Equation of state of hexagonal aluminous phase in basaltic composition to 63 GPa at 300 K

A laser-heated diamond-anvil cell that is capable of operating up to a pressure of 63 GPa, with X-ray diffraction facilities using a synchrotron radiation source at the SPring-8, has been developed to observe the compressibility of a hexagonal aluminous phase, [K_0.15Na_1.66Ca_0.11Mg_1.29Fe²⁺ _0.86Al_3.13Ti_0.09Si_1.98] _Σ9.27O₁₂. The hexagonal aluminous phase is a potassium host mineral from the subducted oceanic crust in the Earth's lower mantle. A sample was heated using a YAG laser at each pressure increment to relax the deviatoric stress in the sample. X-ray diffraction measurements were carried out at 300 K using an angle-dispersive technique. Pressure was measured using an internal platinum pressure calibrant. The observed unit-cell volumes were used to obtain a third-order Birch–Murnaghan equation of state: unit-cell volume V _o=185.94(±16) ų, density ρ _o=4.145 g/cm³, and bulk modulus K _o=198(±3) GPa when the first pressure is derivative of the bulk modulus K ^′ _o is fixed to 4. The density of hexagonal aluminous phase is lower than that of coexisting Mg-perovskite in the subducted oceanic crust.     

Temporal and spatial variability of cobalt in the Atlantic Ocean

The spatial and temporal variability of cobalt in the Atlantic Ocean was investigated by means of adsorptive cathodic stripping voltammetry. A vertical profile of total dissolved cobalt at the Bermuda Atlantic Time Series station ranged from 17 to 73 pM and displayed surface depletion indicative of biological utilization. This profile when compared with a cobalt profile from the northeast Pacific shows no increase in deep-water concentrations with thermohaline circulation through the deep ocean basins. Moreover, the middepth maximum observed in northeast Pacific profiles is not present in the Sargasso Sea, perhaps because of the lack of cobalt scavenging by particulate manganese oxides in surface waters and to the absence of a suboxic oxygen minimum zone, which, if present, could dissolve the manganese oxides.Total dissolved cobalt measurements were also made on a surface transect from the Sargasso Sea to coastal Massachusetts, USA, and on time-series samples from the Moored In Situ Trace Element Serial Sampler. Dissolved cobalt on this transect correlated strongly with salinity (r² = 0.93) and ranged from 19 to 133 pM, indicating mixing of cobalt from shelf waters into the Sargasso Sea. Time-series samples near Bermuda did not show an obvious response to the summer maximum in aeolian dust deposition, with an annual average of 20 ± 10 pM at 40- to 47-m depths. By use of this annual value and particulate cobalt data from the literature, 100-m surface-water residence times were calculated to be as low as 0.32 yr for cobalt. Several sharp decreases in cobalt were observed in the time series that occurred simultaneously with a shallowing of the thermocline depth. These decreases could be caused by nutrient drawdown associated with higher productivity mesoscale eddy events.A west-east surface transect across the South Atlantic showed high cobalt concentrations at the boundaries of the transect and low concentrations in the center despite the high precipitation rates in the intertropical convergence zone. Phosphate measurements showed the similar trends as the total cobalt transect. A regression of cobalt vs. phosphate reveals a slope that is an order of magnitude higher than that of the northeast Pacific and that is similar to the slopes observed for zinc vs. phosphate in the Pacific.     

Observation of core discing and in situ stress measurements; Stress criteria causing core discing

Summary Core discing was typically observed in cores recovered from near horizontal holes drilled in Palaeogene sandstones at a depth of 1055 m in the Horonai colliery, Hokkaido, Japan. We have observed disc- and ring-like cores and measured in situ stress where they were recovered. We compared the measured stress state with an empirical criterion of core discing based on Obert and Stephenson (1965) and a theoretical criterion based on Sugawara et al. (1978) and Ishida and Saito (1989). Consequently, we found that disc-like cores were recovered under lower stress state than predicted by both criteria. The stress state where ring-like cores were recovered satisfied the empirical criterion, however, it was below the critical stress state according to the theoretical criterion. These discrepancies indicate that existing stress criteria are not satisfactory and that further experimental, theoretical and field investigations are needed.     

Vibrations of beams with an absorber consisting of a viscoelastic solid and a beam

This paper considers the response of a beam with a dynamic vibration absorber, which consists of a viscoelastic solid and a double-cantilever viscoelastic beam, attached to the centre of the main beam. The ends of the main beam are built in and excited sinusoidally by the base motion. The transfer matrix method is used in the analysis. The displacement transmissibility, i.e. the ratio of the displacement at the centre of the main beam to that of the base is investigated in the numerical example. It is shown that the present absorber is effective to suppress several resonances of the main beam simultaneously by only one compact device. Values of the optimum tuning design parameters are presented in the numerical example.     

济州岛西南泥质区近2300 a来环境敏感粒度组分记录的东亚冬季风变化

对位于东海陆架济州岛西南泥质区的B2孔进行了沉积物粒度分析, 从中提取出了对沉积环境变化敏感的粒度组分. 研究表明该敏感组分的粒级含量和平均粒径变化主要受东亚冬季风的强弱变化制约. 根据以上粒度指标与AMS14C测年相结合建立了近2300 a东亚冬季风高分辨率的时间变化序列. 结果表明近2300 a东亚冬季风变化和中国东部气候变化序列有较好的一致性, 可以划分为四个阶段: 1900 aBP (50 AD)以前和1450 ~ 780 aBP (500 ~ 1170 AD)这两个阶段东亚冬季风相对较弱, 与气候变化的暖期相对应; 1900 ~ 1450 aBP (50 ~ 500 AD)和 780 ~ 219 aBP (1170 ~ 1731 AD)两个阶段为东亚冬季风强盛期, 与气候变化的冷期对应, 后者为近2300 a以来最寒冷的气候阶段, 对应于小冰期. 其中各阶段内部东亚冬季风有明显的次级波动. 在1900 aBP (50 AD)和780 aBP (1130 AD)前后有两次明显的阶段性的气候由暖转冷突变事件, 后者可能与全球尺度大气环流的改变有关.     

Grazing impact of the copepod community in the Oyashio region of the western subarctic Pacific Ocean

The role of copepod grazing on the ecosystem dynamics in the Oyashio region, western subarctic Pacific was investigated during six cruises from June 2001 to June 2002. In situ grazing rates of the copepod community (CGR) were measured by the gut fluorescence method in respect to developmental stages of dominant species. In terms of biomass, more than 80% of the copepod community was dominated by six large calanoid species (Neocalanus cristatus, Neocalanus flemingeri, Neocalanus plumchrus, Eucalanus bungii, Metridia pacifica and Metridia okhotensis) throughout the year. Resulting from the observed pattern of the interzonal migrating copepods, the CGR in the Oyashio region was divided into three phases, i.e. spring (bloom), summer (post-bloom) and autumn-winter phase. During the spring bloom, late copepodites of the interzonal migrating species, N. cristatus, N. flemingeri and E. bungii appeared in the surface layer (0-50 m) to consume the production of the bloom, resulting in a high grazing rate of the copepod community (7.9 mg Chl m⁻² d⁻¹), though its impact on phytoplankton community was low due to the high primary productivity. During the post-bloom period, although the copepod community which was dominated by N. cristatus, N. plumchrus, M. pacifica and newly recruited E. bungii still maintained a high biomass, the CGR was generally lower (1.8-2.6 mg Chl m⁻² d⁻¹ for June and August 2001), probably due to the lower availability of phytoplankton. Nevertheless, the highest CGR was also observed during this period (10.5 mg Chl m⁻² d⁻¹ in June 2002). The high CGR on autotrophic carbon accounted for 69% of the primary production, suggesting that the copepod community in the Oyashio region potentially terminates the phytoplankton bloom. Abundant occurrence of young E. bungii, which is a characteristic phenomenon in the Oyashio region, was largely responsible for the high grazing pressure in June 2002 suggesting that success of reproduction, growth, and survival in E. bungii during the spring bloom is an important factor in controlling phytoplankton abundance during the post-bloom season. During autumn and winter, CGR was the lowest in the year (0.29-0.38 mg Chl. m⁻² d⁻¹) due to the disappearance of the interzonal migrating copepods from the surface layer. Diel migrant M. pacifica was the most important grazer during this period. The annual ingestion of the copepod community is estimated as 37.7 gC m⁻² on autotrophic carbon (converted using C:Chl ratio of 30) or 137.9 gC m⁻² on suspended particles (using C:Chl ratio of in situ value, 58-191), accounting for 13% and 46% of annual primary production, respectively. This study confirms that copepod grazing is an important pathway in carbon flow in the Oyashio region and in particular their role in the phytoplankton dynamics is significant for the termination of the spring bloom.     

Cobalt, manganese, and iron near the Hawaiian Islands: A potential concentrating mechanism for cobalt within a cyclonic eddy and implications for the hybrid-type trace metals

The vertical distributions of cobalt, iron, and manganese in the water column were studied during the E-Flux Program (E-Flux II and III), which focused on the biogeochemistry of cold-core cyclonic eddies that form in the lee of the Hawaiian Islands. During E-Flux II (January 2005) and E-Flux III (March 2005), 17 stations were sampled for cobalt (n=147), all of which demonstrated nutrient-like depletion in surface waters. During E-Flux III, two depth profiles collected from within a mesoscale cold-core eddy, Cyclone Opal, revealed small distinct maxima in cobalt at 100 m depth and a larger inventory of cobalt within the eddy. We hypothesize that this was due to a cobalt concentrating effect within the eddy, where upwelled cobalt was subsequently associated with sinking particulate organic carbon (POC) via biological activity and was released at a depth coincident with nearly complete POC remineralization [Benitez-Nelson, C., Bidigare, R.R., Dickey, T.D., Landry, M.R., Leonard, C.L., Brown, S.L., Nencioli, F., Rii, Y.M., Maiti, K., Becker, J.W., Bibby, T.S., Black, W., Cai, W.J., Carlson, C.A., Chen, F., Kuwahara, V.S., Mahaffey, C., McAndrew, P.M., Quay, P.D., Rappe, M.S., Selph, K.E., Simmons, M.P., Yang, E.J., 2007. Mesoscale eddies drive increased silica export in the subtropical Pacific Ocean. Science 316, 1017–1020]. There is also evidence for the formation of a correlation between cobalt and soluble reactive phosphorus during E-Flux III relative to the E-Flux II cruise that we suggest is due to increased productivity, implying a minimum threshold of primary production below which cobalt–phosphate coupling does not occur. Dissolved iron was measured in E-Flux II and found in somewhat elevated concentrations (0.5 nM) in surface waters relative to the iron depleted waters of the surrounding Pacific [Fitzwater, S.E., Coale, K.H., Gordon, M.R., Johnson, K.S., Ondrusek, M.E., 1996. Iron deficiency and phytoplankton growth in the equatorial Pacific. Deep-Sea Research II 43 (4–6), 995–1015], possibly due to island effects associated with the iron-rich volcanic soil from the Hawaiian Islands and/or anthropogenic inputs. Distinct depth maxima in total dissolved cobalt were observed at 400–600 m depth, suggestive of the release of metals from the shelf area of comparable depth that surrounds these islands.     

Tide‐modulated hyperpycnal flows off the Huanghe (Yellow River) mouth,China

Few hyperpycnal flows have ever been observed in marine environments although they are believed to play a critical role in sediment dispersal within estuarine and deltaic depositional systems. The paper describes hyperpycnal flows observed in situ off the Huanghe (Yellow River) mouth, their relationship to tidal cycles, and the mechanisms that drive them. Simultaneous observations at six mooring stations during a cruise off the Huanghe mouth in the flood season of 1995 suggest that hyperpycnal flows observed at the river mouth are initiated by high concentrations of sediment input from river and modulated by tides. Hyperpycnal flows started near the end of ebb tides, when near‐bottom suspended sediment concentration (SSC) increased rapidly and salinity decreased drastically (an inverse salt wedge). The median grain size of suspended particles within the hyperpycnal layer increased, causing strong stratification of the suspended sediments in the water column. Towards the end of flood tides, the hyperpycnal flow attenuated due to frictions at the upper and lower boundaries of the flow and tidal mixing, which collapsed the stratification of the water column. Both sediment concentration and median grain size of suspended particles within the bottom layer significantly decreased. The coarser sediment particles were deposited and the hyperpycnal flows stopped. The intra‐tidal behaviors of hyperpycnal flows are closely associated with the variations of SSC, salinity, and stratification of the water column. As nearly 90% of riverine sediment is delivered to the sea during the flood seasons when hyperpycnal flows are active, hyperpycnal flows at the Huanghe mouth and the river's high sediment loads have caused rapid accretion of the Huanghe delta. Copyright © 2010 John Wiley & Sons, Ltd.