangeable Fe. At > 50% exchangeable Fe, no appreciable increase in the signal was noted. The TL intensity decreased linearly with increasing surface Fe up to 50% nominal exchangeable Fe. At > 50%, the signal was not appreciably further diminished. The natural TL showed only a high-temperature peak, but irradiation produced an additional low-temperature peak. One month after gamma-irradiation, the integrated TL signal was still 10-100 times higher than that from the non-irradiated material. Thus, (1) surface iron clusters may form above a certain critical Fe concentration; (2) the Fe clusters are probably less effective in quenching TL than are single Fe atoms, implying interaction between surface Fe and the stored energy content of the material; and (3) the electronic energy stored in the material as the result of gamma-irradiation is only slowly dissipated.     

"The Bush is No More": Insights on Institutional Change and Natural Resource Availability in Rural South Africa

The past decade has brought substantial transition to South Africa. The introduction of democracy in 1994 has yielded important political and socioeconomic transformations affecting millions of people. Here, we explore the impact of institutional and structural changes on the availability and management of fuelwood, a key natural resource in rural South Africa. As in other developing regions, many households depend on natural resources for both sustenance and energy needs. Drawing on qualitative data from 32 interviews, our objective is to describe, from the perspective of the respondents, (1) resource scarcity, (2) the underlying causes of resource scarcity, (3) the role of traditional authority in managing resources, and (4) strategies used by community members in the face of resource scarcity. The results have important implications for the well-being of both social and natural systems in many transitional, rural developing societies.