Occurrence and turnover of DMSP and DMS in deep waters of the Ross Sea,Antarctica

High concentrations of the phytoplankton metabolite dimethylsulfoniopropionate (DMSP) and its degradation product dimethylsulfide (DMS) are associated with blooms of Phaeocystis antarctica in the Ross Sea, Antarctica. Episodic and rapid vertical export of Phaeocystis biomass to deep water has been reported for the Ross Sea, therefore we examined the distribution and microbial consumption rates of DMSP and DMS throughout the sub-euphotic water column. Total DMSP (dissolved+particulate; DMSPt) was present at 0.5–22 nM at depths between 70 and 690 m during both the early bloom (November) and the late bloom (January). Sub-euphotic peaks of DMSP were sometimes associated with mid-water temperature maxima, and elevated DMSP below 70 m was found mainly in water masses characterized as Modified Circumpolar Deep Water or Antarctic Shelf Water. Overall, 50–94% of the integrated water-column DMSPt was found below the euphotic zone. At one station during the early bloom, local maxima of DMSPt (14 nM) and DMS (20 nM) were observed between 113 and 240 m and these maxima corresponded with high chlorophyll a concentrations, P. antarctica cell numbers, and Fv/Fm (the quantum yield of photosystem II). During the late bloom, a sub-euphotic maximum of DMSPt (15.8 nM) at 250 m cooccurred with peaks of chlorophyll a concentration, DMSP lyase activity, bacterial production and dissolved DMSP consumption rates. DMSP turnover contributed ～12% of the bacterial carbon demand between 200 and 400 m. DMS concentrations peaked at 286 m but the maximum concentration (0.42 nM) was far lower than observed during the early bloom, probably because of relatively rapid biological consumption of DMS (1–3 turnovers per day) which, in turn, contributed to elevated dissolved dimethylsulfoxide (DMSO) concentrations. Relatively stable DMSPt distributions at some sites suggest that rapid sinking of Phaeocystis biomass is probably not the major mechanism responsible for mesopelagic DMSP accumulations. Rather, subduction of near-surface water masses, lateral advective transport or trapping of slowly sinking P. antarctica biomass in intermediate water masses are more likely mechanisms. We found that a culture of P. antarctica maintained cellular integrity during 34 days of darkness, therefore the presence of intact cells (and DMSP) at depth can be explained even under a slow sinking/advection scenario. Whatever the mechanism, the large pools of DMSP and DMS below the euphotic zone suggest that export exerts a control on potential DMS emission from the surface waters of the Ross Sea.     

Using the spectral scaling exponent for validation of quantitative precipitation forecasts

This study evaluates the spectral scaling of a heavy rainfall event and assesses the performance of the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS) model in terms of the multiscale variability of rainfall in the temporal spectral domain. The event occurred over southern Malay Peninsula on 18 December 2006 and was simulated at high resolutions. 10, 5 and 1?min aggregate rainfall data from rain gauge stations in Singapore and simulated rainfall sampled at different evaluation points on 0.9, 0.3 and 0.1?km grids were utilized. The simulated and observed rain rates were compared via Fourier and wavelet analyses. A scaling regime was noted in the observed rainfall spectra in the timescales between 60?min and 2?min. The scaling exponent obtained from the observed spectra has a value of about 2, which may be indicative of the physics of turbulence and raindrop coalescence and might suggest the predominance of a characteristic raindrop size. At 0.9?km resolution, the model rainfall spectra showed similar scaling to the observed down to about 10?min, below which a fall-off in variance was noted as compared to observations. Higher spatial resolution of up to 0.1?km was crucial to improve the ability of the model to resolve the shorter timescale variability. We suggest that the evaluation of dynamical models in the spectral domain is a crucial step in the validation of quantitative precipitation forecasts and assessing the minimal grid resolution necessary to capture rainfall variability for certain short timescales may be important for hydrological predictions.     

Large-Eddy Simulation of Flow and Pollutant Transport in Urban Street Canyons with Ground Heating

Our study employed large-eddy simulation (LES) based on a one-equation subgrid-scale model to investigate the flow field and pollutant dispersion characteristics inside urban street canyons. Unstable thermal stratification was produced by heating the ground of the street canyon. Using the Boussinesq approximation, thermal buoyancy forces were taken into account in both the Navier–Stokes equations and the transport equation for subgrid-scale turbulent kinetic energy (TKE). The LESs were validated against experimental data obtained in wind-tunnel studies before the model was applied to study the detailed turbulence, temperature, and pollutant dispersion characteristics in the street canyon of aspect ratio 1. The effects of different Richardson numbers (Ri) were investigated. The ground heating significantly enhanced mean flow, turbulence, and pollutant flux inside the street canyon, but weakened the shear at the roof level. The mean flow was observed to be no longer isolated from the free stream and fresh air could be entrained into the street canyon at the roof-level leeward corner. Weighed against higher temperature, the ground heating facilitated pollutant removal from the street canyon.     

Removal of trace metals from seawater during a phytoplankton bloom as studied with sediment traps in Funka Bay,Japan

To study biological effects on the particulate removal of chemical elements from seawater, sediment trap experiments were carried out successively ten times throughout the spring phytoplankton bloom in Funka Bay. Sediment traps were deployed every one to two weeks at 1, 40 and 80 m depths. The settling particles obtained were analyzed for trace metals, phosphate and silicate. The propagation of diatoms in spring results in larger particulate fluxes than that of dinoflagellates. The biogenic silicate concentration is higher in the earlier period, when diatoms are predominant, than in the subsequent period, when dinoflagellates are predominant. The concentrations of aluminum, iron, manganese and cobalt in the settling particles comprising largely biogenic particles are lower during phytoplankton bloom. The concentration of copper is not reduced by the addition of biogenic particles, and its vertical flux is approximately proportional to the total flux, indicating that its concentration in the biogenic particles is nearly equal to that in the non-biogenic particles. The results for nickel and lead show the same tendency as for copper. Cadmium is more concentrated in biogenic particles than in non-biogenic particles, and the concentration of cadmium in the settling particles decreases with depth, similarly to phosphate and organic matter. Thus, metals in seawater are segregated by biological affinities, and the degree of incorporation into biogenic particles is in the order Cd > Pb, Ni, Cu > Co > Mn, Fe, Al. Biogenic particles are the most important agent controlling the vertical distribution of metals in the ocean. They remove the metals from the surface water, transport them through the water column, and regenerate them in the deep.     

Different partitioning among thorium isotopes in seawater of the Northern North pacific

Each about 400 l of seawater sample was collected in the northern North Pacific and filtered through a membrane filter. Four radioisotopes of thorium,²³²Th,²³⁰Th,²²⁸Th and²³⁴Th, were determined for the two FractionsF (filtrate) andP (particles on the filter). In the percentages of FractionP in the subsurface water,²³⁰Th was significantly larger than other 3 isotopes, and²³²Th was significantly smaller than other 3 isotopes. The former finding can be explained by the slower rates in the reversible change between the FractionsF andP. The latter one, however, cannot be explained if thorium isotopes in the FractionF are truly dissolved with the same chemical form. This suggests that major part of the FractionF of²³²Th is not identical with those of other radiogenic thorium isotopes, and it should not be composed of simple dissolved ions. The removal of radiogenic²³⁴Th was related to the biological activity, but there was a deviation, between the FractionP and radioactivity deficiency of²³⁴Th in their vertical profiles. The deviation was similar to that between the chlorophylla and phaeo-pigments contents including their maximum depths.     

A practical method for the simultaneous determination of234Th,226Ra,210Pb and210Po in seawater

A practical method has been developed for the simultaneous determination of²²⁶Ra,²³⁴Th,²¹⁰Pb and²¹⁰Po in seawater. In the method, the samples are spiked with²²⁸Ra,²³⁰Th,²⁰⁸Po and common lead to determine chemical yield. These nuclides are coprecipitated with calcium carbonate and ferric hydroxide from 20 to 50 l of seawater and separated from one another by using coprecipitation and ion exchange techniques. Counting sources of Ra and the other nuclides are prepared by electrodeposition onto silver discs. Their radioactivities are counted with an-spectrometer and a low background-counter. This method gives a standard deviation of about 5% for replicate determination of²²⁶Ra and the other nuclides.     

Development of new drain method for protection of existing pile foundations from liquefaction effects

Pile foundation as well as other underground structures could be seriously affected by soil liquefaction during strong earthquakes. Damages on pile foundation due to liquefaction can be reduced by implementation of some soil improvement method. Main objective of present study is developing of drain method that can improve the soil in order to mitigate the destructiveness of liquefaction on superstructure supported by pile foundation. Series of shaking table tests were conducted on 2×2 pile foundation and soil model was improved by drains. Configurations of drains around piles, intensity of shaking were one of the parameters that were changing during the tests in order to investigate the response of pile foundation in improved soil condition.Shaking table tests and performed On-site experiment showed the following effects of the new drain method. (1) When the intensity of earthquake motion is 200 gal or less, generation of excess pore water pressure is reduced and the pile bending moment is decreased, (2) when the intensity of earthquake motion is stronger (300 gal or more), drainage effect prevents disappearance of subgrade reaction, and (3) proposed new type of drain can control excess pore water pressure without clogging.     

Hydrogeochemical and isotopic evidence of groundwater salinization in a coastal aquifer: a case study in Jeju volcanic island, Korea

In order to identify the origin of saline groundwater in the eastern part of Jeju volcanic island, Korea, a hydrogeochemical and isotopic study has been carried out for 18 observation wells located in east and southeast coastal regions. The total dissolved solid contents of groundwaters are highly variable (77–21,782 mg/l). Oxygen, hydrogen, sulfur, and strontium isotopic data clearly show that the saline water results from mixing of groundwater with seawater. Strontium isotopic compositions and Br/Cl and I/Cl ratios strongly suggest that the source of salinity is modern seawater intrusion. Hydrogeochemical characteristics based on bivariate diagrams of major and minor ions show that changes in the chemical composition of groundwater are mainly controlled by the salinization process followed by cation-exchange reactions. The highly permeable aquifers at the east coastal region are characterized by low hydraulic gradient and discharge rate and high hydraulic conductivity as compared with other regions. These properties enhance the salinization of groundwater observed in the study area. Based on the Cl, Br, and δ¹⁸O data, seawater was determined to have intruded inland some 2.5 km from the coastline. Considering the poor correlation of sampling depth and Cl concentrations observed, the position of seawater-freshwater interface is not uniformly distributed in the study area, due to heterogeneities of the basaltic aquifers.     

Characteristics of alkenones synthesized by a bloom of emiliania huxleyi in the Bering Sea

We investigated the characteristics of the alkenones produced by a bloom of Emiliania huxleyi in the eastern Bering Sea in 2000. Alkenones were detected in surface waters between 57°N and 63°N, where phosphate concentrations were low and the ammonium/nitrate ratio was high. The total alkenone content (C_37:2, C_37:3, and C_37:4) ranged from 22.0 to 349 μg g⁻¹ in suspended particles and from 0.109 to 1.42 μg g⁻¹ in surface sediments. This suggests that a large proportion of the particulate alkenones synthesized in the surface water rapidly degraded within the water column and/or at the water-sediment interface of the Bering Shelf. The change in the stable carbon isotopic composition (δ¹³C) of C_37:3 alkenone could not be explained only by variation in [CO₂(aq)] in the surface water but also depended on the growth rate of E. huxleyi. The alkenone unsaturation index (U^K′₃₇) was converted into an alkenone “temperature” with three equations [Prahl et al 1988], [Sikes et al 1997] and [Müller et al 1998]; Sikes et al.’s (1997) equation gave the best correlation with the observed sea surface temperature (SST) in the eastern Bering Sea. However, some temperatures estimated by Sikes et al.’s (1997) equation from the U^K′₃₇ varied from the observed SST, possibly because of the rapidly changing rate of alkenone synthesis in the logarithmic growth stage or the low rate of alkenone synthesis when nutrients were limiting. Temperatures estimated from U^K′₃₇ in the surface sediments (6.8-8.2°C) matched the observed SST in September (7-8°C) but differed from the annual average SST of 4 to 5°C, suggesting that most of the alkenone in the eastern Bering Sea was synthesized during limited periods, for instance, in September. The relative amounts of C_37:4 alkenone as proportions of the total alkenones (referred to as C_37:4%) were high, ranging from 18.3 to 41.4%. Low-salinity water (<32 psu) within the study area would have contributed to the high C_37:4% because a negative linear relationship between C_37:4% and salinity was found in this study.     

Application of arsenopyrite geothermometry and sphalerite geobarometry to the Taebaek Pb-Zn(-Ag) deposit at Yeonhwa I mine,Republic of Korea

The Taebaek Pb-Zn(-Ag) deposit of the Yeonhwa I mine, Republic of Korea, occurs in a broadly folded and reverse-faulted terrain of Paleozoic sedimentary rocks: the Taebaeksan basin. The orebodies consist of several thin tabular orebodies of hydrothermal replacement type where they are hosted by carbonate rocks. The Pb-Zn(-Ag) mineralization can be divided into four distinct stages based upon the mode of occurrence of ore minerals, ore textural relationships and their composition. Based on temperatures inferred from arsenopyrite compositions by means of electron microprobe and fluid inclusions, the estimated temperatures for the stages I, II, III and IV reach 330 to 350 °C, 270 to 340 °C, 230 to 250 °C, and <220 °C, respectively. The sulphur activity (atm) of ore formation at the Taebaek deposit was estimated for each stage as 10^–11 to 10^–11.5, 10^–9.5 to 10^–13, 10^–13.5 to 10^–15, and <10^–15, respectively. Even though application of sphalerite geobarometry is problematic because of the absence of good mineral assemblages, sphalerite coexisting with pyrite but not with pyrrhotite was used to estimate the minimum mineralization pressure (about 1 kbar).