THE FREE-WILSON PARADIGM REDUX:SIGNIFICANCE OF THE FREE-WILSON COEFFICIENTS,INSIGNIFICANCE OF COEFFICIENT ‘UNCERTAINTIES’ AND STATISTICAL SINS

The Free-Wilson paradigm is an established and powerful tool for quantitatively relating activity withchemical structure.Current implementations of the paradigm,however,are flawed both conceptually andin execution.As part of an attempt to more fully realize the promise of the paradigm,it was necessaryto examine these limitations in detail.This report introduces a robust,theory-founded Free-Wilson implementation:stepwise principalcomponents regression analysis(SPCRA).SPCRA is computationally superior to previousimplementations but does not in itself correct their conceptual flaws.The development of SPCRA did,however,facilitate derivation of a simple and chemically significantinterpretation of the Free-Wilson structure-activity model.A number of statistical aspects of this modelcommonly misused in previous applications are discussed at length.These discussions provide criticalbackground for the development of an alternative implementation of the Free-Wilson paradigm.     

Stardust impact analogs: Resolving pre‐ and postimpact mineralogy in Stardust Al foils

Abstract– The grains returned by NASA’s Stardust mission from comet 81P/Wild 2 represent a valuable sample set that is significantly advancing our understanding of small solar system bodies. However, the grains were captured via impact at ～6.1 km s^?1 and have experienced pressures and temperatures that caused alteration. To ensure correct interpretations of comet 81P/Wild 2 mineralogy, and therefore preaccretional or parent body processes, an understanding of the effects of capture is required. Using a two‐stage light‐gas gun, we recreated Stardust encounter conditions and generated a series of impact analogs for a range of minerals of cometary relevance into flight spare Al foils. Through analyses of both preimpact projectiles and postimpact analogs by transmission electron microscopy, we explore the impact processes occurring during capture and distinguish between those materials inherent to the impactor and those that are the product of capture. We review existing and present additional data on olivine, diopside, pyrrhotite, and pentlandite. We find that surviving crystalline material is observed in most single grain impactor residues. However, none is found in that of a relatively monodisperse aggregate. A variety of impact‐generated components are observed in all samples. Al incorporation into melt‐derived phases allows differentiation between melt and shock‐induced phases. In single grain impactor residues, impact‐generated phases largely retain original (nonvolatile) major element ratios. We conclude that both surviving and impact‐generated phases in residues of single grain impactors provide valuable information regarding the mineralogy of the impacting grain whilst further studies are required to fully understand aggregate impacts and the role of subgrain interactions during impact.     

THE NATURE AND EXTENT OF A STRATIGRAPHICAL BREAK IN THE CAMBRO-ORDOVICIAN LIMESTONES OF NORTHERN ANHUI,AND ITS BEARING UPON THE SYSTEMATIC CLASSIFICATJON OF THE CAMBRO-ORDOVICIAN STRATA

Those who have followed the historical development of the systematicclassification of the old Palaeozoic rocks in Europe would undoubtedly wellremember how the Ordovician became recognized as a well-defined,independ-     

A PETROGRAPHICAL STUDY OF THE CHINESE AGALMATOLITES

Ⅰ. INTRODUCTION. The most popular Chinese agalmatolites are Shoushanshih (壽山石), Changhuashih (昌化石), Chingtienshih (青田石) and Kwanglushih (廣綠石). They are named after the names of places, as the name Shoushanshih is from     

DATA RELATING TO THE STUDY OF THE PROBLEM OF GLACIATION IN THE LOWER YANGTZE VALLEY

In a commemorable evening—I believe it was in the early part of December, 1933—when I happened to discuss the problem of Pleistocene climate in China with the late Dr. Davidson Black, I informed him, without     

Coordinated observations of two large Leonid meteor fireballs over northern New Mexico,and computer model comparisons

Abstract— This paper describes the coordinated results of several sets of measurements of two Leonid meteor fireballs over northern New Mexico at 1:32 and 3:06 MST, respectively, on the night of 1998 November 17. The measurements included visible band photometry on both events, as well as filtered 5890 Å all-sky images of the Na airglow. Also, for the 3:06 a.m. event, we obtained an infrasound measurement of the hydrodynamic yield. For the 1:32 a.m. event, we obtained a set of visible band charge-coupled device (CCD) camera images of the meteor train for times extending to 30 min after the initial impact. The measurement results have been combined to derive an optical efficiency for the intense early-time optical flash, and the total explosion yields and masses for both of the meteors. We have also done a set of numerical radiation, hydrodynamic, and chemistry computations to investigate the nature and distribution of the long-lasting airglow. We attribute the brightest visible airglow to atomic O 5577 Å line emission, with additional contributions from atomic Na emission and NO₂ chemiluminescence. The near-infrared atmospheric bands of molecular O₂ should be very strong as well. All of the band emissions are expected to show a hollow limb-brightened structure.     

From the editors

正Dear Members of the Editorial Board,Contributors and Friends of EEEV,To commemorate the tenth anniversary of the Wenchuan earthquake disaster,the journal of Earthquake Erngineering and Engineering Vibratiorn will publish special sections with invited papers in 2018.We sincerely appreciate the contributions from the following experts:Professor Akira WADA,and Professor Kuo-Chun CHANG.     

A three‐dimensional transmitting boundary formulated in Cartesian co‐ordinate system for the dynamics of non‐axisymmetric foundations

A three‐dimensional transmitting boundary is formulated in the Cartesian co‐ordinate system. It is developed for the dynamic soil–structure interaction problems of arbitrary shape foundations in laterally heterogeneous strata overlying rigid bedrock. Dynamics of a rectangular rigid surface foundation on a homogeneous stratum is analysed by a hybrid approach in which the finite region including foundation is modelled by the conventional finite element method and the surrounding infinite region by the newly developed transmitting boundary. To demonstrate its strength, the present method is applied to a rectangular foundation in a horizontally heterogeneous ground consisting of two distinct regions divided by and welded along a vertical plane. Copyright © 2000 John Wiley & Sons, Ltd.     

Experimental Investigation and Numerical Analysis to Develop Low-Energy Large-Midwater Trawls

Fuel consumption in fisheries is a primary concern because of its effects on the environment and the costs incurred by fishermen. Many studies have been conducted to reduce the fuel consumption in fishing operations. Fuel consumption due to fishing gear during a fishing operation is generally related to the hydrodynamic resistance on the gear. This means that fuel consumption is proportional to the drag created by the towing speed. Based on numerical methods, this study suggests a new approach to reduce fuel consumption in fisheries. The results of the simulation are in good agreement with those of model experiments. The total as well as partial resistance forces on the gear are calculated by simulation. The simulation results suggest improved materials and gear structure for reducing the hydrodynamic forces on the gear while maintaining gear performance. The method for assessing the gear performance involves measuring the height and width of the net mouth. Furthermore, this study investigates the efficiency of a low-energy trawl from an economic point of view. The findings of this study will be useful in reducing greenhouse gas (GHG) emissions in fishing operations, and thereby contribute toward lowering fishing costs by saving fuel.     

Forward induced seismic hazard assessment: application to a synthetic seismicity catalogue from hydraulic stimulation modelling

The M _w 3.2-induced seismic event in 2006 due to fluid injection at the Basel geothermal site in Switzerland was the starting point for an ongoing discussion in Europe on the potential risk of hydraulic stimulation in general. In particular, further development of mitigation strategies of induced seismic events of economic concern became a hot topic in geosciences and geoengineering. Here, we present a workflow to assess the hazard of induced seismicity in terms of occurrence rate of induced seismic events. The workflow is called Forward Induced Seismic Hazard Assessment (FISHA) as it combines the results of forward hydromechanical-numerical models with methods of time-dependent probabilistic seismic hazard assessment. To exemplify FISHA, we use simulations of four different fluid injection types with various injection parameters, i.e. injection rate, duration and style of injection. The hydromechanical-numerical model applied in this study represents a geothermal reservoir with preexisting fractures where a routine of viscous fluid flow in porous media is implemented from which flow and pressure driven failures of rock matrix and preexisting fractures are simulated, and corresponding seismic moment magnitudes are computed. The resulting synthetic catalogues of induced seismicity, including event location, occurrence time and magnitude, are used to calibrate the magnitude completeness M _c and the parameters a and b of the frequency-magnitude relation. These are used to estimate the time-dependent occurrence rate of induced seismic events for each fluid injection scenario. In contrast to other mitigation strategies that rely on real-time data or already obtained catalogues, we can perform various synthetic experiments with the same initial conditions. Thus, the advantage of FISHA is that it can quantify hazard from numerical experiments and recommend a priori a stimulation type that lowers the occurrence rate of induced seismic events. The FISHA workflow is rather general and not limited to the hydromechanical-numerical model used in this study and can therefore be applied to other fluid injection models.