Evolution of melt composition during intrusion of basalts into a silicic magma chamber

The article describes heat exchange between basaltic and rhyolite melts accompanied by fractional crystallization of phases in a basaltic melt. A numerical model has been developed for the homogenization mechanism of magma composition during intrusion of basaltic magma batches into felsic magma chambers. The results of numerical modeling demonstrate that the time needed for cooling the basalts and their fractionation to rhyolite melts is much shorter than the time required for chemical interaction based on diffusive mechanisms.     

Changes of deformational and reservoir properties of arenaceous-argillaceous rocks due to operation of underground gas storage facilities

This paper discusses issues of the decline of the reservoir properties of arenaceous-argillaceous rocks as a result of declining porosity due to long-term operation of underground gas storage facilities. An analysis of the many-year operation of storage facilities, as well as calculation, has revealed that the active capacity of a storage reservoir gradually decreases under certain conditions of underground storage operations. We performed a series of experiments with model specimens in order to support the hypothesis of decreasing reservoir (capacity-filtration) properties because of changes in the value and structure of the pore space. These experiments showed that the cyclic loading and unloading of arenaceous-silty rocks during long-term operation of underground gas storage facilities can significantly decrease the reservoir parameters of reservoirs created within worked out gas-and-gas condensate fields. Laboratory studies of model specimens corresponding to feldspar sandstone in their composition, porosity, and strength proved that porosity considerably decreases in such reservoirs at actually existing values of formation pressure. Tests of sand performed under conditions close to those existing during the development of hydrocarbon fields also showed that their permeability gradually decreases in the process of cyclic changes of effective pressure.     

Silica phase transformations in the petroliferous sequences

The joint evolution of organic matter and silica in petroliferous sequences is considered in the terms of the laws of transformation of dispersion systems. The dispersion systems are transformed under conditions of low-temperature solid-phase processes accompanied by the silica phase transition and dehydration that favors the evolution of organic matter.     

鄂尔多斯盆地西峰地区长8砂岩微观非均质性的实验分析

通过真实砂岩微观模型实验,客观地分析了鄂尔多斯盆地西峰地区长8砂岩的微观非均质性特征,发现该区长8储层为致密型砂岩,直观地显示出长8砂岩储层具有很强的微观非均质性,砂岩的成岩作用和孔隙结构是影响鄂尔多斯盆地西峰地区长8砂岩储层微观非均质性的主要原因。在低渗透砂岩中,引起砂岩产生强烈的非均质性,而这些砂岩则形成长8砂岩储层的高渗带。     

车镇凹陷上古生界高分辨率层序地层研究

以高分辨率层序地层学原理为指导,利用测井、岩芯和录井等资料,对车镇凹陷上古生界不同级次基准面旋回进行了高分辨率层序划分。将上古生界划分为2个超长期、7个长期、16个中期和45个短期基准面旋回,精细对比研究了短期、中期和长期基准面旋回。其中,短期基准面旋回可分为2大类3种亚类,并区别出A型、B型不对称短期基准面旋回和C型对称性短期基准面旋回,总结了它们的结构特征、形成条件、岩性岩相组成;通过研究不同沉积体系下中期、长期基准面旋回特点,得出中期、长期基准面旋回的特点和发育特征,区别出不同沉积环境下层序界面特点;分析了研究区内超长期基准面旋回特征,综合分析认为车镇凹陷超长期基准面旋回以下降半旋回为主。     

准噶尔盆地腹部Z2井三叠系地层及沉积特征

对准噶尔Z2井三叠系各组的岩性、电性特征进行了详细解释与描述,对各组的孢粉、大孢子组合特征展开了讨论,提出了该井三叠系地层划分为自碱滩组、克拉玛依组和百口泉组,且将其与邻区钻遇的三叠系进行了横向及纵向对比。在此基础上,通过对测、录井资料的精细解释,并借鉴前人的区域沉积相研究成果,探讨了该区三叠纪沉积环境。     

土壤中氟的形态分析

以宁夏盐池地区高氟土壤为例,采用连续提取法对土壤样品中各形态氟进行提取,离子色谱法测定各形态氟的含量。根据研究目的及土壤特点将氟的形态划分为水溶态、离子交换态、可还原态、可氧化态及残渣态5种形态;对各种形态连续提取过程中使用的提取液进行了选择。采用建立的方法获得提取土壤中F-的检出限为0.76μg/g;方法精密度(RSD,n=7)各形态氟为水溶态氟11.3%,离子交换态氟13.5%,可还原态氟10.7%,可氧化态氟8.9%。     

多接收器电感耦合等离子体质谱法测定镉标准溶液中镉的同位素组成

建立了多接收器电感耦合等离子体质谱仪对Cd标准溶液同位素组成进行分析的实验方法。仪器的质量分馏校正采用Standard-Sample Bracketing法。实验结果用δ114/110Cd来表达。在此研究基础上,以SPEX Cd标准溶液为参考标准,对国外4种Cd标准溶液进行了测定。结果表明,实验测定的精度在0.07‰~0.13‰(δ114/110Cd),与目前文献报道的结果具有相似的精度。以最新SPEX Cd标准样品(δ114/110Cd=0)为基准,计算的δ114/110CdJMC、δ114/110CdSPEX-1、δ114/110CdBAM1012和δ114/110CdM櫣nster的值分别为0.55‰、0.56‰、-0.65‰和5.14‰,说明不同批次SPEX标准溶液的Cd同位素组成是明显不同的,最新的SPEX Cd标准溶液与SPEX-1 Cd的δ114/110Cd值存在着0.56‰的差别。将以SPEX Cd为参考标准的δ114/110CdBAM1012和δ114/110CdM櫣nster转化为以SPEX-1或JMC为参考标准后,得到的结果与文献报道的结果在误差范围内一致。     

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。     

激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。