Water in star‐forming regions with Herschel

The Herschel Space Observatory is well suited to address several important questions in star‐ and planet formation, as is evident from its first year of operation. This paper focuses on observations of water, a key molecule in the physics and chemistry of star‐formation. In the WISH Key Program, a comprehensive set of water lines is being obtained with the HIFI and PACS instruments toward a large sample of well‐characterized protostars, covering a wide range of luminosities and evolutionary stages. Lines of H₂O, CO and their isotopologues, as well as chemically related hydrides, [O I] and [C II] are observed. Together, the data determine the abundance of water in cold and warm gas, reveal the entire CO ladder up to 4000 K above ground, elucidate the physical processes responsible for the warm gas (passive heating, UV or X‐ray‐heating, shocks), quantify the main cooling agents, and probe dynamical processes associated with forming stars and planets (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Single lunation <Emphasis Type="Italic">N</Emphasis>-observation orbits

Initial orbit determination by least squares of N observations is essentially a linear problem if the coordinates x ₀ and x ₁ at two standard epochs are used as elements. The orbit of a main belt object is approximated within the observational errors by a third degree polynomial during a month. A 4-observation orbit is useful for the initial linking between two nights. Parallax is treated rigorously and future simultaneous space and Earth based observations determine the critical distance directly. The N-observation method is a great simplification of the classical 3-observation orbit followed by a differential correction by N observations.     

Road Traffic and Avalanches – Methods for Risk Evaluation and Risk Management

This paper considers the methods for risk analysis and management in connection with avalanches and road traffic. Examples with calculations of encounter probability and quantification of uncertainty are given, along with suggestions for risk management in Norway.     

Time series tapering for short data samples

We explore the effect of applying tapered windows on atmospheric data to eliminate overestimation inherent in spectra computed from short time series. Some windows are more effective than others in correcting this distortion. The Hamming window gave the best results with experimental data. The Hanning window, which performed almost as well with the same data set, was used to demonstrate the effectiveness of the window in a numerical simulation of the process. We recommend that either of these windows be applied to short data samples prior to spectral analysis.     

In search of a gust definition

We propose a simple gust definition based on the theory of excursions by Rice (1944 and 1945). We discuss the relation to the distribution of extreme events and demonstrate theoretically and experimentally that the most probable extreme event is very close to being identical to the gust according to our definition. We demonstrate how it is possible to predict the gust on the basis of the measured mean wind and variance rather than rely on actually measured extreme excursions. Our gust definition also allows us to predict the average duration of a gust.Supported by the Catalonian Research Council (CIRIT), Spain.     

Geostatistical modelling of the spatial life history of post-larval deepwater hake Merluccius paradoxus in the Benguela Current Large Marine Ecosystem

Optimal and sustainable management of fish resources cannot be ensured without a thorough understanding of the migration patterns and population (demographic stock) structure. Recent studies suggest that these aspects of the economically and ecologically important deepwater hake Merluccius paradoxus are not reflected in the current assessment and management practices for the Benguela Current Large Marine Ecosystem. In this study, we compiled data from multiple demersal trawl surveys from the entire distribution area and applied state-of-the-art geostatistical population modelling (GeoPop) to estimate growth rate, mortality, and spatial and temporal distribution patterns of M. paradoxus. The data and the model enabled us to follow temporal and spatial changes in the distribution and infer movements from the recruitment/nursery areas, through the juvenile phase and the adults’ migration to the spawning areas outside/upstream of the nursery areas. The results indicated one primary recruitment/nursery area on the west coast of South Africa and a secondary less-productive recruitment/nursery area on the south coast near Port Elizabeth. Juveniles initially migrated away from the main recruitment area, followed by natal homing by larger individuals. This pattern was highly consistent through the time-series of the study. This perception of a, primarily, panmictic population that performs transboundary migrations between Namibia and South Africa corresponds largely to the hypothesis and data plots given in recent studies. We recommend that fisheries assessment, advice and management take into consideration these aspects of the distribution and population (stock) structure of M. paradoxus.     

Behaviour of Fe-oxides relevant to contaminant uptake in the environment

The behaviour of Fe-oxides was investigated during precipitation and co-precipitation, phase transformation and dissolution, while their ability to adsorb and incorporate trace components was examined. Some samples were synthesised and studied under controlled laboratory conditions and other samples were taken from experiments designed to test the effectiveness of waste treatment strategies using iron. Surface-sensitive and high-resolution techniques were used to complement information gathered from classical, macroscopic methods.

Adsorption isotherms for Ni²⁺ uptake on synthetic ferrihydrite (Fe₅HO₈·4H₂O, often written simply Fe(OH)₃), goethite (-FeOOH), hematite (-Fe₂O₃) and magnetite (Fe₃O₄) were all similar, increasing as expected at higher pH. Desorption behaviour was also similar, but one third or more of the Ni²⁺ failed to return to solution. In the past, “irreversible sorption” has been blamed on uptake into micro-fractures or pores, but during examination (using Atomic force microscopy, AFM) of hundreds of Fe-oxide particles, no evidence for such features could be found, leading to the conclusion that Ni²⁺ must become incorporated onto or into the solids. When solutions of Fe(II) are oxidised in controlled laboratory conditions or during treatment of ash from municipal waste incinerators, two-line ferrihydrite forms rapidly and on never-dried samples, AFM shows abundant individual particles with diameter ranging from 0.5 to several tens of nanometers. Aging in solution at 70°C promotes growth of the particles into hematite and goethite and their identification (by X-ray powder diffraction, XRPD, with Rietveld refinement) becomes possible at the same aging stage as mineral morphology becomes recognisable by AFM. In other experiments that were designed to mimic natural attack by organic acids, colloidal lepidocrocite (γ-FeOOH) was observed in situ by AFM, while reductive dissolution removed material on specific crystal faces. Lath ends are eroded fastest while basal planes are more stable.

In order to help elucidate mechanisms of contaminant immobilisation by Fe-oxides, we examined samples from a reactive barrier made with 90% quartz sand, 5% bentonite and 5% zero-valent iron filings that had reacted with a solution typical of leachate from coal-burning fly ash using time-of-flight secondary ion mass spectroscopy (TOF-SIMS). Fe(0) oxidised to Fe(III), while soluble and toxic Cr(VI) was reduced to insoluble Cr(III). Chemical maps show Fe-oxide coatings on bentonite; Cr is associated with Fe-oxides to some extent but its association with Ca in a previously undescribed phase is much stronger. Other samples taken from municipal waste incinerator ash that had been treated by aeration in Fe(II) solutions were examined with transmission electron microscopy (TEM), selected area electron diffraction (SAED) and energy dispersive X-ray spectroscopy (EDS). Pb and some Zn are seen to be dispersed throughout two-line ferrihydrite aggregates, whereas Sn and some Zn are incorporated simply as a result of entrainment of individual ZnSn-oxide crystallites.

Geochemical speciation models that fail to account for contaminant uptake in solid solutions within major phases or as thin coatings or entrained crystals of uncommon phases such as those described here risk to underestimate contaminant retardation or immobilisation.