Air-sea exchange of mercury in Tokyo Bay

In Tokyo Bay the concentrations of dissolved gaseous mercury (DGM) in the surface seawater and total gaseous mercury (TGM) over the sea were measured during December 2003, October 2004 and January 2005. Based on these data, the evasional fluxes of mercury from the sea surface were estimated using a gas exchange model. In addition, an automatic wet and dry deposition sampler was used to measure the wet and dry depositional fluxes of mercury from December 2003 to November 2004 at three locations in and near Tokyo Bay. The results indicate that the average DGM and TGM levels of seven locations are 52 ± 26 ng m⁻³ and 1.9 ± 0.6 ng m⁻³, respectively, which shows that the surface seawater in Tokyo Bay is supersaturated with gaseous mercury, leading to an average mercury evasional flux of 140 ± 120 ng m⁻²d⁻¹. On the other hand, the annual average wet and dry depositional fluxes of mercury at three locations were 19 ± 3 μg m⁻²yr⁻¹ and 20 ± 9 μg m⁻²yr⁻¹, respectively. These depositional fluxes correspond to the daily average total depositional flux of 110 ± 20 ng m⁻²d⁻¹. Thus, it is suggested that in Tokyo Bay, the evasional fluxes of mercury are comparable to the depositional fluxes.     

Change in seismic activity in the Tokai region related to weakening and strengthening of the interplate coupling

We investigate the relationship between changes in seismicity and crustal deformations in the Tokai region. We describe how seismicity in the subducted slab increased remarkably in the fall of 2000 and decreased in the fall of 2001, while in contrast, the crust seismicity decreased in the fall of 2000 and increased in the fall of 2001. We note that the trend of horizontal displacement at GPS stations changed coincidentally and we propose interpreting the increase and decrease in seismic activities and the changes in crustal deformations in a unified way based on changes in the state of the interplate coupling, i.e., the back-slip rate was reduced in the fall of 2000 and was partially restored in the fall of 2001. We explain why reduction of the back-slip rate increases seismogenic stress in the slab and decreases stress in the crust. We also describe the substantial positive dilatation observed in the region around Mt. Fuji in the fall of 2000 and suggest that the remarkable increase of low-frequency earthquakes beneath Mt. Fuji in October 2000 may have been caused by deceleration of the converging motion of the Izu micro-plate with the Eurasian plate. The decrease of the subduction velocity of the Izu micro-plate on the Suruga Trough in late 2000 would also have contributed to weakening of the interplate coupling beneath the Tokai region, since reduction of the relative velocity between overriding and subducting plates produces the same effect on the plate interface as a diminishing back-slip rate. However, subduction of the Izu micro-plate on the Suruga Trough was accelerated in early 2003, which may have caused increases in both slab and crust seismicities in that period.     

Mass balance and sources of mercury in Tokyo Bay

The mass balance and sources of mercury in Tokyo Bay were investigated on the basis of observations from December 2003 to January 2005. Estimated input terms included river discharge (70 kg yr⁻¹) and atmospheric deposition (37 kg yr⁻¹), and output terms were evasion (49 kg yr⁻¹), export (13 kg yr⁻¹) and sedimentation (495 kg yr⁻¹). Thus, the outputs (557 kg yr⁻¹) considerably exceeded the inputs (107 kg yr⁻¹). In addition, the imbalance between the inputs and outputs of mercury was much larger than that of other trace metals (Cd, Cr, Cu, Pb and Zn), which suggests that there are other major inputs of mercury to Tokyo Bay. The mercury concentrations in rivers correlated significantly with the concentrations of Al and Fe, major components of soil. In Japan, large amounts of organomercurous fungicides (about 2500 tons as Hg) were used extensively in fields in the past, and most of the mercury was retained in the soil. In this study, the mercury concentration in rivers was measured primarily in ordinary runoff. These observations lead to the hypothesis that field soil discharged into stormwater runoff is a major source of mercury in Tokyo Bay. As a preliminary approach to validating this hypothesis, we measured the concentrations of mercury and other trace metals in river water during a typhoon. The mercury concentrations in stormwater runoff increased to 16–50 times the mean value in ordinary runoff, which is much higher than the increases for other metals. This tends to support the hypothesis.     

Sedimentary humic acid and fulvic acid as surface active substances

Surface tension of sedimentary fulvic acid (FA) and humic acid (HA) with molecular weight from < 10,000 to > 300,000 was measured at 5°C and 25°C, over a wide range of concentrations (0.114-107.4 g/l) at pH 8. HA was in the form of sodium humate. Surface tension decreases with an increase in HA and FA concentration and both HA and FA were found to be surface active materials with FA exhibiting the lowest surface tension (31 dynes/cm).Plots of surface tension vs. log concentration gave two straight lines with a break at a certain concentration similar to surfactants. From the concentration at the break point, aggregation concentration (AGC) was determined. For HA with molecular weight above 10,000, the AGC decreased with an increase in molecular weight. The more hydrophobic the HA, the greater was the tendency to form aggregates. Surface excess (surface concentration) was determined (2.3 × 10^?10?5.5 × 10^?10mol/cn²) from the slope of the plot of surface tension vs. log concentration for concentrations lower than the AGC. Adsorption of HA into the surface layer increased with increasing molecular weight of HA.     

Contraction and Fragmentation of Magnetized Rotating Clouds and Formation of Binary Systems

Using three-dimensional (3D) magnetohydrodynamical (MHD) nested-grid simulations, the fragmentation of a rotating magnetized molecular cloud core is studied. An isothermal rotating magnetized cylindrical cloud in hydrostatic balance is considered. We studied non-axisymmetric evolution of the cloud. It is found that non-axisymmetry hardly evolves in the early phase, but it begins to grow after the gas contracts and forms a thin disk. The disk formation and thus growth of non-axisymmetric perturbation are strongly promoted by rotation and magnetic field strength. We found two types of fragmentations: fragmentation from a ring and that from a bar. These two types of fragmentations occur in thin adiabatic cores with the thickness being smaller than 1/4 of the radial size. For the fragments to survive, they should be formed in a heavily elongated barred core or a flat round disk. In the models showing fragmentation, outflows from respective fragments are found as well as that driven by the rotating bar or the disk.     

Collapse and fragmentation of rotating magnetized clouds – II. Binary formation and fragmentation of first cores

Subsequent to Paper I, the evolution and fragmentation of a rotating magnetized cloud are studied with use of three-dimensional magnetohydrodynamic nested grid simulations. After the isothermal runaway collapse, an adiabatic gas forms a protostellar first core at the centre of the cloud. When the isothermal gas is stable for fragmentation in a contracting disc, the adiabatic core often breaks into several fragments. Conditions for fragmentation and binary formation are studied. All the cores which show fragmentation are geometrically thin, as the diameter-to-thickness ratio is larger than 3. Two patterns of fragmentation are found. (1) When a thin disc is supported by centrifugal force, the disc fragments into a ring configuration (ring fragmentation). This is realized in a rapidly rotating adiabatic core as  Ω > 0.2τ⁻¹_ff  , where Ω and  τ_ff  represent the angular rotation speed and the free-fall time of the core, respectively. (2) On the other hand, the disc is deformed to an elongated bar in the isothermal stage for a strongly magnetized or rapidly rotating cloud. The bar breaks into 2–4 fragments (bar fragmentation). Even if a disc is thin, the disc dominated by the magnetic force or thermal pressure is stable and forms a single compact body. In either ring or bar fragmentation mode, the fragments contract and a pair of outflows is ejected from the vicinities of the compact cores. The orbital angular momentum is larger than the spin angular momentum in the ring fragmentation. On the other hand, fragments often quickly merge in the bar fragmentation, since the orbital angular momentum is smaller than the spin angular momentum in this case. Comparison with observations is also shown.     

In situ filtration sampler for taking filtered water samples

A new type ofin situ filtration sampler is described. The all Teflon sampler is hung on a nylon rope attached to a steel wire (Fig. 3). By dropping a messenger, the sampler piston is pulled down by a released weight of 50 kg, and the sampler is filled with about 400 ml of filtered water. The sample is not contaminated by metals because there is no metal around the sampler.     

Sedimentary humic acid and fulvic acid as fluorescent organic materials

Fluorescence and absorption spectra of sedimentary humic acid (HA) and fulvic acid (FA), with molecular weights ranging from < 10,000 to >300,000, were measured at 20°C and pH 8. The maximum excitation and emission wavelengths of HA were longer than those of FA, being independent of molecular weight. The excitation and emission maxima can be utilized to differentiate between sedimentary HA and FA. It is suggested that the fluorophors in HA are of a higher molecular weight aromatic groups than those in FA.Smaller molecules were found to have a greater fluorescence than larger ones for sedimentary humic substances and this phenomenon is similar to those obtained for humic substances of terrestrial origin. The absorption coefficient (1/g/cm) of HA decreased, while that of FA increased with the increase in molecular weight. It was shown that fluorescence intensity per weight concentration unit of HA increases and that of FA decreases with increasing absorption coefficient.     

Sequential explosions of supernovae in an ob association and formation of a superbubble

From the standpoint of view that the early type stars are formed sequentially at an OB association, it is expected that the supernova explosions will also occur sequentially. We study the expansion law of a supernova remnant, which is formed by sequential explosions of supernovae. The superbubbles and supershells with the radii 2001000 pc are naturally explained by this model. Assuming that the sequential explosion of supernovae occurs at every OB association, we deduce the star formation rate in our Galaxy.