Sound velocity and elastic properties of Fe–Ni and Fe–Ni–C liquids at high pressure

The sound velocity (V _P) of liquid Fe–10 wt% Ni and Fe–10 wt% Ni–4 wt% C up to 6.6 GPa was studied using the ultrasonic pulse-echo method combined with synchrotron X-ray techniques. The obtained V _P of liquid Fe–Ni is insensitive to temperature, whereas that of liquid Fe–Ni–C tends to decrease with increasing temperature. The V _P values of both liquid Fe–Ni and Fe–Ni–C increase with pressure. Alloying with 10 wt% of Ni slightly reduces the V _P of liquid Fe, whereas alloying with C is likely to increase the V _P. However, a difference in V _P between liquid Fe–Ni and Fe–Ni–C becomes to be smaller at higher temperature. By fitting the measured V _P data with the Murnaghan equation of state, the adiabatic bulk modulus (K _S0) and its pressure derivative (K _S ^′ ) were obtained to be K _S0 = 103 GPa and K _S ^′  = 5.7 for liquid Fe–Ni and K _S0 = 110 GPa and K _S ^′  = 7.6 for liquid Fe–Ni–C. The calculated density of liquid Fe–Ni–C using the obtained elastic parameters was consistent with the density values measured directly using the X-ray computed tomography technique. In the relation between the density (ρ) and sound velocity (V _P) at 5 GPa (the lunar core condition), it was found that the effect of alloying Fe with Ni was that ρ increased mildly and V _P decreased, whereas the effect of C dissolution was to decrease ρ but increase V _P. In contrast, alloying with S significantly reduces both ρ and V _P. Therefore, the effects of light elements (C and S) and Ni on the ρ and V _P of liquid Fe are quite different under the lunar core conditions, providing a clue to constrain the light element in the lunar core by comparing with lunar seismic data.     

Eocene extensional tectonics in the Amakusa region,northern Ryukyu arc

Paleogene surface tectonics in Japan is not well understood because of the paucity of onshore Paleogene stratigraphic records except for those from accretionary complexes. Paralic Paleogene formations remaining in SW Japan are usually so thin that it is difficult to decipher the tectonics from them. However, the Eocene paralic sedimentary package with a thickness of kilometers indicates syn-depositional tectonic subsidence by a few kilometers in the Amakusa archipelago, west of Kyushu Island. Thus, we made a detailed geological map of the Eocene formations in an area of ~50 square kilometers in the northwestern part of the archipelago. We identified NE-SW and NW-SE trending normal faults, most of which were recognized by previous researchers, and also discovered low-angle faults. NW-SE trending ones are known to be of the Miocene. NE-SW trending and low-angle normal faults are the oldest map-scale structures in the Eocene ones. It is not obvious within the above-mentioned area whether those normal faults are accompanied by growth strata. However, the significant southeastward thickening of the Eocene formations across the Amakusa archipelago suggests that they filled a large half graben with the basin margin fault along the eastern side of the archipelago. This basin model is consistent with the N-S to NW-SE transport directions of the low-angle and NE-SW trending normal faults. Since many NE-SW to EW trending Eocene grabens were formed in the offshore regions west of Kyushu Island and in the East China Sea, the Amakusa region was probably a northeastern branch of the rift system. The geologic structures and depositional ages of the Eocene formations indicate that the Eocene extensional tectonics removed the overlying strata to some extent for the high-P/T Takahama Metamorphic Rocks which crops out to the south of our study area.     

Review on observational studies of western tropical Pacific Ocean circulation and climate

The Western Tropical Pacific(WTP) Ocean holds the largest area of warm water(28℃) in the world ocean referred to as the Western Pacific Warm Pool(WPWP),which modulates the regional and global climate through strong atmospheric convection and its variability.The WTP is unique in terms of its complex 3-D ocean circulation system and intensive multiscale variability,making it crucial in the water and energy cycle of the global ocean.Great advances have been made in understanding the complexity of the WTP ocean circulation and associated climate impact by the international scientific community since the 1960 s through field experiments.In this study,we review the evolving insight to the 3-D structure and multi-scale variability of the ocean circulation in the WTP and their climatic impacts based on in-situ ocean observations in the past decades,with emphasis on the achievements since 2000.The challenges and open que stions remaining are reviewed as well as future plan for international study of the WTP ocean circulation and climate.     

Geochemical characteristics of zircons in the Ashizuri A‐type granitoids: An additional granite topology tool for detrital zircon studies

Zircon is resistant to alteration over a wide range of geological environments, and isotopic ratios within the mineral provide constraints on ages and their parental magmas. Trace element compositions in zircon are also expected to reflect those of their parent magmas, and have a potential as essential indicators for their host rocks. Because most detrital zircons that accumulate at river mouths are derived primarily from granitoids, the classification of zircon within granitoids is potentially meaningful. This study employs the conventional classification scheme of granites (I‐, S‐, M‐, and A‐types). To clarify geochemical characteristics of zircons in A‐type granites, trace element compositions of zircons extracted from the A‐type Ashizuri granitoids were examined. Zircons from the Ashizuri granitoids commonly show enrichments of heavy rare earth elements and positive Ce anomalies, indicating that these zircons were igneous in origin. In addition, zircons in these A‐type granites are characterized by enrichments of Nb, Y, Ta, Th, and U and strong negative Eu anomalies, which exhibit good positive correlations with those in their whole rocks. This fact indicates that these signatures in zircons reflect well those in their parental bodies and are useful in identifying zircons derived from A‐type granite. Based on compilations of available data, zircons from A‐type granites can be clearly discriminated from other‐types of granites within Nb/Sr–Eu anomaly, U/Sr–Eu anomaly, Nb/Sr–U/Sr, and Nb/Sr–Ta/Sr cross‐plots. All indices used in these diagrams were selected based on the geochemical features of both zircon and whole rock of A‐type granites. Application of these discrimination diagrams to detrital zircons will likely provide further insights. For example, some Hadean detrital zircons plot in similar fields to A‐type granites, implying the existence of A‐type magmatism in the Earth's earliest history.     

CFC Indicating Renewal of the Japan Sea Deep Water in Winter 2000–2001

The distributions of CFC (chlorofluorocarbon) in the water column was determined twice in 2000 and 2001 in the northwestern Japan Sea. In 2000 the CFC-11 concentration decreased almost exponentially with depth from 6 pmol/kg at a few hundred m deep to 0.3 pmol/kg or less at the bottom of about 3400 m depth at three stations (40–41°N, 132–133°E) about 300 km off Vladivostok. In 2001 the CFC-11 concentration increased sharply up to 2 pmol/kg in the bottom water, while it did not increase at a station (42.0°N, 136.5°E) about 450 km away to the northeast. This is due to the renewal of the bottom water which is replaced by the surface water flowing down along the continental slope, as suggested by Tsunogai et al. (1999), who proposed the continental shelf pump. Furthermore, an increase in the CFC-11 concentration was observed throughout the entire water column above 3000 m depth, although the proportion of the increase was about 20%, which was one order of magnitude smaller than that in the bottom water. The increase in inventory is almost four times larger than that in the bottom water below 3000 m depth which is equivalent to about 1/6 of the total inventory found in 2000. The increase also means that 3% of the deep water was replaced by the recent surface water, or, if the turnover occurs every year, that the turnover time of the deep water to be about 30 years. This revised version was published online in July 2006 with corrections to the Cover Date.     

Fractional-order derivative and time-dependent viscoelastic behaviour of rocks and minerals

A general constitutive equation for viscoelastic behaviour of rocks and minerals with fractional-order derivative is investigated. This constitutive law is derived based on differential geometry and thermodynamics of rheology, and the fractional order of derivative represents the degree of time delay. Analyzing some laboratory experimental data of high temperature deformation of rocks and minerals such as halite, marble and orthopyroxene, we propose how to determine the orders of fractional derivative for viscoelastic behaviours of rocks and minerals. The order is related to the exponents for the temporal scaling in the relaxation modulus and the stress power-law of strain rate, i.e., the non-Newtonian flow law, and considered as an indicator representing the macroscopic behaviour and microscopic dynamics of rocks.     

Three‐dimensional microstructure of samples recovered from asteroid 25143 Itokawa: Comparison with LL5 and LL6 chondrite particles

In this study, the three‐dimensional (3‐D) microstructure of 48 Itokawa regolith particles was examined by synchrotron microtomography at SPring‐8 during the preliminary examination of Hayabusa samples. Moreover, the 3‐D microstructure of particles collected from two LL6 chondrites (Ensisheim and Kilabo meteorites) and an LL5 chondrite (Tuxtuac meteorite) was investigated by the same method for comparison. The modal abundances of minerals, especially olivine, bulk density, porosity, and grain size are similar in all samples, including voids and cracks. These results show that the Itokawa particles, which are surface materials from the S‐type asteroid Itokawa, are consistent with the LL chondrite materials in terms of not only elemental and isotopic composition of the minerals but also 3‐D microstructure. However, we could not determine whether the Itokawa particles are purely LL5, LL6, or a mixture of the two. No difference between the particles collected from Rooms A and B of the sample chamber, corresponding to the sampling sequence of the spacecraft's second and first touchdowns, respectively, was detected because of the statistically small amount of particles from Room B.     

Detection of Pacific tropical water variability by taut-line moorings in the western equatorial Pacific

This study uses temperature and salinity time series acquired with taut-line moorings in the western equatorial Pacific to investigate water mass behavior on the thermocline layer. Basically, it is insufficient to trace water mass variation by the original discrete depth coordinate data because of relatively high variability of density at fixed depth near the thermocline. A reconstruction method based on the density surface motion caused by tidal forcing was used to derive continuous profiles of temperature and salinity from vertically discrete measurements at fixed depths. This method can represent detailed vertical salinity structures and their variation, especially along the potential density surface of 24.8σ_θ, where the salinity maximum of South Pacific tropical water (SPTW) appeared. Variability around the 24.8σ_θ surface at each site was as large as that observed at the surface, which suggests a strong influence of SPTW behavior. High salinity along the 24.8σ_θ surface within the equatorial band of the western Pacific appeared during boreal fall-winter at sites far from New Guinea. In contrast, high salinity appeared near New Guinea during the boreal spring-summer. These features suggest the influence of the New Guinea Coastal Undercurrent. Over longer time scales, several higher salinity events were observed. The most pronounced salinity event occurred during 2007–2008. Interannual variation of the salinity anomaly along the 24.8σ_θ surface was negatively correlated with the Niño 3.4 sea surface temperature anomaly. A long-term salinity anomaly shift from negative to positive occurred around the end of 2002. The relationship with decadal variation in subtropical cell transport is also discussed.     

Two Modes of Salinity and Temperature Variation in the Surface Layer of the Pacific Warm Pool

The characteristics of temperature and salinity variation in the Pacific warm pool were investigated using Empirical Orthogonal Function (EOF) analysis on one year's temperature and salinity data in the surface layer (0–50 m) obtained from the Triangle Trans-Ocean Buoy Network (TRITON) buoy array. Two dominant modes of surface temperature and salinity variation were found. One is a positive correlation mode where temperature and salinity were scattered almost parallel to isopycnal lines in a T-S diagram, which has little effect on the density field. The other is a negative correlation mode where temperature and salinity were distributed across isopycnal lines, which has a substantial impact on the density field. In particular, we found that the negative correlation mode at 5°N, 156°E was predominant on a seasonal time scale and contributed to the surface dynamic height variation, and therefore to surface geostrophic current. This revised version was published online in July 2006 with corrections to the Cover Date.     

Primary productivity in the fast ice area near syowa station,Antarctica, during spring and summer 1983/84

In situ measurements of the primary productivity of ice algae and phytoplankton were carried out in the fast ice area near Syowa Station (69°00S, 39°35E) during the austral spring and summer of 1983/84. Standing stock of ice algae reached a maximum of 45.1 mg chla m^–2 in late October. Phytoplankton standing stock attained a value of 3.57 mg chla m^–2 in mid-January. Primary production of ice algae in late October (7.64 mgC m^–2 hr^–1) was 14 times greater than that in mid-January (0.54 mgC m^–2 hr^–1). Production in the water column in mid-January (3.46 mgC m^–2 hr^–1) was 50 times greater than that in late October (0.07 mgC m^–2 hr^–1). These results indicate a substantial production by ice algae in the spring and by phytoplankton in the summer period.