Effective macroscopic transport parameters between parallel plates with constant concentration boundaries

A macroscopic transport model is developed, following the Taylor shear dispersion analysis procedure, for a 2D laminar shear flow between parallel plates possessing a constant specified concentration. This idealized geometry models flow with contaminant dissolution at pore-scale in a contaminant source zone and flow in a rock fracture with dissolving walls. We upscale a macroscopic transient transport model with effective transport coefficients of mean velocity, macroscopic dispersion, and first-order mass transfer rate. To validate the macroscopic model the mean concentration, covariance, and wall concentration gradient are compared to the results of numerical simulations of the advection–diffusion equation and the Graetz solution. Results indicate that in the presence of local-scale variations and constant concentration boundaries, the upscaled mean velocity and macrodispersion coefficient differ from those of the Taylor–Aris dispersion, and the mass transfer flux described by the first-order mass transfer model is larger than the diffusive mass flux from the constant wall. In addition, the upscaled first-order mass transfer coefficient in the macroscopic model depends only on the plate gap and diffusion coefficient. Therefore, the upscaled first-order mass transfer coefficient is independent of the mean velocity and travel distance, leading to a constant pore-scale Sherwood number of 12. By contrast, the effective Sherwood number determined by the diffusive mass flux is a function of the Peclet number for small Peclet number, and approaches a constant of 10.3 for large Peclet number.     

The Longdendale landslides

Throughout its geomorphological history the South Pennine valley of Longdendale has been especially prone to landsliding and some ten landslide areas have been identified. These prove on analysis to be bedding plane slides with a strong degree of translation but often exhibiting non-circular rotational elements as well. Instability in the lower slopes has often led to cambering and valley bulging so that the slopes become deformed and slump earth flows developed at some sites. Several different types of landslide are examined in detail and by means of pollen analysis the slides are dated from the early postglacial to at least as recently as two thousand years B.P. although it has not yet been possible to decide when these slides started. The causes of sliding are identified, and comments are made upon.

• (a) The location of slip surfaces–which are frequently at the base of the Grindslow Shales above a sandstone aquifer.
• (b) The geomorphic processes which built up high pore-water pressures and steep pressure gradients in the past.
• (c) The effects of sliding on the development of hillslopes in the post-glacial period.

     

Thermodynamics of minerals of variable composition: Andradite-grossularite and pistacite-clinozoisite solid solutions

Exchange-mineral equilibria with Al and Fe³⁺ aqueous chloride solutions (aq.), Andr + AlCl _aq ³ = FeCl _aq ³ + Gros, (1) Psc + AlCl _aq ³ = FeCl _aq ³ + Czo, (2) were studied under the following experimental conditions: 500°;C and 580°;C and 1 and 2 kbar, respectively, with an overall concentration of metals in the aqueous solutions of about 0.5 M and pH 3. The mixing functions of the components in garnet and epidote were calculated from the experimental data. Thermodynamic treatment of experimental evidence for reaction (1) led to the conclusion that, within the accuracy of experiment, garnet in the andradite-grossularite series was an ideal solid solution. However, epidote solid solution markedly departed from the ideal, as was shown by concentration and pressure-temperature (PT) dependencies of Gibbs's molar excess energies and by mixing-volume concentration dependence.     

Developing a large‐scale water‐balance approach to seasonal forecasting: application to the 2012 drought in Britain

Seasonal hydrological forecasts, or outlooks, can potentially provide water managers with estimates of river flows and water resources for a lead time of several months ahead. An experimental modelling tool for national hydrological outlooks has been developed which combines a hydrological model estimate of sub‐surface water storage across Britain with a range of seasonal rainfall forecasts to provide estimates of area‐wide hydrological conditions up to a few months ahead. The link is made between a deficit in sub‐surface water storage and a requirement for additional rainfall over subsequent months to enable sub‐surface water storage and river flow to return to mean monthly values. The new scheme is assessed over a recent period which includes the termination of the drought that affected much of Britain in the first few months of 2012. An illustration is provided of its use to obtain return‐period estimates of the ‘rainfall required’ to ease drought conditions; these are well in excess of 200 years for several regions of the country, for termination within a month of 1 April 2012, and still exceed 40 years for termination within three months. National maps of sub‐surface water storage anomaly show for the first time the current spatial variability of drought severity. They can also be used to provide an indication of how a drought situation might develop in the next few months given a range of possible future rainfall scenarios. © 2013 CEH/Crown and John Wiley & Sons, Ltd.     

Der Tagesgang von Temperatur und Luftfeuchtigkeit in San Salvador

Zusammenfassung Der Tagesgang von Temperatur und Luftfeuchtigkeit in San Salvador zeigt deutliche jahreszeitliche Verschiedenheiten, die wesentlich durch Strahlungsgenuss, Sonnenauf- und Untergangszeiten und ein tageszeitliches mittelräumiges Windsystem bestimmt ist.

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Summary The daily variation of air temperature and humidity shows clear seasonal differences, which are essentially determined by incoming radiation, sunrise and sunset and a diurnal meso-scale wind system.

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Resumen El transcurso diurno de la temperatura y de la humedad del ambiente en San Salvador demuestra netamente diferencias segun la estación del año, las cuales se deben a las condiciones de radiación, salida y puesta del sol y un sistema diurno de viento.

     

Age and source material of the Kingash ultramafic-mafic massif,East Sayan

The REE distribution patterns and Nd whole-rock and mineral isotope ratios of the Kingash ultramafic-mafic massif enabled us to propose a multistage history for its evolution at 1410 and 875 Ma. These stages reflect the magmatic evolution of the Siberian paleocontinent margin during the Late Precambrian. The age of metamorphism of the massif during collision and accretion in the Early Paleozoic (∼500 Ma) was obtained based on a Sm-Nd mineral isochron from rheomorphic veined albitite. The Nd and Sr isotopic compositions of rocks from the Kingash massif suggest mantle sources for picritic and basic magmas, which are thought to have originated by mixing of different proportions of depleted (PREMA or DM) and enriched (EM) melts. The initial isotope ratios of the parental melts transformed during interaction with Sr-rich material from the host metasedimentary complexes.     

PRELIMINARY NOTE ON THE GRANULOMETRIC ANALYSIS OF SEDIMENTARY ROCKS

The observation that the results of line and point counting analyses of the particle size distribution of the same sand are different leads to the conclusion that these results are biased by the sampling technique¹. The influence of the currently used sampling techniques on the numerical results of a particle size analysis is discussed. Evidence is presented to show that the use of line and point counting methods in granulometric analysis leads to results in which the influence of the sampling method is so strong that the practical value of these techniques is doubtful. It is therefore considered advisable to discontinue line and point counting techniques in granulometric analysis in favour of ribbon sampling methods.     

Estimating water balance components of tropical wetland lakes in the Pantanal dry season,Brazil

Abstract

Water balance studies with stable water isotopes have rarely been conducted in remote and tropical wetland areas. As such, little is known regarding the water balance and groundwater–surface water interaction in the Pantanal, one of the largest and most pristine wetlands in the world. We applied MINA TrêS, a water balance model utilizing stable water isotopes (δ¹⁸O, δ²H) and chloride (Cl^-) to assess the dry-season hydrological processes controlling groundwater–surface water interactions and the water balance of six floodplain lakes in the northern Pantanal, Brazil. Qualitatively, all lakes exhibited similarity in hydrological controls. Quantitatively, they differed significantly due to morphological differences in controlling groundwater inflow and lake volume. Our approach is readily transferable to other remote and tropical wetland systems with minimal data input requirements, which is useful in regions with sparse hydrometric monitoring.

Editor Z.W. Kundzewicz     

Structural and stratigraphical constraints on the kinematics history of the Southern Tan–Lu Fault Zone during the Mesozoic Anhui Province, China

The Tan–Lu Fault Zone (TLFZ) extends in a NNE–SSW direction for more than 2000 km in Eastern China. It has been considered either as a major sinistral strike-slip fault, as a suture zone or as a normal fault. We have conducted a structural analysis of the southern segment of this fault zone (STLFZ) in the Anhui Province. The ages (Triassic to Palaeocene) of the formations affected by the faults have been re-appraised taking into account recent stratigraphical studies to better constraint the ages of the successive stages of the kinematics of the STLFZ. Subsequently, the kinematics of the faults is presented in terms of strain/stress fields by inversion of the striated fault set data. Finally, the data are discussed in the light of the results obtained by previous workers.We propose the following history of the STLFZ kinematics during the Mesozoic. At the time of collision, a  NNE orientated Tan–Lu margin probably connected two margins located north of the Dabie and Sulu collision belts. During the Middle–Late Triassic, the SCB has been obliquely subducted below the NCB along this margin which has acted as a compressional transfer zone between the Dabie and Sulu continental subduction zones. The STLFZ has been initiated during the Early Jurassic and has acted as a sinistral transform fault during the Jurassic, following which the NCB/SCB collision stopped. A  NW-trending extension related to metamorphic domes was active during the basal Early Cretaceous ( 135–130 Ma); it has been followed by a NW–SE compression and a NE–SW tension during the middle–late Early Cretaceous ( 127 to  105 Ma, possibly  95 Ma); at that time the TLFZ was a sinistral transcurrent fault within the eastern part of the Asian continent. During the Late Cretaceous–Palaeocene, the STLFZ was a normal fault zone under a WNW–ESE tension.     

Studies of temperature effects of dust storms

We studied the temperature variations of the lower air layer caused by dust content using a dust storm in Dushanbe in November 2007 as an example. Quantitative estimates of air cooling and a decrease in the diurnal temperature difference due to a diminishing horizontal visibility range are given. Observations of air temperature variations due to the dust content of the atmosphere in an arid zone are presented. The critical value of aerosol concentration for toggling between the greenhouse and antigreenhouse effects is determined. The long-term effect of dust aerosol on climate is analyzed.