Nontronit und Pieotit aus dem Basalt des Ölberges bei Hundsangen,Westerwald

Zusammenfassung Der Basalt des Ölberges enthält an verschiedenen Stellen bis zu faustgroße, blasenförmige Einschlüsse von Nontronit. Der Nontronit zeigt eine starke Montmorillonit- und Saponitkomponente und hat folgende stöchiometrische Zusammensetzung: (Fe ₊₊₊ ^1,18 , Al_0,44, Cr_0,06, Mg_0,58, Fe ₊₊ ^0.01 )_2,27 [Al_0,22Si_3,75O₁₀] (OH)₂.Dem Nontronit ist ein Picotit (Mgo_0,58, Fe ₊₊ ^0,34 )_0.92 ( Al_1,36, Cr_0,64), beigemengt. Der Picotit hat die Gitterkonstante ₀= 8,18 Å und das spezifische Gewicht = 4,00 g/cm³. Die kleine Gitterkonstante und das geringe spezifische Gewicht des Picotits bestätigen, daß ein Mischkristall mit einer -Al₂O₃-Komponente vorliegt. Der Picotit weist außerdem einen Nickelgehalt von etwa 0,1% Ni0 in der Analyse auf.Neben Picotit sind in der Nontronitmasse einzelne Bronzitkriställchen vorhanden. Der Chromgehalt des Nontronits, der Chrom- und Nickelgehalt des Spinellminerals, sowie das Vorhandensein von Bronzit beweisen, daß der Nontronit im Basalt des Ölberges ein Zersetzungsprodukt von Olivinknollen ist.     

Immunological studies on microbial mats from Solar Lake (Sinai)— A contribution to the organic geochemistry of sediments

Immunological and biochemical techniques were used to investigate organic matter in microbial mats from Solar Lake (Sinai, Egypt). Antibodies, elicited in rabbits against samples taken at different depths from a core of these mats, were used for the detection of immunological determinants preserved in these samples. Special attention was given to an antiserum directed against a top mat fraction (3–10 mm depth) and an antiserum against a fraction from a lower section of the core (380–390 mm depth). Both antisera, tested in a dot-blot immunobinding assay, were found to give positive reactions with organic matter from different depths of the sediment. An immunohistochemical experiment with the antisera points to antigenic determinants on Recent and subfossil sheaths of Microcoleus. In addition, extracts of sediment samples were submitted to electrophoresis in polyacrylamide gels in order to characterize the separated macromolecules by immunological means. The results showed a rapid decrease in the number of antigenic determinants from Recent to subfossil samples. However, even in the deepest layers of the sediment (690–700 mm depth) intact biopolymers were detected.     

The Project for Intercomparison of Land-surface Parameterization Schemes (PILPS) phase 2(c) Red-Arkansas River basin experiment:: 2. Spatial and temporal analysis of energy fluxes

The energy components of sixteen Soil-Vegetation Atmospheric Transfer (SVAT) schemes were analyzed and intercompared using 10 years of surface meteorological and radiative forcing data from the Red-Arkansas River basin in the Southern Great Plains of the United States. Comparisons of simulated surface energy fluxes among models showed that the net radiation and surface temperature generally had the best agreement among the schemes. On an average (annual and monthly) basis, the estimated latent heat fluxes agreed (to within approximate estimation errors) with the latent heat fluxes derived from a radiosonde-based atmospheric budget method for slightly more than half of the schemes. The sensible heat fluxes had larger differences among the schemes than did the latent heat fluxes, and the model-simulated ground heat fluxes had large variations among the schemes. The spatial patterns of the model-computed net radiation and surface temperature were generally similar among the schemes, and appear reasonable and consistent with observations of related variables, such as surface air temperature. The spatial mean patterns of latent and sensible heat fluxes were less similar than for net radiation, and the spatial patterns of the ground heat flux vary greatly among the 16 schemes. Generally, there is less similarity among the models in the temporal (interannual) variability of surface fluxes and temperature than there is in the mean fields, even for schemes with similar mean fields.     

Evidence for gammacerane as an indicator of water column stratification

A new route for the formation of gammacerane from tetrahymanol is proposed; in addition to dehydration and hydrogenation, sulphurisation and early C-S cleavage are shown to be important in the pathway of formation, especially in marine sediments. Evidence is twofold. First, relatively large amounts of the gammacerane skeleton are sequestered in S-rich macromolecular aggregates formed by natural sulphurisation of functionalised lipids. Selective cleavage of polysulphide linkages with MeLi/MeI led to formation of 3-methylthiogammacerane, indicating that the gammacerane skeleton is primarily bound via sulphur at position 3, consistent with the idea that tetrahymanol (or the corresponding ketone) is the precursor for gammacerane. Second, upon mild artificial maturation of two sediments using hydrous pyrolysis, gammacerane is released from S-rich macromolecular aggregates by cleavage of the relatively weak C-S bonds. The stable carbon isotopic compositions of gammacerane and lipids derived from primary producers and green sulphur bacteria in both the Miocene Gessoso-solfifera and Upper Jurassic Allgau Formations indicate that gammacerane is derived from bacterivorous ciliates which were partially feeding on green sulphur bacteria. This demonstrates that anaerobic ciliates living at or below the chemocline are important sources for gammacerane, consistent with the fact that ciliates only biosynthesize tetrahymanol if their diet is deprived of sterols. This leads to the conclusion that gammacerane is an indicator for water column stratification, which solves two current enigmas in gammacerane geochemistry. Firstly, it explains why gammacerane is often found in sediments deposited under hypersaline conditions but is not necessarily restricted to this type of deposits. Secondly, it explains why lacustrine deposits may contain abundant gammacerane since most lakes in the temperate climatic zones are stratified during summer.     

Coproducing urban space: Rethinking the formal/informal dichotomy

Providing an introduction to the special section ‘Close encounters: ethnographies of the coproduction of space by the urban poor’, this article sets out to argue that the image of ‘the informal’ as unruly, messy and dirty continues to inform urban planning around the world. As a reaction to this view, it contends that the informal and formal should be analysed as interconnected and that the informal sphere should be revalued. Urban development is studied as close encounters between established practices, with a locus and a history (tree‐like), and newly emerging, unstable and untraceable practices (rhizomatic). Contrary to the tendency in urban planning to conflate the formal with the tree and the informal with the rhizome, we argue that from the perspective of marginal urbanites, formal planning tends to be very arbitrary and frightening (rhizomatic), whereas informal practices can be very predictable and stable (arboreal). The article analyses residents of marginalized urban areas as inventive navigators who explore the changing physical, spatial and sociopolitical environment, avoiding threats and looking for opportunities, grounded in their everyday practices and life histories. The article concludes that marginal urbanites should be acknowledged as coproducers of urban space and that the right to ‘coproduce’ the city lies at the heart of the call for the right to the city.     

Regimes of spatial ordering in Brazil: Neoliberalism,leftist populism and modernist aesthetics in slum upgrading in Recife

This paper shows how regimes of spatial ordering in Brazil are produced by the entangling of neoliberalism, leftist populism and modernist visions. The paper focuses on Prometrópole, a slum upgrading project in Recife funded by the World Bank, which commenced in 2007. In this project, the neoliberal dimension manifests in the idea that the state, private companies and citizens together are responsible for (re)constructing urban space, and further, that beneficiaries should behave as autonomous citizens, taking responsibility for their new living environment. The leftist political dimension is seen in participatory procedures to involve the target population from project design through to implementation, in expectation of their cooperation with the government. The modernist aesthetics – of straight lines, open spaces and visible order – informs the project design with the requirement to use the new houses and public spaces according to the standards of ‘modern civilization’. As our research shows, such a regime of spatial ordering clashes with the livelihoods of the urban poor, whose quality of life might even deteriorate as a result of the intervention. Furthermore, so‐called participatory procedures fail to grant the target population any real influence in creating their environment. Consequently, these residents of the new housing estate drastically reconstruct their private and public areas, reappropriating the urban space and contesting the regime of spatial ordering imposed upon them.     

Free fatty acid analysis of the early proterozoic animikie group,Minnesota and Ontario

The Early Proterozoic iron formation-slate sequences of the Animikie Group have been analyzed for fatty acids and the results discussed in light of the regional metamorphic history and kerogen H/C and N/C atomic ratios. No fatty acids, free or inorganically bound, were detected. The highest H/C ratios are found in the Gunflint (mean = 0.57) and lowest in the Virginia State (0.19). The lower H/C ratio in the Biwabik (mean = 0.45) is interpreted as a function of higher metamorphic grade in that iron formation. The absence of fatty acids is attributed to dehydrogenation and cyclization of the original material to the present H/C ratio of about 0.5. The Gunflint Iron-Formation, which represents those conditions most likely to preserve chemical fossils in the Animikie Group has already exceeded minimum conditions for fatty acid preservation. Hydrogen to carbon ratios in pelitic rocks are consistently lower than their underlying iron-formation. It is suggested that sulfur and/or clay alter the kinetics of the dehydrogenation reaction, creating lower H/C ratios in the pelites.     

Tracing tsunami signatures of the ad 551 and ad 1303 tsunamis at the Gulf of Kyparissia (Peloponnese,Greece) using direct push in situ sensing techniques combined with geophysical studies

The western Peloponnese was repeatedly hit by major tsunami impacts during historical times as reported by historical accounts and recorded in earthquake and tsunami catalogues. Geological signatures of past tsunami impacts have also been found in many coastal geological archives. During the past years, abundant geomorphological and sedimentary evidence of repeated Holocene tsunami landfall was found between Cape Katakolo and the city of Kyparissia. Moreover, neotectonic studies revealed strong crust uplift along regional faults with amounts of uplift between 13 m and 30 m since the mid-Holocene. This study focuses on the potential of direct push in situ sensing techniques to detect tsunami sediments along the Gulf of Kyparissia. Direct push measurements were conducted on the landward shores of the Kaiafa Lagoon and the former Mouria Lagoon from which sedimentary and microfaunal evidence for tsunami landfall are already known. Direct push methods helped to decipher in situ high-resolution stratigraphic records of allochthonous sand sheets that are used to document different kinds of sedimentological and geomorphological characteristics of high-energy inundation, such as abrupt increases in grain size, integration of muddy rip-up clasts and fining upward sequences which are representative of different tsunami inundation pulses. These investigations were completed by sediment coring as a base for local calibration of geophysical direct push parameters. Surface-based electrical resistivity tomography and seismic data with highly resolved vertical direct push datasets and sediment core data were all coupled in order to improve the quality of the geophysical models. Details of this methodological approach, new in palaeotsunami research, are presented and discussed, especially with respect to the question of how the obtained results may help to facilitate tracing tsunami signatures in the sedimentary record and deciphering geomorphological characteristics of past tsunami inundation. Using direct push techniques and based on sedimentary data, sedimentary signatures of two young tsunami impacts that hit the Kaiafa Lagoon were detected. Radiocarbon age control allowed the identification of these tsunami layers as candidates for the ad 551 and ad 1303 earthquake and tsunami events. For these events, there is reliable historical data on major damage on infrastructure in western Greece and on the Peloponnese. At the former Mouria Lagoon, corroborating tsunami traces were found; however, in this case it is difficult to decide whether these signatures were caused by the ad 551 or the ad 1303 event.     

Key results and implications from phase 1(c) of the Project for Intercomparison of Land-surface Parametrization Schemes

 Using atmospheric forcing data generated from a general circulation climate model, sixteen land surface schemes participating in the Project for the Intercomparison of Land-surface Parametrization Schemes (PILPS) were run off-line to equilibrium using forcing data from a GCM representative of a tropical forest and a mid-latitude grassland grid point. The values for each land surface parameter (roughness length, minimum stomatal resistance, soil depth etc.) were provided. Results were quality controlled and analyzed, focusing on the scatter simulated amongst the models. There were large differences in how the models’ partitioned available energy between sensible and latent heat. Annually averaged, simulations for the tropical forest ranged by 79 1 3;W m^-2 for the sensible heat flux and 80 W m^-2 for the latent heat flux. For the grassland, simulations ranged by 34 W m^-2 for the sensible heat flux and 27 W m^-2 for the latent heat flux. Similarly large differences were found for simulated runoff and soil moisture and at the monthly time scale. The models’ simulation of annually averaged effective radiative temperature varied with a range, between all the models, of 1.4 K for tropical forest and 2.2 K for the grassland. The simulation of latent and sensible heat fluxes by a standard ‘bucket’ models was anomalous although this could be corrected by an additional resistance term. These results imply that the current land surface models do not agree on the land surface climate when the atmospheric forcing and surface parameters are prescribed. The nature of the experimental design, it being offline and with artificial forcing, generally precludes judgements concerning the relative quality of any specific model. Although these results were produced de-coupled from a host model, they do cast doubt on the reliability of land surface schemes. It is therefore a priority to resolve the disparity in the simulations, understand the reasons behind the scatter and to determine whether this lack of agreement in de-coupled tests is reproduced in coupled experiments. Received: 15 October 1997 / Accepted: 22 April 1999     

Soil moisture effects on seasonal temperature and precipitation forecast scores in Europe

The Second Global Land Atmosphere Coupling Experiment (GLACE2) is designed to explore the improvement of forecast skill of summertime temperature and precipitation up to 8?weeks ahead by using realistic soil moisture initialization. For the European continent, we show in this study that for temperature the skill does indeed increase up to 6 weeks, but areas with (statistically significant) lower skill also exist at longer lead times. The skill improvement is smaller than shown earlier for the US, partly because of a lower potential predictability of the European climate at seasonal time scales. Selection of extreme soil moisture conditions or a subset of models with similar initial soil moisture conditions does improve the forecast skill, and sporadic positive effects are also demonstrated for precipitation. Using realistic initial soil moisture data increases the interannual variability of temperature compared to the control simulations in the South-Central European area at longer lead times. This leads to better temperature forecasts in a remote area in Western Europe. However, the covered range of forecast dates (1986–1995) is too short to isolate a clear physical mechanism for this remote correlation.