Carbon isotope fractionation between graphite and diamond during shock experiments

Abstract— Carbon isotopic compositions were measured for shock‐produced diamond and shocked graphite formed at peak pressures ranging from 37 to 52 GPa. The δ¹³C values of diamonds produced in a sealed container were generally lower than that of the initial graphite. The differences in the carbon isotopic composition between initial graphite and shocked graphite/diamond may reflect kinetic isotopic fractionation during the oxidation of the graphite/diamond and/or analytical artifacts possibly induced by impurities in the samples. The pressure effect on the isotopic fractionations between graphite and diamond can be estimated from the δ¹³C values of impurity‐free diamonds produced using a vented container from which gases, including oxygen, in pore spaces escaped during or after the diamond formation (e.g., 0.039 ± 0.085‰ at a peak pressure of 52 GPa). Any isotopic fractionation induced by shock conversion of graphite to diamond is too small to be detected in natural shock‐induced diamond‐graphite systems related to terrestrial impact cratering processes.     

The equilibrium configuration of rapid rotating compact stars and some gravitational effects

In this paper, the equilibrium configurations of rapid rotating compact stars and some gravitational effects are studied within the general relativity by use of the Harrison-Wheeler equation of state and by the self-consistent field method. Numerical calculations show that the equilibrium configuration of a rotating star is a spheroid. For large spin velocities, say, ω > 3.0 × 10² sec⁻¹ the eccentricity and mass increase very rapidly as the angular velocity increases, for the critical angular velocity of the rotating star, the eccentricity is about 0.7, the increase in mass is about 10–35%. The difference of the gravitational redshifts at the surface of the star caused by rotation, and the difference of the light bending when the beam moves in the direction of rotation or in the opposite direction are obvious.     

Distinct climate change synchronous with Heinrich event one, recorded by stable oxygen and carbon isotopic compositions in stalagmites from China

Uranium-series dating of oxygen and carbon isotope records for stalagmite SJ3 collected in Songjia Cave, central China, shows significant variation in past climate and environment during the period 20-10 ka. Stalagmite SJ3 is located more than 1000 km inland of the coastal Hulu Cave in East China and more than 700 km north of the Dongge Cave in Southwest China and, despite minor differences, displays a clear first-order similarity with the Hulu and Dongge records. The coldest climatic phase since the Last Glacial Maximum, which is associated with the Heinrich Event 1 in the North Atlantic region, was clearly recorded in SJ3 between 17.6 and 14.5 ka, in good agreement in timing, duration and extent with the records from Hulu and Dongge caves and the Greenland ice core. The results indicate that there have been synchronous and significant climatic changes across monsoonal China and strong teleconnections between the North Atlantic and East Asia regions during the period 20-10 ka. This is much different from the Holocene Optimum which shows a time shift of more than several thousands years from southeast coastal to inland China. It is likely that temperature change at northern high latitudes during glacial periods exerts stronger influence on the Asian summer monsoon relative to insolation and appears to be capable of perturbing large-scale atmospheric/oceanic circulation patterns in the Northern Hemisphere and thus monsoonal rainfall and paleovegetation in East Asia. Climatic signals in the North Atlantic region propagate rapidly to East Asia during glacial periods by influencing the winter land-sea temperature contrast in the East Asian monsoon region.     

氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲

采用硝酸-氢氟酸-高氯酸溶解样品,以Fe3+作减缓剂,不需分离富集,用氢化物发生-原子荧光光谱法直接测定地球化学样品中痕量碲。对测定介质、KBH4浓度、铁盐的作用等条件进行试验。方法检出限为0.0031μg/g,精密度(RSD,n=11)<6.10%。方法用于国家一级地球化学标准物质中痕量碲的测定,结果与标准值一致。     

内蒙古敖包吐萤石矿床的Sr、Nd、Pb同位素地球化学特征

敖包吐萤石矿床是内蒙古北部苏莫查干地区单一萤石矿集区中的一个代表性矿床,产于早二叠世大石寨组火山-沉积岩与早白垩世敖包吐花岗岩的接触带上。文章通过分析该矿床岩、矿石的微量元素和稀土元素,揭示出萤石的成矿作用可分为2个阶段,即交代作用和充填作用。交代作用过程中大石寨组的结晶灰岩可能为萤石的形成提供了部分Ca来源,萤石矿石的稀土元素配分模式与海水基本类似,具有Ce负异常;成矿作用后期主要表现为充填作用,形成颗粒粗大的萤石,表现为重稀土元素富集的特征,并随着萤石的沉淀析出,稀土元素总量逐渐下降,反映出成矿流体经历了较长期的演化过程。各地层单元、花岗岩体和萤石矿石的Sr、Nd、Pb同位素研究表明,萤石的放射性同位素组成具有壳、幔源混合的特点,成矿物质来源具有多源性。早白垩世敖包吐花岗岩可能是萤石中F的主要来源,而大石寨组的结晶灰岩则可能提供了Ca。另外,Pb、Nd同位素的极大不均一性,有可能是成矿流体在运移过程中对艾力格庙群放射性组分的选择性吸收的结果。萤石成矿作用与钾玄岩的时空关系暗示了萤石的成矿过程可能是中国东部岩石圈减薄和下地壳的置换地质事件的结果。在构造转型的过程中,燕山中期富碱的酸性花岗岩浆的活动分异出富含F的成矿流体,与幔源流体混合,沿区域重新活化的深大断裂和大石寨组的层间破碎带上升,交代其间的灰岩透镜体,从而形成敖包吐中型萤石矿床。     

邹平王家庄铜矿床成矿地球化学及成因探讨

王家庄铜矿床的矿化脉石英中流体包裹体均一温度介于116 ~ 566 ℃之间,均值为 289 ℃;盐度介于7.2%～63.2% NaCleq,均值为21.1% NaCleq。流体的气相成分主要为H2O和CO2。在均一温度为240 ~ 440 ℃区间内,出现了富气相的两相水溶液包裹体、富液相的两相水溶液包裹体和含子晶的三相水溶液包裹体共存现象,以及加温后富气相包裹体均一到气相和同期富液相包裹体均一到液相的特征,表明成矿流体曾发生过沸腾作用;其中第一次发生于360 ~ 400 ℃,主要形成高温、高盐度含子晶的三相水溶液包裹体和高温、中盐度富液相的两相水溶液包裹体及高温、低盐度富气相的两相水溶液包裹体;第二次发生于240 ~ 320 ℃,主要形成高—中温、高盐度的含子晶的三相水溶液包裹体和高—中温、中盐度富液相的两相水溶液包裹体及高—中温、低盐度富气相的两相水溶液包裹体;之后主要形成富液相的两相水溶液包裹体,具有中低温和中盐度的特征。矿化脉石英中的δ18OH2O介于-1.14‰ ~ 1.79‰之间,均值为0.94‰;δD介于-63.70‰ ~ -56.50‰之间,均值为-59.8‰;说明王家庄铜矿床的成矿流体主要来源于岩浆,后期混入大气降水。矿石矿物的δ34S变化于-8.80‰ ~ -2.80‰之间,均值为-6.33‰。矿石矿物的n(206Pb)/n(204Pb)介于18.1684 ~ 18.3637之间,均值为18.2892;n(207Pb)/n(204Pb)介于155546 ~ 156342之间,均值为155777;n(208Pb)/n(204Pb)介于38.1286 ~ 38.4840之间,均值为38.2780。说明矿石具有贫重硫和富放射性成因铅的特征,硫、铅主要来源于深部,后期可能受到地壳物质或大气降水的混染。     

鉴江河口底泥盐度释放规律研究

底泥盐度释放是河口水资源利用的主要限制因子。本文以鉴江为例,基于野外实测与室内实验,系统分析了鉴江河口底泥盐度及水体氯离子的分布特征;通过振荡、换水及静态等实验。定量研究了河口底泥盐度释放规律。结果表明：（1）潮泛河口底泥盐度主要受上溯潮水的影响。有较为明显的梯度性;（2）底泥盐度释放量在初期较大,随着换水周期的累加,则逐步降低;在同一换水周期。底泥盐度释放强度与其本底盐度浓度成正指数关系;（3）静态释放时间越长,上覆水盐度越大。静置30d。三组样品上覆水的浓度分别达2626mg&#183;L-1、932mg&#183;L-1、533mg&#183;L-1。远远超过用水水质的要求。     

花岗岩残积土水土特征曲线的试验研究

本文采用渗析法测定花岗岩残积土的水土特征曲线,详细介绍了渗析法的试验步骤及注意事项,并对花岗岩残积土的水土特征曲线进行了分析。通过试验得到残积土水土特征曲线,无论是干燥段或是浸湿段,下降都较为平缓。花岗岩残积土的进气值较低,仅为10kPa左右,而土体残余含水量较大,为20%左右,说明花岗岩残积土持水能力较强。文章还对水土特征曲线的滞回圈进行了分析,认为水土特征曲线的滞回圈应该是由多种原因引起的。