Investigation of the Possibility of Copper Removal from Industrial Leachate by Raw and Calcined Phosphogypsum: D‐Optimal and Taguchi Designs

In the present study, the removal of Cu(II) was evaluated by raw and calcined phosphogypsum (PG) as an industrial product. The role of experimental factors on the removal of Cu(II) was examined by using D‐optimal and Taguchi designs. The experimental factors and their related levels were selected as initial pH of 3–6–8, adsorbent content of 5, 10, and 25 g L^?1, contact time of 5, 10, and 20 min, and temperature of 20, 40, and 60°C. The results are evaluated by ANOVA test to extract important experimental factors and their levels. The performances of the suggested factorial designs were then compared and regression models that took into account the significant main and interaction effects were suggested. Taguchi design was found as a reliable solution with less number of experiments for adsorption studies with the optimized values. The resultant removal efficiency is calculated as 78.34%. The results revealed that calcined PG is an appropriate adsorbent for Cu(II) removal from leachate of industrial waste.     

DETERMINATION OF SEDIMENTARY RATE IN ESTUARY AND COAST BY ~(228)Th TECHNIQUE

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Liquefaction potential and susceptibility mapping in the city of Yalova, Turkey

This study presents results of both field and laboratory tests that have been used to asses liquefaction susceptibilities of the soils in Yalova city, located in the well-known seismically active North Anatolian Fault Zone. Liquefaction potentials of the sub-surface materials in Yalova city were estimated by using the standard penetration test (SPT) method of field testing. The data obtained have been mapped according to susceptibility, and the susceptibility maps based on the geotechnical data indicated a moderate to high susceptibility to liquefaction for the magnitude of earthquake of M=7.4. Both the high groundwater level and the grain size of the soils, in conjunction with the active seismic features of the region, result in conditions favourable to the occurrence of liquefaction. When the surface and near surface geological conditions were taken under consideration, it was seen that the study areas geology is prone to liquefaction having a moderate liquefaction susceptibility. If geologic and geomorphological criteria are considered, it should be understood that the study area as discussed under the regions geology is susceptible to liquefaction. The geotechnical data largely support the geologic-based liquefaction susceptibility of the study area.     

Ecological risk assessment using trace elements from surface sediments of Izmit Bay (Northeastern Marmara Sea) Turkey

The aim of this study was to study ecological risk assessment of trace elements (As, Cd, Cr, Cu, Ni, Pb and Zn) in Izmit Bay surface sediments in the <63 microm fraction. Sediment samples were collected from 8 sites along the north coastline of the bay. Samples were subjected to a total digestion technique and analyzed for major (organic carbon) and minor (As, Cd, Cr, Cu, Ni, Pb and Zn) elements. Sediments heavily contaminated are evaluated by the Sediment Quality Guidelines (SQG) of US EPA. The degree of contamination (Cd) is estimated as very high at each site. Two sets of SQGs, effect range-low/effect range median values and TEL/probable effect level (PEL) values were used in our study. Sediments from the each site are judged toxic when two or more of the PEL values exceed EPA guidelines. Our results are in agreement with previously reported sediment toxicity test results.     

A geohazard reconnaissance study based on geoscientific information for development needs of the western region of Istanbul (Turkey)

The role of geoenvironmental information is becoming increasingly important as legislative changes have forced developers and planning authorities to consider more implications and impact on the environment of large-scale development initiatives. Therefore, integration of surface and subsurface geoscientific information for development needs has prime importance and provides a means of identifying potential problems and opportunities at an early stage in any planned development. However, from the experience of recent natural disasters, it is evident that this was not case the taken into consideration in many countries. In addition to thousands of casualties, many urbanized areas, industrial districts and large-scale engineering structures suffered severe damages from the natural hazards due to many reasons including the lack of preliminary engineering geological maps and zoning maps of the settlement areas. Turkey is one of the countries which is exposed to natural hazards such as earthquakes, landslides and floods. In particular, the devastating 1999 Kocaeli earthquake, which affected the Marmara Region of Turkey, focused the attention on densely urbanized and industrialized metropolitan areas such as Istanbul. The rapid growth of Istanbul, particularly towards west with minimal geoscientific information resulted in an overwhelming pressure on the natural environment. In addition, a large earthquake, which is expected to occur in the Marmara Sea within the next 30 years, also pose a threat to the city and its surroundings. In this study, on the basis of the geological, geomorphological and geophysical reconnaissance study, an integrated geoscientific data were collected from the western region of Istanbul and evaluated for geohazards. The paper focuses on the geological and geomorphological aspects that control the occurrence of some geohazards such as earthquake-induced liquefaction, landslides and flooding. In this context, the geological map of the region was revised and Quaternary deposits were classified into 11 units, in detail. Liquefaction-prone areas were evaluated by using geomorphological criteria based on field investigation, by the examination of the available records from 88 boreholes drilled on recent deposits and by the data from resistivity profiles. The landslides within the region were classified according to their type, relative depth and activity. In addition, fluvial and marine flood-prone areas were also delimited within the region. Finally, a series of maps such as landslide inventory maps, and maps showing liquefaction- and flood-prone areas were produced with the aid of Geographic Information Systems (GIS) to assist in designing further detailed site investigations and to reduce costs by ensuring a more focused approach to strategic planning and site selection.     

Landfill site selection by using geographic information systems

One of the serious and growing potential problems in most large urban areas is the shortage of land for waste disposal. Although there are some efforts to reduce and recover the waste, disposal in landfills is still the most common method for waste destination. An inappropriate landfill site may have negative environmental, economic and ecological impacts. Therefore, it should be selected carefully by considering both regulations and constraints on other sources. In this study, candidate sites for an appropriate landfill area in the vicinity of Ankara are determined by using the integration of geographic information systems and multicriteria decision analysis (MCDA). For this purpose, 16 input map layers including topography, settlements (urban centers and villages), roads (Highway E90 and village roads), railways, airport, wetlands, infrastructures (pipelines and power lines), slope, geology, land use, floodplains, aquifers and surface water are prepared and two different MCDA methods (simple additive weighting and analytic hierarchy process) are implemented to a geographical information system. Comparison of the maps produced by these two different methods shows that both methods yield conformable results. Field checks also confirm that the candidate sites agree well with the selected criteria.     

1994年南海夏季风爆发的数值模拟和分析研究

1994年南海夏季风建立于5月第一候,利用MM5成功地模拟了这一过程,并通过敏感性试验,讨论了中纬度系统和中南半岛及其附近地区的积云对流对夏季风环流建立的影响,结果表明:(1)南下接近副热带一定强度的中纬度槽-锋系统的强迫,可引起南海地区副热带高压脊的减弱东撤,因而有利于南海夏季风的建立;(2)东移的中纬度高压脊与南亚高压的同相叠加是触发夏季风建立的重要因子之一,它引起南亚高压中心迅速北移至中南半岛的北部;(3)中南半岛及其附近地区的积云对流加热,对南海地区夏季风环流的建立也有重要的影响.     

Determination of cirrus radiative parameters from combination between active and passive remote sensing measurements during FRENCH/DIRAC 2001

In the context of the next AQUA Train satellite experiment, airborne measurements were carried out to simulate satellite measurements. They were conducted between September 25 and October 12, 2001, off the coast of southern France over the Atlantic Ocean and over the Mediterranean Sea, respectively. During the intensive Field Radiation Experiment on Natural Cirrus and High-level clouds (FRENCH/DIRAC 2001), natural ice clouds were sampled from in situ and remote sensing measurements. On October 5 and 7, 2001, cirrus cloud decks were described by a complete data set acquired by: (i) in situ microphysical instruments onboard the TBM-700 aircraft: PMS probe, and Polar Nephelometer (ii) and downward-looking radiative instruments onboard the Mystère 20 aircraft: an infrared radiometer, a lidar, a visible imager with polarisation capabilities, and a middle infrared radiometer. Moreover, classical thermodynamical measurements were carried out onboard the Mystère 20. Mean microphysical characteristics of cirrus deck are derived from interpretation of remote sensing measurements. These properties are compared with those derived from in situ microphysical measurements in order to evaluate the radiative impact of natural cirrus clouds.     

Ecological quality status of coastal benthic ecosystems in the Sea of Marmara

The macrofauna in the north Marmara Sea were identified and evaluated with univariate measures and biotic indices (BENTIX, AMBI). As expected, the diversity and species' variety decreased as the sediments became muddier and as the stress increased. The AMBI index failed to detect the spatial differentiation of the EcoQ between the sites whereas, the BENTIX index succeeded (in 70% of the cases) in producing an ecologically relevant classification reflecting the environmental pressures. Results suggested that risks of reduced species' richness and diversity from organic loading and other associated stressors in sediments should be relatively low at TOC concentrations < about 6 mg/g, high at concentrations>about 22 mg/g, and intermediate at concentrations in-between. It is suggested that these TOC critical points may be used as a general screening-level indicator for assessing the EcoQ in association with reduced biodiversity over coastal areas receiving organic wastes and other pollutants from human activities. It is further suggested that both assignment of species to ecological groups and classification scales for biotic indices (AMBI, BENTIX) for sites in the Mediterranean Sea should be readjusted so as to be closer related to environmental variables.