Effects of Lime‐Based Waste Materials on Immobilization and Phytoavailability of Cadmium and Lead in Contaminated Soil

Low cost lime‐based waste materials have recently been used to immobilize metals in contaminated soils. This study was conducted to evaluate the effects of oyster shells and eggshells as lime‐based waste materials on immobilization of cadmium (Cd) and lead (Pb) in contaminated soil, as well as their effects on metal availability to maize plants (Zea mays L.). Oyster shells and eggshells were applied to soils at 1 and 5% w/w, after which they were subject to 420 days of incubation. The toxicity characteristic leaching procedure (TCLP) test was employed to determine the mobility of Cd and Pb in soils. The results showed that the addition of waste materials effectively reduced the metal mobility as indicated by the decrease in the concentration of TCLP‐extractable Cd and Pb, and this was mainly due to significant increases in soil pH (from 6.74 in untreated soil to 7.85–8.13 in treated soil). A sequential extraction indicated that the addition of such alkaline wastes induced a significant decline in the concentration of Cd in the exchangeable fraction (from 23.64% in untreated soil to 1.90–3.81% in treated soil), but it increased the concentration of Cd in the carbonate fraction (from 19.59% in untreated soil to 36.66–46.36% in treated soil). In the case of Pb, the exchangeable fraction was also reduced (from 0.67% in untreated soil to 0.00–0.01% in treated soil), and the fraction of Pb bound to carbonate was slightly increased (from 16.61% in untreated soil to 16.41–18.25% in treated soil). Phytoavailability tests indicated that the metal concentrations in the shoots of maize plant were reduced by 63.39–77.29% for Cd and by 47.34–75.95% for Pb in the amended soils, with no significant differences being observed for the amendment types and the application rates. Overall, these results indicate that oyster shells and eggshells can be used as low cost lime‐based amendments for immobilizing Cd and Pb in contaminated soils.     

Analytical and experimental studies on midstory isolated buildings with modal coupling effect

In a midstory isolated building, the isolation system is incorporated into the midstory rather than the base of the building. Because of the flexibility of the substructure below the isolation system in a midstory isolated building, the contribution of higher modes to the seismic responses of the midstory isolated structure may not be negligible, especially when the coupling of higher modes exists. To investigate this modal coupling effect, a simplified three‐lumped‐mass structural model of the midstory isolated building is assumed in this study. Through the equivalent linear analysis and shaking table tests, it is found that the coupling of higher modes may lead to enlarged acceleration responses at the super‐floor and superstructure above the isolation layer. Accordingly, a simple method to prevent the midstory isolation design from the coupling of higher modes attributed to the improper design of the substructure and superstructure is proposed in this paper. Copyright © 2012 John Wiley & Sons, Ltd.     

Trace metals associated with deep-sea tailings placement at the Batu Hijau copper–gold mine,Sumbawa, Indonesia

The Batu Hijau copper–gold mine on the island of Sumbawa, Indonesia operates a deep-sea tailings placement (DSTP) facility to dispose of the tailings within the offshore Senunu Canyon. The concentrations of trace metals in tailings, waters, and sediments from locations in the vicinity of the DSTP were determined during surveys in 2004 and 2009. In coastal and deep seawater samples from Alas Strait and the South Coast of Sumbawa, the dissolved concentrations of Ag, As, Cd, Cr, Hg, Pb and Zn were in the sub μg/L range. Dissolved copper concentrations ranged from 0.05 to 0.65 μg/L for all depths at these sites. Dissolved copper concentrations were the highest in the bottom-water from within the tailings plume inside Senunu Canyon, with up to 6.5 μg Cu/L measured in close proximity to the tailings discharge. In general, the concentrations of dissolved and particulate metals were similar in 2004 and 2009.     

Risk assessment and national measure plan for oil and HNS spill accidents near Korea

Many oil and HNS spill accidents occur in the waters surrounding the Korean Peninsula because Korea is one of the biggest trading partners in the world. In this study, we analyzed the oil and HNS spill accidents that occurred between 1994 and 2005 and created risk matrices to assess these accidents. The worst scenarios of future oil and HNS spill accidents were established, and the maximum spill amounts were estimated using historic accident data and a correlation from IPIECA. The maximum spill amounts are estimated to be between 77,000 and 10,000 tons of oil and HNS, respectively. One third of the spill materials should be removed using recovery equipment within three days of the spill event, according to the national measure plan. The capability of recovery equipment to remove spill materials can be estimated, and the equipment should then be prepared to mitigate the harmful effects of future oil and HNS accidents on humans and marine ecosystems.     

Historical record of metal accumulation and lead source in the southeastern coastal region of Korea

Concentrations of heavy metals and Pb isotopes were measured in the 1-M HCl leaching fraction of core sediments spanning the last 400 years. This sedimentary record of pollution history in metal concentrations shows a good correlation with the increases in industrialization, urbanization, and energy consumption since 1901s. Notably, the Pb concentration and the ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb ratios were constant before the 1910s (16.7 μg/g, 0.844, and 2.098, respectively), whereas they increased steadily up to 21.9 μg/g, 0.848, and 2.101 after the 1910s. The correlations between Pb isotope ratios (²⁰⁶Pb, ²⁰⁷Pb, and ²⁰⁸Pb) showed different linear regression trends for core sediments before and after the 1910s, indicating differences in Pb sources. Our interpretation suggests that the source of anthropogenic Pb in Korean coastal region and the Yellow Sea shelf was presumed to be Chinese coals or ores, which have also played a major role as sources of atmospheric particulate Pb.     

Three‐dimensional responses of buried corrugated pipes and ANN‐based method for predicting pipe deflections

This study investigated localized responses, such as circumferential stresses, on corrugation and pipe deflections. Also, this study examined the effect of corrugation geometry on the overall and localized response of corrugated pipes with refined three‐dimensional modeling of the entire soil–pipe interaction system, including corrugation. To investigate the availability of the traditional two‐dimensional method, the results from the three‐dimensional finite element method (FEM) were compared with those from the two‐dimensional FEM. The soil–pipe modeling techniques of this study were verified by comparing the FEM results by Utah State University and analytical results. An artificial neural network (ANN)‐based model to predict vertical deflections of buried corrugated pipes was developed to overcome the shortcomings of existing methods and obtain results that are close to the level of accuracy of FEM results. In order to train an ANN, analyses on a large amount of data were executed with various standardized pipe geometries and burial depths regulated by the Korea Highway Corporation using the two‐dimensional FEM verified in this study. The widely used back propagation algorithm was adopted. The ANN‐based model developed in this study was shown to be an effective tool by comparing the results with test data and sensitivity analyses were executed based on the data from the developed ANN. Copyright © 2010 John Wiley & Sons, Ltd.     

利用有限元方法模拟力学拉伸试验以钢纤维混凝土为例

力学试验是获取岩石等许多工程材料力学性能的主要方法之一。 但是对某些特殊材料, 由于影响其力学性能的因素众多, 单纯通过试验来获取其力学性能, 成本高, 过程复杂。 如工程抗震中目前普遍使用的钢纤维混凝土(SFRC), 很难单纯通过力学试验来获取钢纤维的分布对其力学性能的影响。 本文基于随机方法对钢纤维混凝土建立有限元模型, 利用数值模拟的方法来估计钢纤维的分布和体积率对钢纤维混凝土拉伸性能的影响。 通过与试验结果比较验证了其可行性, 结果表明钢纤维的分布对钢纤维混凝土屈服前的力学性能影响较小, 对屈服后的应力-应变特征影响较大。 当钢纤维体积率从1%变化到2%, 钢纤维混凝土的屈服强度与体积率大致为线性关系, 强度随之增加。     

Spatial variability of biochemical responses in resident fish after the M/V Hebei Spirit Oil Spill (Taean, Korea)

This study describes the spatial variation and the duration of the impacts from the Hebei Spirit oil spill using specific biochemical indices in resident benthic fish. Enzymatic activities and biliary PAHs metabolites were higher at the site closer to the spill area in four months after spill incident. Regarding our results of detoxification response, markers of Phase I followed a similar trend in accordance with levels of biliary metabolites, while markers of phase II and GST appeared relatively unchanged.     

Long-term ocean simulations in FESOM: evaluation and application in studying the impact of Greenland Ice Sheet melting

The Finite Element Sea-ice Ocean Model (FESOM) is formulated on unstructured meshes and offers geometrical flexibility which is difficult to achieve on traditional structured grids. In this work, the performance of FESOM in the North Atlantic and Arctic Ocean on large time scales is evaluated in a hindcast experiment. A water-hosing experiment is also conducted to study the model sensitivity to increased freshwater input from Greenland Ice Sheet (GrIS) melting in a 0.1-Sv discharge rate scenario. The variability of the Atlantic Meridional Overturning Circulation (AMOC) in the hindcast experiment can be explained by the variability of the thermohaline forcing over deep convection sites. The model also reproduces realistic freshwater content variability and sea ice extent in the Arctic Ocean. The anomalous freshwater in the water-hosing experiment leads to significant changes in the ocean circulation and local dynamical sea level (DSL). The most pronounced DSL rise is in the northwest North Atlantic as shown in previous studies, and also in the Arctic Ocean. The released GrIS freshwater mainly remains in the North Atlantic, Arctic Ocean and the west South Atlantic after 120 model years. The pattern of ocean freshening is similar to that of the GrIS water distribution, but changes in ocean circulation also contribute to the ocean salinity change. The changes in Arctic and sub-Arctic sea level modify exchanges between the Arctic Ocean and subpolar seas, and hence the role of the Arctic Ocean in the global climate. Not only the strength of the AMOC, but also the strength of its decadal variability is notably reduced by the anomalous freshwater input. A comparison of FESOM with results from previous studies shows that FESOM can simulate past ocean state and the impact of increased GrIS melting well.