Biogeochemical evidence of large diapycnal diffusivity associated with the subtropical mode water of the North Pacific

A profiling float equipped with a fluorimeter, a dissolved oxygen (DO) sensor, and temperature and salinity sensors was deployed in the subtropical mode water (STMW) formation region of the North Pacific. It acquired quasi-Lagrangian, 5-day-interval time-series records from March to July 2006. The time-series distribution of chlorophyll showed a sustained and sizable subsurface maximum at 50–100 m, just above the upper boundary of the STMW, throughout early summer (May–July). The DO concentration in this lower euphotic zone (50–100 m) was almost constant and supersaturated in the same period, becoming more supersaturated with time. On the other hand, the DO concentration at 100–150 m near the upper boundary of the STMW decreased much more slowly compared with the main layer of STMW below 150 m, even though oxygen consumption by organisms was expected to be larger in the former depth range. The small temporal variations of DO in the lower euphotic zone and near the upper boundary of the STMW were reasonably explained by downward oxygen transport because of large diapycnal diffusion near the top of the STMW. Assuming that the oxygen consumption rate at 100–150 m was the same as that in the main layer of STMW and compensated by the downward oxygen flux, the diapycnal diffusivity was estimated to be 1.7 × 10⁻⁴ m² s⁻¹. Nitrate transport into the euphotic zone by the same large diffusion was estimated to be 0.8 mmol N m⁻² day⁻¹. All of the transported nitrate could have been used for photosynthesis by the phytoplankton; net community production was estimated to be 5.3 mmol C m⁻² day⁻¹.     

Collapse and fragmentation of rotating magnetized clouds – II. Binary formation and fragmentation of first cores

Subsequent to Paper I, the evolution and fragmentation of a rotating magnetized cloud are studied with use of three-dimensional magnetohydrodynamic nested grid simulations. After the isothermal runaway collapse, an adiabatic gas forms a protostellar first core at the centre of the cloud. When the isothermal gas is stable for fragmentation in a contracting disc, the adiabatic core often breaks into several fragments. Conditions for fragmentation and binary formation are studied. All the cores which show fragmentation are geometrically thin, as the diameter-to-thickness ratio is larger than 3. Two patterns of fragmentation are found. (1) When a thin disc is supported by centrifugal force, the disc fragments into a ring configuration (ring fragmentation). This is realized in a rapidly rotating adiabatic core as  Ω > 0.2τ⁻¹_ff  , where Ω and  τ_ff  represent the angular rotation speed and the free-fall time of the core, respectively. (2) On the other hand, the disc is deformed to an elongated bar in the isothermal stage for a strongly magnetized or rapidly rotating cloud. The bar breaks into 2–4 fragments (bar fragmentation). Even if a disc is thin, the disc dominated by the magnetic force or thermal pressure is stable and forms a single compact body. In either ring or bar fragmentation mode, the fragments contract and a pair of outflows is ejected from the vicinities of the compact cores. The orbital angular momentum is larger than the spin angular momentum in the ring fragmentation. On the other hand, fragments often quickly merge in the bar fragmentation, since the orbital angular momentum is smaller than the spin angular momentum in this case. Comparison with observations is also shown.     

Aenigmatite,sodic pyroxene,arfvedsonite and associated minerals in syenites from Morotu,Sakhalin

Aenigmatite, sodic pyroxene and arfvedsonite occur as interstitial minerals in metaluminous to weakly peralkaline syenite patches in alkali dolerite, Morotu, Sakhalin. Aenigmatite is zoned from Ca, Al, Fe³⁺-rich cores to Ti, Na, Mn, Si-rich rims reflecting the main substitutions Fe²⁺Ti⁴⁺Fe³⁺, NaSiCaAl and Mn²⁺Fe²⁺. Aenigmatite replaces aegirine and ilmenite supporting the existence of a no-oxide field in — T space. In one case aenigmatite has apparently formed by reaction between ilmenite and arfvedsonite. Titanian aegirine (up to 3.0 wt% TiO₂) and Fe-chlorite may replace aenigmatite. Sodic pyroxene occurs as zoned crystals with cores of aegirine-augite rimmed by aegirine and in turn by pale green aegirine containing 93 mol% NaFe³⁺Si₂O₆. Additional substitution of the type NaAlCaFe²⁺ is indicated by significant amounts (up to 6 mol%) of NaAlSi₂O₆. Arfvedsonite is zoned with rims enriched in Na, Fe and depleted in Ca which parallels the variation of these elements in the sodic pyroxenes.The high peralkalinity of the residual liquid from which the mafic phases formed resulted from the early crystallization of microperthite (which makes up the bulk of the syenites) leading to an increase in the Na₂O/(Na₂O+K₂O) and (Na₂O+K₂O)/Al₂O₃ ratios of the remaining interstitial liquid which is also enriched in Ti, Fe, and Mn. Bulk composition of the melt, , temperature and volatile content were all important variables in determining the composition and stability of the peralkaline silicates. in the residual liquid appears to have been buffered by arfvedsonite-aegirine and later by the arfvedsonite-aenigmatite and aenigmatite-aegirine equilibria under conditions of a no-oxide field. An increase in , above that of the alkali buffer reactions, is inferred by an increase of Ti and Mn in aenigmatite rims. The latest postmagmatic vapour crystallization stage of the syenites is marked by extremely low which may have been facilitated by exsolution of a gas phase. Low is supported by the replacement of aenigmatite by titanian aegirine, and the formation of rare Ti-rich garnet with a very low (Ti⁴⁺+Fe³⁺)/(Ti+Fe) ratio of 0.51, associated with leucoxene alteration of ilmenite.     

Comparison of surface current variations observed by TOPEX altimeter with TOLEX-ADCP data

Variations of surface current velocity derived by the TOPEX altimeter are compared with data from Tokyo-Ogasawara Line Experiment (TOLEX)-Acoustic Doppler Current Profiler (ADCP) monitoring for a period from October 1992 to July 1993. Since the locations of ADCP ship track and TOPEX altimeter ground tracks do not coincide with each other, and the temporal and spatial sampling are also different between the ADCP and altimeter observations, re-sampling, interpolation and smoothing in time and space are needed to the ADCP and altimeter data. First, the interpolated TOPEX sea surface height is compared with sea level data at Chichijima in the Ogasawara Islands. It is found that aliasing caused by the tidal correction error for M2 constituent in the TOPEX data is significant. Therefore, comparison of the TOPEX data with the TOLEX-ADCP data is decided to be made by using cross-track velocity components of the surface current, which are considered to be relatively less affected by the errors in the tidal correction. The cross-track velocity variations derived from the TOPEX sea surface heights agree well with those of the ADCP observations. The altimeterderived velocity deviations associated with transition of the Kuroshio paths coincide with the ADCP data. It is quantitatively confirmed that the TOPEX altimeter is reliable to observe the synoptic variations of surface currents including fluctuations of the Kuroshio axis.     

New type of pycnostad in the western subtropical-subarctic transition region of the North Pacific: Transition Region Mode Water

A new type of pycnostad has been identified in the western subtropical-subarctic transition region of the North Pacific, based on the intensive hydrographic survey carried out in July, 2002. The potential density, temperature and salinity of the pycnostad were found to be 26.5–26.7 σ _θ , 5°–7°C and 33.5–33.9 psu respectively. The pycnostad is denser, colder and fresher than those of the North Pacific Central Mode Water and different from those of other known mode waters in the North Pacific. The thickness of the pycnostad is comparable to that of other mode waters, spreading over an area of at least 650 × 500 km around 43°N and 160°E in the western transition region. Hence, we refer to the pycnostad as Transition Region Mode Water (TRMW). Oxygen data, geostrophic current speed and climatology of mixed layer depth in the winter suggest that the TRMW is formed regularly in the deep winter mixed layer near the region where it was observed. Analysis of surface heat flux also supports the idea and suggests that there is significant interannual variability in the property of the TRMW. The TRMW is consistently distributed between the Subarctic Boundary and the Subarctic Front. It is also characterized by a wide T-S range with similar density, which is the characteristic of such a transition region between subtropical and subarctic water masses, which forms a density-compensating temperature and salinity front. The frontal nature also tends to cause isopycnal intrusions within the pycnostad of the TRMW.     

North Pacific Tropical Water: its climatology and temporal changes associated with the climate regime shift in the 1970s

North Pacific Tropical Water (NPTW) is characterized as a subsurface salinity maximum flowing in the North Equatorial Current and is the main source of salt for the North Pacific. We briefly describe the climatological features of its formation and circulation, and then examine temporal changes in its properties associated with the climate regime shift in the 1970s. We use a variety of data, which include the repeat hydrographic sections along 130°E, 137°E, 144°E and 155°E meridians, the hydrographic data from the Hawaii Ocean Time-series, the World Ocean Atlas 1994, and available gridded data of wind stress and evaporation. The classical idea that NPTW originates from the zone of the highest sea surface salinity at 20°–30°N centered around the international date line and spreads along the isopycnal geostrophic flow patterns is confirmed. Further, it is shown that the meridional extent of NPTW along 137°E is from 10°N to 23°N on average and the highest salinity core lies at about 15°N and 24.0σ_θ, and that the portion of NPTW north (south) of about 15°N originates from the formation region west (east) of the date line. NPTW in the 137°E section changed remarkably associated with the mid-1970s regime shift. North of 15°N NPTW increased both in its salinity and thickness while to the south of 15°N only its salinity increased and its thickness remained unchanged. The westward geostrophic velocity is increased significantly in both the southern and northern parts of NPTW. The northern thickening and speedup and the southern speedup increased NPTW transport across 137°E. The changes in the thermohaline forcing such as evaporation and Ekman salt convergence in the NPTW formation region possibly contributed to the increases in salinity in the southern part of NPTW, but not to that of the northern part. On the other hand, the increased Ekman pumping accounts for the increase of the NPTW inventory and transport at 137°E. The increased salinity of NPTW at 137°E, especially its northern portion, was presumably caused by an increase in its formation rate rather than changes in the sea surface salinity in its formation region; the thicker the NPTW layer is, the saltier is the core that tends to survive the mixing processes.     

Ventilation of the North Pacific subtropical pycnocline and mode water formation

The annual subduction rate of the North Pacific was calculated based on isopycnally averaged hydrographic climatology (HydroBase), high-resolution winter mixed-layer climatology (NWMLC), and various wind stress climatologies from ship reports, numerical weather prediction products, and satellite products. The calculation was performed using Lagrangian coordinates in the same manner as in previous works, except a less smoothed oceanic climatology (HydroBase and NWMLC) was used instead of a World Ocean Atlas. Differences in the wind stress climatologies have very little effect on subduction rate estimates. The subduction rate census for density classes showed peaks corresponding to subtropical mode water (STMW), central mode water (CMW), and eastern subtropical mode water (ESTMW). The deeper mixed layer and the associated sharper mixed-layer fronts in the present climatology resulted in a larger lateral induction, which boosted the subduction rate, especially for the potential density anomaly (σ_θ) range of the lighter STMW (25.0 < σ_θ < 25.2 kg m⁻³) and lighter CMW (26.0 < σ_θ < 26.2 kg m⁻³), compared to previous estimates. The renewal time of permanent pycnocline water was estimated as the volume of water divided by the subduction rate for each σ_θ class: 2–4 years for ESTMW (24.5 < σ_θ < 25.2 kg m⁻³), 2 years for the lighter STMW (25.0 < σ_θ < 25.3 kg m⁻³), 5–9 years for the denser STMW (25.3 < σ_θ < 25.6 kg m⁻³), 10–20 years for the lighter CMW (26.0 < σ_θ < 26.2 kg m⁻³), 20–30 years for the middle CMW (26.2 < σ_θ < 26.3 kg m⁻³), and 60 years or longer for the denser CMW (26.3 < σ_θ < 26.6 kg m⁻³). A comparison of the water volume and subduction rate in potential temperature–salinity (θ–S) space indicated that the upper permanent pycnocline water (25.0 < σ_θ < 26.2 kg m⁻³) was directly maintained by nondiffusive subduction of winter surface water, including STMW and lighter CMW. The lower permanent pycnocline water (26.2 < σ_θ < 26.6 kg m⁻³) may be maintained through the subduction of fresher and colder water from the subarctic–subtropical transition region and subsequent mixing with saltier and warmer water. Diagnosis of the potential vorticity (PV) of the subducted water demonstrated that the low PV of STMW was mainly due to the large subduction rate, whereas that of both ESTMW and CMW was due mainly to the small density advection rate (cross-isopycnal flow). Additionally, a relatively large subduction rate probably contributes to the low PV of part of the lighter CMW (ESTMW) formed in the region around 38°N and 170°W (28°N and 145°W), which is characterized by a relatively thick winter mixed layer and an associated mixed-layer front, causing a large lateral induction rate.     

Correlation between dissolved He concentration and Cl in groundwater at Äspö, Sweden

Tunnel excavation at Äspö Island, Sweden, has caused severe groundwater disturbance, gradually extending deeper into the tunnel as present-day Baltic seawater intrudes through fractures connecting to the surface. However, the paleo-hydrogeochemical conditions have remained in the deep highly saline waters that have avoided mixing. A correlation has been observed between dissolved ⁴He concentration and Cl⁻ ion concentration, measured every two years from 1995 to 2001 at Äspö. Groundwater mixing conditions can be examined by the correlations between 1/Cl, ³⁶Cl/Cl, and ³H concentrations. Subsurface production is responsible for the majority of the ³⁶Cl and excess dissolved ⁴He of interstitial groundwater in fractures. The secular equilibrium ratio of ³⁶Cl/Cl in rock was theoretically estimated to be (5.05 ± 0.82) × 10⁻¹⁴ based on the neutron flux intensity, a value comparable to the measured ³⁶Cl/Cl ratio in rock and groundwater. The degassing crustal ⁴He flux was estimated to be 2.9 × 10⁻⁸  1.3 × 10⁻⁶ (ccSTP/cm²a) using the HTO diffusion coefficient for the Äspö diorite. The ⁴He accumulation rate ranges from 6.8 × 10⁻¹⁰ (for the in situ accumulation rate) to 7.0 × 10⁻⁹ (ccSTP/(g_water · a) considering both ⁴He in situ production and the degassing flux, assuming ⁴He is accumulated constantly in groundwater. By comparing the subsurface ³⁶Cl increase with ⁴He concentrations in groundwater, the ⁴He accumulation rate was determined from data for groundwater arriving at the secular equilibrium of ³⁶Cl/Cl. The ⁴He accumulation rate was found to be (1.83 ± 0.72) × 10⁻⁸ ccSTP/(g_water · a) without determining the magnitude of degassing ⁴He flux.     

Interannual variations in the Hawaiian Lee Countercurrent

The Hawaiian Lee Countercurrent (HLCC) is an eastward surface current flowing against the broad westward flow of the North Pacific subtropical circulation. Analyses of satellite altimeter data over 16 years revealed that the HLCC is characterized by strong interannual variations. The strength and meridional location of the HLCC axis varied significantly year by year. The eastward velocity of the HLCC was higher when the location of the axis was stable. Mechanisms for the interannual variations were explored by analyses of the altimeter data and results from a simple baroclinic model. The interannual variations in the strength of the HLCC did not correlate with those of the wind stress curl (WSC) dipole formed on the leeward side of the Hawaii Islands, although the WSC dipole has been recognized as the generation mechanism of the HLCC. Meridional gradients of the sea surface height anomaly (SSHA) across the HLCC generated by baroclinic Rossby waves propagating westward from the east of the Hawaii Islands were suggested as a possible mechanism for the interannual variations in the HLCC. The spatial patterns in the observed SSHAs were reproduced by a linear baroclinic Rossby wave model forced by wind fields from a numerical weather prediction model. Further analysis of the wind data suggested that positive and negative anomalies of WSC associated with changes in the trade winds in the area east of the Hawaii Islands are a major forcing for generating SSHAs that lead to the HLCC variations with a time lag of about 1 year.