Petrography, chemistry and genesis of phosphorite concretions in the Eocene Umm Rijam Chert limestone Formation, Ma'an area, south Jordan

Phosphorite concretions are recorded for the first time within the lower part of the Umm Rijam Chert Limestone Formation (Eocene) in the Ma'an area, southern Jordan. The phosphorite concretions are typically hosted and encountered as individual layer in moderately lithified sediments of marl, chalk and chalky marl. The phosphorite concretions are present in thin layer (10–30 cm thick). They are localized on a hardground surface that formed as a result of cementation of soft ground by bioclastic materials. Light grey and brownish to black colors are encountered with isometric, ellipsoid, elongated, subangular to subrounded phosphorite concretions (up to 6 cm in length). Most of the phosphorite concretions preserve bioturbation structures; they also include fecal pellets of various sizes. The main biogenic components are fragments of macrofossils (bivalves) and microfossils (planktonic foraminifera) in different proportions. Petrographic examinations reveal that the phosphorite concretions are composed of cryptocrystalline apatite that characteristically appears in cross-polarized light almost as isotropic phosphate and minor anisotropic phosphate. Apatite and calcite are the main mineral constituents of the phosphorite concretions identified by XRD. The apatite is identified as francolite (carbonate-flour-apatite). Chemical analyses of the phosphorite concretions using X-ray florescence indicate that the P₂O₅ content ranges from 18.8 to 31.19%, whereas SEM–EDS analyses indicate that the phosphorus proportion is around 14% by volume. It could be argued that the phosphorite concretions were transported after being reworked, or were derived from carbonate and chalk pebbles that were later phosphatized and subjected to erosion, forming residual lag deposit along the hardground surface.     

Seismic demand sensitivity of reinforced concrete shear‐wall building using FOSM method

The uncertainty in the seismic demand of a structure (referred to as the engineering demand parameter, EDP) needs to be properly characterized in performance‐based earthquake engineering. Uncertainties in the ground motion and in structural properties are responsible for EDP uncertainty. In this study, sensitivity of EDPs to major uncertain variables is investigated using the first‐order second‐moment method for a case study building. This method is shown to be simple and efficient for estimating the sensitivity of seismic demand. The EDP uncertainty induced by each uncertain variable is used to determine which variables are most significant. Results show that the uncertainties in ground motion are more significant for global EDPs, namely peak roof acceleration and displacement, and maximum inter‐storey drift ratio, than those in structural properties. Uncertainty in the intensity measure (IM) of ground motion is the dominant variable for uncertainties in local EDPs such as the curvature demand at critical cross‐sections. Conditional sensitivity of global and local EDPs given IM is also estimated. It is observed that the combined effect of uncertainties in structural properties is more significant than uncertainty in ground motion profile at lower IM levels, while the opposite is true at higher IM levels. Copyright © 2005 John Wiley & Sons, Ltd.     

Strain localization in clay: plane strain versus triaxial loading conditions

The paper presents a comparison between the behavior of slurry-consolidated Kaolin specimens tested under axisymmetric Conventional Triaxial Compression (CTC) and Plane Strain (PS) loading conditions. The PS experiments were conducted on an instrumented apparatus capable of capturing the onset of shear bands. The specimens were consolidated and then sheared under undrained condition. The PS specimens failed via a well-defined shear band that began to develop during the hardening stress regime whereas CTC specimens failed through a diffuse bulging mode. The undrained shear strength (S _u) of CTC experiments is smaller than the S _u of PS experiments. However, the normalized S _u of CTC experiments is very close to PS1, which was consolidated under similar K _o condition.     

Organochlorine micropollutants in the Jiulong River Estuary and Western Xiamen Sea, China

Organochlorine contaminants including 12 polychlorinated biphenyl (PCB) congeners and 18 insecticides were determined in water, pore water and sediments of the Jiulong River Estuary and Western Xiamen Sea, China. The results showed that the levels of the total PCBs ranged from non-detectable to 1500 ng l⁻¹ in water, from 209 to 3870 ng l⁻¹ in pore water, and from 2.78 to 14.8 ng g⁻¹ dry weight in sediments. Total organochlorine insecticide concentrations were from below the limit of detection to 2480 ng l⁻¹ in water, from 267 to 33400 ng l⁻¹ in pore water, and from 4.22 to 46.3 ng g⁻¹ dry weight in sediments. Concentrations of PCBs and insecticides in pore water were significantly higher than those in surface water, due to the high affinity of these hydrophobic compounds for sediment phase. The PCB congeners with the highest concentrations were CB153, CB180 and CB194, which together accounted for 68–87% of total PCBs in water, pore water and sediment. Among the hexachlorocyclohexane (HCH) compounds, beta-HCH was found to be a major isomer. Analysis of 1,1,1-trichloro-2,2-bis-chlorophenyl-ethane (DDT) and its metabolites showed that 1,1-dichloro-2[o-chlorophenyl]-2[p-chlorophenyl]-ethylene (DDE) was dominant in the group. In comparison to a 1998 study in the Western Xiamen Sea, levels of organochlorines were enhanced due probably to recent inputs and changes in sediments.     

Mixture distributions - an alternative approach for estimating maximum magnitude earthquake occurrence

Summary. Gumbel's theory of extreme value has been employed in the statistical forecasting of maximum-magnitude earthquake occurrence. The basic working hypothesis behind this method assumes that observations follow either Gumbel type I or type III asymptotic distributions. In certain cases, however, it is found that neither type of distribution fits the data well enough to produce accurate parameter-estimates, particularly in the larger earthquake range. This article proposes an alternative approach based on finite-mixture distributions whereby a more realistic prediction of upper earthquake magnitudes (at given return periods) is expected using a combined analysis of both Gumbel types I and III extremal distributions.     

Spectroscopic characterization of fulvic acids extracted from the rock exudate Shilajit

The present work describes the extraction of fulvic acids (FA) from Shilajit and its spectroscopic and mass spectrometric characterization. The spectral features obtained from FT-IR and ¹HNMR were similar to those reported for humic substances from other sources. The molecular elemental composition analysis by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) in electrospray negative ion mode resulted in extraordinary high average O/C ratios (0.55) which might be caused by a significant contribution of carbohydrates in Shilajit. A very high average H/C ratio of 1.27 also points to dominant aliphatic or alicyclic structures and relatively low aromaticity. The average molecular formula of the nitrogen free elemental compositions measured by FT-ICR mass spectrometry is C_18.2H_23.0O_10.0.     

Network-constrained and category-based point pattern analysis for Suguo retail stores in Nanjing,China

The distribution of many geographical objects and events is affected by the road network; thus, network-constrained point pattern analysis methods are helpful to understand their space structures and distribution patterns. In this study, network kernel density estimation and network K-function are used to study retail service hot-spot areas and the spatial clustering patterns of a local retail giant (Suguo), respectively, in Nanjing city. Stores and roads are categorized to investigate the influence of weighting different categories of point events and network on the analysis. In addition, the competitive relation between Suguo and foreign-brand retail chains was revealed. The comprehensive analysis results derived from the combination of the first-order and second-order properties can be further used to examine the reasonability of the existing store distribution and optimize the locational choice of new stores.