Acigöl rhyolite field,Central Anatolia (part 1): high-resolution dating of eruption episodes and zircon growth rates

Protracted pre-eruptive zircon residence is frequently detected in continental rhyolites and can conflict with thermal models, indicating briefer magma cooling durations if scaled to erupted volumes. Here, we present combined U-Th and (U-Th)/He zircon ages from the Acigöl rhyolite field (Central Anatolia, Turkey), which is part of a Quaternary bimodal volcanic complex. Unlike other geochronometers, this approach dates crystallization and eruption on the same crystals, allowing for internal consistency testing. Despite the overall longevity of Acigöl rhyolite volcanism and systematic trends of progressive depletion in compatible trace elements and decreasing zircon saturation temperatures, we find that zircon crystallized in two brief pulses corresponding to eruptions in the eastern and western part of the field during Middle and Late Pleistocene times, respectively. For Late Pleistocene zircon, resolvable differences exist between interior (average: 30.7 ± 0.9 ka; 1σ error) and rim (21.9 ± 1.3 ka) crystallization ages. These translate into radial crystal growth rates of ~10^?13 to 10^?14 cm/s, broadly consistent with those constrained by diffusion experiments. Rim crystallization and (U-Th)/He eruption ages (24.2 ± 0.4 ka) overlap within uncertainty. Evidence for brief zircon residence at Acigöl contrasts with many other rhyolite fields, suggesting that protracted zircon crystallization in, or recycling from, long-lived crystal mushes is not ubiquitous in continental silicic magma systems. Instead, the span of pre-eruptive zircon ages is consistent with autochthonous crystallization in individual small-volume magma batches that originated from basaltic precursors.     

Levels of Organohalogenated Pollutants in Human Milk Samples from Konya City,Turkey

This study reports the levels of organochlorine pesticides (OCPs, α‐, β‐, γ‐ and Δ‐HCHs, p,p′‐DDE, p,p′‐DDD and p,p′‐DDT), polychlorinated biphenyls (PCBs, PCB 28, 52, 101, 153, 138 and 180 congeners) and polybrominated diphenyl ethers (PBDEs, PBDE 47, 99, 100, 153 and 154 congeners) in 45 individual human milk samples collected from Konya City, Turkey. Average concentrations of ΣHCHs, ΣDDTs, ΣPCBs and ΣPBDEs were 22.62, 37.10, 104.95 and 67.34 ng/g lipid wt., respectively. No significant differences in investigated pollutants were found between primiparous and multiparous mothers. There was no correlation between levels of each group of pollutants in human milk and the age of mothers. Moreover, there was no significant difference in the levels of ΣDDTs, between mothers who have eaten fish more than once a week and those who consumed fish less than once. An analysis of the infant exposure to DDTs, HCHs and PCBs via mother's milk indicated that the estimated daily intakes of these pollutants were below the guideline proposed by the World Health Organization (WHO) and the Health Canada which means that there is definitely no concern on children health.     

Increasing numerical efficiency of iterative solution for total least-squares in datum transformations

Cartesian coordinate transformation between two erroneous coordinate systems is considered within the Errors-In-Variables (EIV) model. The adjustment of this model is usually called the total Least-Squares (LS). There are many iterative algorithms given in geodetic literature for this adjustment. They give equivalent results for the same example and for the same user-defined convergence error tolerance. However, their convergence speed and stability are affected adversely if the coefficient matrix of the normal equations in the iterative solution is ill-conditioned. The well-known numerical techniques, such as regularization, shifting-scaling of the variables in the model, etc., for fixing this problem are not applied easily to the complicated equations of these algorithms. The EIV model for coordinate transformations can be considered as the nonlinear Gauss-Helmert (GH) model. The (weighted) standard LS adjustment of the iteratively linearized GH model yields the (weighted) total LS solution. It is uncomplicated to use the above-mentioned numerical techniques in this LS adjustment procedure. In this contribution, it is shown how properly diminished coordinate systems can be used in the iterative solution of this adjustment. Although its equations are mainly studied herein for 3D similarity transformation with differential rotations, they can be derived for other kinds of coordinate transformations as shown in the study. The convergence properties of the algorithms established based on the LS adjustment of the GH model are studied considering numerical examples. These examples show that using the diminished coordinates for both systems increases the numerical efficiency of the iterative solution for total LS in geodetic datum transformation: the corresponding algorithm working with the diminished coordinates converges much faster with an error of at least 10^-5 times smaller than the one working with the original coordinates.     

Analysis of faulting in porous sandstones

Faults in porous sandstones occur in three forms: deformation bands about 1-mm thick and tens of m long and across which offsets are a few mm; zones of deformation bands constituted of many closely spaced deformation bands across which offsets are a few cm or dm; and slip surfaces, that is, distinct surfaces within zones of deformation bands across which offsets are a few m to a few tens of m. Deformation bands represent highly localized deformation; analogous localization within a field of homogeneous deformation is theoretically possible in inelastic materials with certain ranges of constitutive parameters. Crushing and consolidation of sandstone within a band cause the material there to become stiffer than the surrounding porous sandstone. A zone of deformation bands behaves mesoscopically much as a stiff inclusion in a soft matrix. According to the constitutive model assumed to investigate the formation of deformation bands, an instability can develop, and strain increments within the zone of deformation bands can become boundlessly large when the far-field stresses reach critical values. This instability is here associated with the formation of slip surfaces.     

Water Quality and Phosphorus Budget of Mogan Lake,Turkey

Mogan Lake is the largest recreational area near Ankara, which is the capital city of Turkey. Increased macrophyte growth in the water body and the present levels of urban development within the catchment are reflected in declining water quality and aesthetic deterioation. A study of the water quality of the lake was undertaken to quantify the variation of phosphorus, nitrogen, and chlorophyll-a concentrations during ice-free seasons from 1992 to 1994. Its total phosphorus and chlorophyll-a concentrations indicate a meso-eutrophic status. The total phosphorus budget of Mogan Lake was measured for a period of 22 months. The estimation of nutrient loading using Dillon-Rigler nutrient budget shows that an artificial load caused too high phosphorus inputs. The management implications of phosphorus loading and budget are discussed.     

Fracture void structure: implications for flow, transport and deformation

 This review focuses on studies of flow, transport and deformation processes at a scale of a single discontinuity. The paper provides an evaluation of: (1) various methods suggested for geometrical characterization of void structure; and (2) theoretical and practical problems arising from significant differences between the actual geometry of fracture void structure and its parallel plate representation. The use of an equivalent aperture concept is shown to be seriously misleading in: (a) evaluation of flow regime, and hence selection of appropriate flow laws; (b) correlating tracer and hydraulic tests, and assessment of solute transport properties; and (c) relating hydraulic and mechanical apertures, and predicting influence of stress perturbation and deformability. Received: 2 August 1999 · Accepted: 30 November 1999     

Microstructural study of a natural slip zone: quantification and deformation history

Microstructure of a natural slip zone was comprehensively examined using a combination of images captured systematically by optical microscopy (OPM) and backscattered electron microscopy (BEM) techniques. Microstructural features identified on these images were processed and evaluated using an advanced image analysis system, which proved that quantitative analyses could considerably enhance the understanding of shear behavior of slip zones. It was found that variations of porosity, abundance of platy clay particles and alignments of particles are significant indicators revealing nature of deformation processes. These indicators show that global mechanical behavior of the investigated slip zone can be conceptualized as that of normally consolidated clayey soils under drained conditions.

The geometric patterns of the microstructure of the slip zone are similar to the S–C fabrics seen in tectonic shear zones. It is suggested that combined progressive bulk simple shear and pure shear modes enable to realistically reconstruct the kinematic history of the slip zone, through which particle movements and microstructural evolution were accomplished via various types of particulate flows. The results of this study show that clay mineralogy plays a more important role in the development of the slip zone than abundance of clay-size particles, while both clay mineralogy and relative proportions of each particle size fraction control the response of particles to shear deformation. Among the fractions present in the slip zone, fine silts are the strongest indicator of global shear stress characterized by their highest degree of alignment, whereas clay particles are the weakest. Highest degree of shape preferred orientation is also found within fine silt domains.