Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.     

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.     

Correction to: El Niño-related sea surface elevation and ocean bottom pressure enhancement associated with the retreat of the Oyashio southeast of Hokkaido,Japan

Marine Geophysical Research - In the original publication, the Fig. 2 was published incorrectly. The correct version (Fig. 2) is given in this correction. The original article has been...     

The interanual rainfall variability in Indonesia corresponding to El Niño Southern Oscillation and Indian Ocean Dipole

The Impact of the Indian Ocean Dipole(IOD) and the El Ni?o Southern Oscillation(ENSO) event for Indonesian rainfall has been investigated for the period from 1950 to 2011. Inter-annual change of IOD and ENSO indices are used to investigate their relationship with Indonesian rainfall. By using the wavelet transform method, we found a positive significant correlation between IOD and Indonesian rainfall on the time scale of nearly 2.5–4 years.Furthermore, the positive significant correlation between ENSO(sea surface temperature anomaly at Ni?o3.4 area indices) and Indonesian rainfall exists for shorter than 2 years and between 5.5 to 6.5-year time scales.     

Variations of Kuroshio geostrophic transport south of Japan estimated from long-term IES observations

Two inverted echo sounders were maintained on coastal and offshore sides of the Kuroshio south of Japan from October 1993 to July 2004. Applying the gravest empirical mode method, we obtained a time series of geostrophic transport. Estimated transports generally agree well with geostrophic transports estimated from hydrography. Their agreement with the hydrographic transports is better than that of transports estimated from satellite altimetry data. The geostrophic transport is expressed as the surface transport per unit depth multiplied by the equivalent depth. The geostrophic transport varies mostly with the surface transport and fractionally with the equivalent depth. Seasonal variation of the geostrophic transport has a minimum in March and a maximum in September, with a range of about one fifth of the total transport.     

Vertical double silicate maxima in the sea-ice reduction region of the western Arctic Ocean: Implications for an enhanced biological pump due to sea-ice reduction

The R/V Mirai conducted hydrographic surveys in the western Arctic Ocean during summer 2004 (Mirai04) over wide east-west ranges from Alaska to eastern Siberia, where sea-ice cover has been greatly reduced in recent summers. The obtained data reveal differences in silicate profiles between shelf slope areas east and west of the Chukchi Plateau, the ridge that divides the Canada Basin into the Alaskan and east Siberian sides. East of the plateau, a single silicate maximum was found in a layer of Pacific-origin winter water, as examined in many previous studies. In contrast, west of the plateau, we found vertical double silicate maxima, which are reported for the first time in this study. The shallower silicate maximum corresponded to an N** minimum, signaling denitrification at the shelf bottom. This suggests that the shallower silicate maximum was caused by the spreading of shelf water. In contrast, the deeper silicate maximum corresponded to an oxygen minimum and a maximum silicate/phosphate ratio (Si/P), suggesting that this deeper maximum resulted from the decomposition of opal-shelled organisms. We also compared a silicate profile from Mirai04 to aprofile from the Arctic Ocean Section 94 (AOS94) expedition of 1994, a heavy ice year. The results suggest that sea-ice loss has enhanced biological activities, likely resulting in the appearance of the deeper silicate maximum.