In situ study of the $$ R\overline{3} c \to R\overline{3} m $$ orientational disorder in calcite

The temperature dependences of the crystal structure and intensities of the (113) and (211) reflections in calcite, CaCO₃, were studied using Rietveld structure refinements based on synchrotron powder X-ray diffraction data. Calcite transforms from to at about T _c = 1,240 K. A CO₃ group occupies, statistically, two positions with equal frequency in the disordered phase, but with unequal frequency in the partially ordered phase. One position for the CO₃ group is rotated by 180° with respect to the other. The unequal occupancy of the two orientations in the partially ordered phase is obtained directly from the occupancy factor, x, for the O1 site and gives rise to the order parameter, S = 2x − 1. The a cell parameter shows a negative thermal expansion at low T, followed by a plateau region at higher T, then a steeper contraction towards T _c, where the CO₃ groups disorder in a rapid process. Using a modified Bragg–Williams model, fits were obtained for the order parameter S, and for the intensities of the (113) and (211) reflections. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Sediment indicators of meromixis: comparison of laminations, diatoms, and sediment chemistry in Brownie Lake, Minneapolis, USA

Meromixis has several powerful effects on lakes, yet there is no single definitive sediment indicator of meromixis. In this study three sediment indicators of meromixis were compared in Brownie Lake, Minneapolis, Minnesota, a small eutrophic lake that became meromictic around 1925. The results show that in Brownie the onset of laminations and changes in the iron to manganese ratio most likely occurred before the development of permanently anoxic bottom water and that changes in the diatom assemblage occurred later, most likely only when meromixis was well developed.This is the 11th in a series of papers published in this special AMQUA issue. These papers were presented at the 1994 meeting of the American Quaternary Association held 19–22 June, 1994, at the University of Minnesota, Minneapolis, Minnesota, USA. Dr Linda C. K. Shane served as guest editor for these papers.     

Time series surface-wave recovery from pressure gage

Recovery of surface-wave time series from pressure gage data is a time-consuming process and is not customarily carried out. Such information is, however, useful particularly in real-time for warning of freak waves or waves of unusual characteristics. Two simple numerical filters are developed here to serve such purpose. The first method is a linear filter with a built-in window to suppress high-frequency noise. The second method recovers the surface wave by computing the local surface curvature. These filters are very simple and can be programmed into a microprocessor to be integrated into field instrument packages.Both filters have been tested satisfactorily against conventional linear filters using simulated wave data and wave data collected in intermediate water depth. Neither filter requires pre-filtering of noise from raw data, which is commonly required to recover surface-wave information from sub-surface pressure data.     

Ensemble of ground subsidence hazard maps using fuzzy logic

Hazard maps of ground subsidence around abandoned underground coal mines (AUCMs) in Samcheok, Korea, were constructed using fuzzy ensemble techniques and a geographical information system (GIS). To evaluate the factors related to ground subsidence, a spatial database was constructed from topographic, geologic, mine tunnel, land use, groundwater, and ground subsidence maps. Spatial data, topography, geology, and various ground-engineering data for the subsidence area were collected and compiled in a database for mapping ground-subsidence hazard (GSH). The subsidence area was randomly split 70/30 for training and validation of the models. The relationships between the detected ground-subsidence area and the factors were identified and quantified by frequency ratio (FR), logistic regression (LR) and artificial neural network (ANN) models. The relationships were used as factor ratings in the overlay analysis to create ground-subsidence hazard indexes and maps. The three GSH maps were then used as new input factors and integrated using fuzzy-ensemble methods to make better hazard maps. All of the hazard maps were validated by comparison with known subsidence areas that were not used directly in the analysis. As the result, the ensemble model was found to be more effective in terms of prediction accuracy than the individual model.     

Landslide susceptibility mapping using random forest and boosted tree models in Pyeong-Chang,Korea

Landslides susceptibility maps were constructed in the Pyeong-Chang area, Korea, using the Random Forest and Boosted Tree models. Landslide locations were randomly selected in a 50/50 ratio for training and validation of the models. Seventeen landslide-related factors were extracted and constructed in a spatial database. The relationships between the observed landslide locations and these factors were identified by using the two models. The models were used to generate a landslide susceptibility map and the importance of the factors was calculated. Finally, the landslide susceptibility maps were validated. Finally, landslide susceptibility maps were generated. For the Random Forest model, the validation accuracy in regression and classification algorithms showed 79.34 and 79.18%, respectively, and for the Boosted Tree model, these were 84.87 and 85.98%, respectively. The two models showed satisfactory accuracies, and the Boosted Tree model showed better results than the Random Forest model.     

The Devonian–Lower Carboniferous succession in Northwest Peninsular Malaysia

A new stratigraphic nomenclature is proposed for the approximately 600 m thick, mainly clastic transitional sequence between the underlying Mempelam Limestone and overlying Kubang Pasu/Singa Formation in northwest Peninsular Malaysia. This sequence represents shallow marine deposits of the continental margin of the Sibumasu Terrane during the Middle Palaeozoic (Devonian–Carboniferous). It is separated into several formations. The Timah Tasoh Formation is an approximately 76 m sequence consisting of 40 m of laminated tentaculitid shales at the base, containing Monograptus yukonensis Jackson and Lenz and Nowakia (Turkestanella) acuaria Alberti, giving an Early Devonian (Pragian–Emsian) age, and about 36 m of rhythmically interbedded, light coloured argillo-arenites. The Chepor Formation is about 90 m thick and consists mainly of thick red mudstone interbedded with sandstone beds, of Middle to Late Devonian age. A new limestone unit is recognized and named the Sanai Limestone, which contains conodonts of Famennian age. The Binjal Formation consists of red and white mudstone interbedded with sandstone beds showing Bouma sequences. The Telaga Jatoh Formation is 9 m thick and consists mainly of radiolarian chert. The Wang Kelian Formation is composed of thick red mudstone beds interbedded with silty sandstone, and contain fossils indicative of an Early Carboniferous (Visean) age. The succession was deposited on the outer shelf, with depositional environments vertically fluctuating from prodelta to basinal marine. The Devonian–Carboniferous boundary is exposed at Hutan Aji and Kampung Guar Jentik, and indicates a major regressive event during the latest Devonian.     

Reclamation of mine-degraded agricultural soils from metal mining: lessons from 4 years of monitoring activity in Korea

The environmental issues associated with mining have damaged the industry’s substantial global economic value. In particular, the mining industry has a negative legacy of contaminated land. The effective reclamation of contaminated soil is therefore required before former mining land can be further developed for residential and commercial purposes. The objective of this study was to technically evaluate the feasibility of reclamation techniques for agricultural soils contaminated with toxic elements (As, Cd, Cu, Pb, and Zn) associated with metal mining. The reclamation methods investigated were covering without stabilization, covering with stabilization, and exchange with stabilization. The thickness of the soil layer used in covering and exchange was in the range of 30–50 cm. Limestone, furnace slag, and a mixture of limestone and furnace slag were applied as soil amendments. After reclamation, the contamination level in surface tillage soils and crops was monitored regularly. Four years of monitoring data revealed that surface soil contamination levels could be maintained at acceptable levels, although at some sites, the metal levels in crops exceeded legislative limits. Soil reclamation at former mining sites in Korea has not yet been perfected, but the results of this study show that there is potential for safe agricultural operations on large sites in a cost-effective manner, as long as the appropriate control of surface soil contamination and adequate agronomic management is undertaken.     

Late Quaternary Floodplain History of the Brazos River in East-Central Texas

The floodplain along a 75-km segment of the Brazos River, traversing the Gulf Coastal Plain of Texas, has a complex late Quaternary history. From 18,000 to 8500 yr B.P., the Brazos River was a competent meandering stream that migrated from one side of the floodplain to the other, creating a thick layer of coarse-grained lateral accretion deposits. After 8500 yr B.P., the hydrologic regime of the Brazos River changed. The river became an underfit meandering stream that repeatedly became confined within narrow and unstable meander belts that would occasionally avulse. Avulsion occurred four times; first at 8100 yr B.P., then at 2500 yr B.P., again around 500 yr B.P., and finally around 300 yr B.P. The depositional regime on the floodplain also changed after 8500 yr B.P., with floodplain construction dominated by vertical accretion. Most vertical accretion occurred from 8100 to 4200 yr B.P. and from 2500 to 1250 yr B.P. Two major and three minor periods of soil formation are documented in the floodplain sequence. The two most developed soils formed from 4200 to 2500 yr B.P. and from around 1250 to 500 yr B.P. These changes on the floodplain appear to be the result not of a single factor, but of the complex interplay among changes in climate, sediment yield, and intrinsic floodplain variables over time.     

Copper toxicity in the marine copepod Tigropus japonicus: Low variability and high reproducibility of repeated acute and life-cycle tests

The intertidal copeopod Tigriopus japonicus, which is abundant and widely distributed along the coasts of Western Pacific, has been suggested to be a good marine ecotoxicity testing organism. In this study, a series of experiments were conducted to investigate the reproducibility and variability of copper (Cu) sensitivity of T. japonicus so as to evaluate its potential to serve as an appropriate test species. To understand the seasonal variation of Cu sensitivity, individuals of T. japonicus were collected from the field in summer and winter, and subjected to standard 96 h acute (static renewal) toxicity tests. 96 h-LC50 values of T. japonicus collected from the two seasons were marginally different (p = 0.05), with an overall coefficient of variation (CV) of 33%. Most importantly, our results indicated that chronic Cu sensitivity of T. japonicus was highly reproducible. The CVs of intrinsic rates of increase in the population of the control and Cu treatment (10 μg Cu l⁻¹) groups were only 10–11% between 10 runs of a standardised complete life-cycle test. Moreover, different Cu(II) salts generally resulted in a similar 96 h-LC50 value while Cu(I) chloride was consistently slightly less toxic than Cu(II) salts. Given such a high reproducibility of toxic responses, it is advocated to use T. japonicus as a routine testing organism.     

A single mooring system with sag-extensibility and flexural rigidity applied to offshore platform

Floating platform system has been extensively used in ocean exploitation, particularly for a tension-leg platform (TLP) system in deep water. Most of the TLPs are multi-mooring systems, where multi-joints are connected to the tension-legs so that the platform is not allowed to twist freely and may subject to enormous force induced by large incident waves in the weak-direction of the structure. This study aims to exploit a single moored offshore platform system that may attract less force and can be operated with less effort. In our analysis, in addition to mechanical properties of the tether, two important properties are also taken into consideration for the single mooring tether with expanded cross sectional dimension and utilization of stronger material, namely, the sag-extensibility and the flexural rigidity. Finally, the dynamic structural behavior produced by the mechanical effects on the new system is investigated and compared with that of traditional design while the wave-structure interactions of large body are also accounted for. Our study finds that the neglect of sag-extensibility or the flexural rigidity of large, strong mooring cable may result in a conservative but not necessarily safe design.