Effective bulk composition changes due to cooling: a model predicting complexities in retrograde reaction textures

Diffusive processes are a strong function of temperature. Thus, during cooling of rocks, mineral grains may develop zoning profiles as successively larger parts of the grain “close” to the diffusive exchange with the rock. One of the consequences of this process is that, during cooling, successively larger parts of zoned minerals (depending on grain size) are effectively removed from the reacting part of the rock volume. Thus, the effective bulk composition of metamorphic rocks changes during cooling and the rate of its change will be a function of grain size. Because the sequence of metamorphic reactions seen by a given rock is a strong function of its bulk composition, this process may have the consequence that two rocks of identical overall bulk composition, but of different grain size, may experience a different sequence of reactions. Qualitatively identical peak paragenesis may therefore react to form qualitatively different retrograde reaction textures. The model is applied to examples in the pelitic system. There, garnet is usually the slowest diffusing phase developing zoning profiles during cooling and the effective removal of garnet from the reacting rock volume will cause changes of the effective bulk composition. It is shown that, during cooling of pelitic rocks from amphibolite facies conditions, typical aluminous peak parageneses of garnet-muscovite-kyanite ± biotite may react to form either staurolite, chlorite or muscovite (or different combinations thereof), depending on grain size. During cooling from the granulite facies, aluminous peak parageneses of garnet-cordierite-sillimanite may form biotite, either on the expense of cordierite or garnet, also depending on grain size. The two examples are illustrated with a series of reaction textures reported for amphibolite and granulite terrains in the literature. Received: 12 March 1996 / Accepted: 7 April 1997     

Glacial rebound of the British Isles—II. A high-resolution, high-precision model

Observations of ice movements across the British Isles and of sea-level changes around the shorelines during Late Devensian time (after about 25 000 yr BP) have been used to establish a high spatial and temporal resolution model for the rebound of Great Britain and associated sea-level change. The sea-level observations include sites within the margins of the former ice sheet as well as observations outside the glaciated regions such that it has been possible to separate unknown earth model parameters from some ice-sheet model parameters in the inversion of the glacio-hydro-isostatic equations. The mantle viscosity profile is approximated by a number of radially symmetric layers representing the lithosphere, the upper mantle as two layers from the base of the lithosphere to the phase transition boundary at 400 km, the transition zone down to 670 km depth, and the lower mantle. No evidence is found to support a strong layering in viscosity above 670 km other than the high-viscosity lithospheric layer. Models with a low-viscosity zone in the upper mantle or models with a marked higher viscosity in the transition zone are less satisfactory than models in which the viscosity is constant from the base of the lithosphere to the 670 km boundary. In contrast, a marked increase in viscosity is required across this latter boundary. The optimum effective parameters for the mantle beneath Great Britain are: a lithospheric thickness of about 65 km, a mantle viscosity above 670 km of about (4-5) 10²⁰ Pa s, and a viscosity below 670 km greater than 4 × 10²¹ Pa s.     

The origin and evolution of magmas from the San Pedro-Pellado volcanic complex,S. Chile: multicomponent sources and open system evolution

The San Pedro-Pellado volcanic complex is located at 36° S in the Chilean Andes. The eruptive rocks of the complex record the development and collapse of a caldera, followed by voluminous, largely basaltic andesite, volcanism. At each stage of evolution, crystal fractionation was accompanied by variable degrees of contamination and mixing. Large variations in incompatible element ratios cannot be produced by closed system evolution. Correlations between indices of differentiation and incompatible element ratios, together with high ¹⁸O values, indicate that basaltic andesites have assimilated crust to generate the evolved volcanic rocks at San Pedro-Pellado. Even in the most mafic rocks, however, incompatible element characteristics are variable as a result of source heterogeneity and deep level processes. The restricted ranges in isotope ratios of Sr, Nd and Pb among San Pedro-Pellado rocks are due to the small contrast in isotopic compositions between magma and wallrock. Three source components are recognized as contributing to parental magmas at San Pedro-Pellado. Although the relative contributions of each cannot be quantified, the volumetrically dominant source component is the sub-arc asthenospheric mantle (MORB source). The major source of LILE is thought to be slab-derived fluids which modified the sub-arc mantle. Other incompatible elements may also have been enriched by interaction with the continental lithosphere (mantle and/or lower crust) during ascent.     

Biomass composition and methods for the determination of metabolic reserve polymers in phototrophic sulfur bacteria

To study nutrient fluxes within aquatic ecosystems, the synthesis of biomass and of various storage polymers has been analysed in samples from a meromictic alpine lake. Methods are described for the quantitative determination of whole cell biomass, glycogen, polyhydroxyalkanoates (PHA) and sulfur. Methods were adapted to conditions present in natural environments and tested with samples from blooms of Chromatiaceae and with corresponding laboratory cultures. Dried bacterioplankton-biomass has been analyzed for sulfur, glycogen and polyhydroxyalkanoates, and after complete oxidation for SO ₄ ^2- , NO ₃ ^- and HPO ₄ ^2- . The average elemental composition of biomass from phototrophic sulfur bacteria, depleted of sulfur and carbon storage compounds, was C₃₈₀H₅₈₀O₁₅₃N₆₇P₃S_2.5M, where M stands for the content of the remaining minor elements. C, H, O, N, P and S accounted for 86.7% of the total dry mass. Storage sulfur in natural populations was equivalent to 2.5% to 13.5% of the dry mass; its content varied by 80% within a diurnal cycle. Glycogen contents fluctuated by approximately 50%; they accounted for 7.5% to 15.2% of the dry cell mass. The total content of reserve materials per cell never exceeded 30% of the dry mass. PHA had not been found in appreciable amounts in cells harvested from the natural lake habitat. Under certain conditions in the laboratoryChromatium okenii could be induced, however, to produce polyhydroxyalkanoates. Sulfur, glycogen and PHA contents of 33, 26 and 11%, respectively, were achieved under laboratory-culture conditions. Cells with up to 60% of their dry mass consisting of reserve materials can be obtained under selected laboratory conditions.     

Nutrient limitation of phytoplankton growth in Georgia nearshore waters

Nutrient enrichment experiments were conducted to investigate the utilization of dissolved organic and inorganic nitrogen by marine phytoplankton in Georgia coastal waters. Natural populations of marine phytoplankton, enriched with different concentrations of ammonium chloride and other plant nutrients, were grown under controlled temperature and irradiance conditions until the populations reached “stationary phase.” Results showed that (1) phytoplankton are limited by DIN up to ca. 20μM, when another nutrient (phosphate or silicate) becomes limiting, (2) very little naturally-occurring DON is directly utilized for growth, (3) very little DON is indirectly made available for growth over time periods of days to ca. 1 week, and (4) trace metals and vitamins do not significantly limit phytoplankton growth.     

Effects of chronic oil pollution from refinery effluent on sediment microflora in a Danish coastal area

Kalundborg Fjord is a Danish marine area which has been heavily oil polluted by refinery effluent, leading to accumulation of petroleum hydrocarbons in the surface sediments. A study of the occurrence in the sediment of heterotrophic bacteria, yeasts and filamentous fungi has been carried out, and the physiological composition of the microbial community has been recorded. Though the abundance of oil-degrading microorganisms was significant, a correlation between the number of these and the oil content of the sediment could not be demonstrated.     

Observational constraints on the angular and spectral distributions of photons in gamma-ray burst sources

The typical spectra of gamma-ray bursts (GRBs) are discussed in the context of the compactness problem for GRB sources and how it is resolved in the popular fireball model. In particular, observational (model-independent) constraints on the collimation of the gamma-rays and the dependence of the collimation angle on the photon energy are considered. The fact that the threshold for the creation of e ^? e ⁺ pairs depends on the angle between the momenta of the annihilating photons in the GRB source provides an alternative solution to the compactness problem. A new approach to explaining GRBs, taking into account the angular dependence for pair creation, is proposed, and the main features of a scenario describing a GRB source with a total (photon) energy smaller or of the order of 10⁴⁹ erg are laid out. Thus, we are dealing with an alternative to an ultra-relativistic fireball, if it turns out (as follows from observations) that all “long” GRBs are associated with normal (not peculiar) core-collapse supernovae. The effects of radiation pressure and the formation of jets as a consequence of even a small amount of anisotropy in the total radiation field in a (compact) GRB source are examined in this alternative model. Possible energy-release mechanisms acting in regions smaller or of the order of 10⁸ cm in size (a compact model for a GRB) are discussed. New observational evidence for such compact energy release in the burst source is considered.     

A water-budget approach to restoring a sedge fen affected by diking and ditching

A vast, ground-water-supported sedge fen in the Upper Peninsula of Michigan, USA was ditched in the early 1900 s in a failed attempt to promote agriculture. Dikes were later constructed to impound seasonal sheet surface flows for waterfowl management. The US Fish and Wildlife Service, which now manages the wetland as part of Seney National Wildlife Refuge, sought to redirect water flows from impounded C-3 Pool to reduce erosion in downstream Walsh Ditch, reduce ground-water losses into the ditch, and restore sheet flows of surface water to the peatland. A water budget was developed for C-3 Pool, which serves as the central receiving and distribution body for water in the affected wetland. Surface-water inflows and outflows were measured in associated ditches and natural creeks, ground-water flows were estimated using a network of wells and piezometers, and precipitation and evaporation/evapotranspiration components were estimated using local meteorological data. Water budgets for the 1999 springtime peak flow period and the 1999 water year were used to estimate required releases of water from C-3 Pool via outlets other than Walsh Ditch and to guide other restoration activities. Refuge managers subsequently used these results to guide restoration efforts, including construction of earthen dams in Walsh Ditch upslope from the pool to stop surface flow, installation of new water-control structures to redirect surface water to sheet flow and natural creek channels, planning seasonal releases from C-3 Pool to avoid erosion in natural channels, stopping flow in downslope Walsh Ditch to reduce erosion, and using constructed earthen dams and natural beaver dams to flood the ditch channel below C-3 Pool. Interactions between ground water and surface water are critical for maintaining ecosystem processes in many wetlands, and management actions directed at restoring either ground- or surface-water flow patterns often affect both of these components of the water budget. This approach could thus prove useful in guiding restoration efforts in many hydrologically altered and managed wetlands worldwide.     

Subsidence and flexure along the Pratt-Welker seamount chain

Chemical and age data led Turner, Jarrard and Forbes to conclude that the origin of the Pratt-Welker seamount chain in the Gulf of Alaska cannot be attributed to a single cause. They argued instead that some seamounts in the chain formed over a hotspot, away from a ridge, while others formed near a ridge. They also noted that the latter group of guyots were generally deeper than the former and they used this observation to predict the origin of the unsampled seamounts in the chain. A second geophysical test of the origin hypothesis is to examine the degree of isostatic compensation of the guyots; seamounts formed near a ridge should be in a state of local isostatic compensation, while seamounts formed away from a ridge should be regionally compensated. This test has been carried out using GEOS 3 and SEASAT altimeter data. The effective flexural rigidity of the lithosphere below all seamounts is found to be less than about 10²⁰ Nm, such that the isostatic state is nearly local, rather than regional. This may be a consequence of all the seamounts having formed on an initially weak lithosphere, of stress relaxation subsequant to their formation away from the ridge, or both. If the seamounts from Giacomini to Durgin formed away from the ridge then these results point to an effective flexural rigidity at the time of loading of about 3 × 10²¹ Nm and to a stress-relaxation time of about 10⁶ years. These values are for an ocean lithosphere that was about 20–22 my old when loaded. Corresponding values for 60 my old lithosphere in the southern Pacific were previously found to be about 3 × 10²² Nm and 5 × 10⁶ years. This comparison suggests that both the initial elastic response and the rate of stress relaxation are functions of the age of the lithosphere. The subsidence of guyots is due to numerous factors including thermal contraction of the seafloor, sediment loading, the flexure of the lithosphere prior to its subduction along the Aleutian Trench and, in view of the above short stress relaxation time, stress relaxation. A principal uncertainty in evaluating the subsidence that has occurred subsequent to the seamount having been eroded to sealevel is the erosion time interval. The comparison of the predicted subsidence with observed depths points to an erosion time constant of the order of 5 my and which is a function of seamount size. The conclusions from the flexure and subsidence analysis as to where the various seamounts formed are in agreement with those of Turner et al. Giacomini, Quinn, Surveyor, Pratt and Durgin formed away from a ridge and are consistent with a fixed hotspot and uniform spreading rate model. The geophysical information for Denson, Davidson and Hodgkins is consistent with the hypothesis that these guyots formed near or on a ridge. The case for Welker seamount is ambiguous, and this guyot may have formed over a second hotspot, located at an intermediate distance between the first and the ridge. The geophysical evidence for Bowie seamount is also ambiguous. Possibly it has a similar source to Welker, suggesting that there may actually be three different origin mechanisms that led to the chain.