Podiform chromitite formation in a low-Cr/high-Al system: An example from the Southwest Indian Ridge (SWIR)

Recent reassessment of abyssal peridotites obtained during the dredging of the oblique supersegment and the easternmost subsection of the Southwest Indian Ridge by the R/V Knorr Cruise 162 and the R/V Yokosuka YK98-07 revealed the occurrence of dunites containing podiform chromitites and dunites with variable chromite concentration closely associated with lherzolite and harzburgite. The size of the chromitite pods varies from a few mm to 2 cm in width. Chromites in the podifom chromitites have very low Cr# (=0.22–0.23) and low TiO₂ (<0.17 wt%). They are almost free of silicate inclusions except for a few euhedral sulfide grains which occur far from cracks and lamellae and are considered primary in origin. The lherzolite which possibly represents the wallrock hosting the dunites with podiform chromitites also show low spinel Cr#(=0.16) and low Cr# in the clinopyroxenes (=0.09–0.10) and orthopyroxenes (=0.07–0.09). The small size of the SWIR podiform chromitites is strongly controlled by the low Cr/Al available in the wallrock and the invading melt. The presence of sulfide inclusions and the absence of PGEs further attest to the low Cr/Al (i.e. low refractoriness) in the system involved in the genesis of the SWIR podiform chromitites. Lastly, the discovery of podiform chromitites in the SWIR implies that the formation of podiform chromitite at mid-oceanic ridges, regardless of its spreading rate, is highly possible.     

Lower Oligocene Calc-Alkaline Spessartitic Lamprophyres from Central Iran (East of Anarak Area); an Evidence from the Eastern Branch of Neotethys Subduction-Related Mantle Enrichment

Geotectonics - The Lower Oligocene Kal-e-kafi (East of Anarak, Central Iran) lamprophyres occur as stocks and dikes, which cross-cut the Eocene volcanic and Cretaceous sedimentary rocks. The...     

http://dx.doi.org/10.1016/j.gsf.2016.11.007

Lunar anorthosite is a major rock of the lunar highlands,which formed as a result of plagioclasefloatation in the lunar magma ocean(LMO).Constraints on the sufficient conditions that resulted in the formation of a thick pure anorthosite(mode of plagioclase 95 vol.%) is a key to reveal the early magmatic evolution of the terrestrial planets.To form the pure lunar anorthosite,plagioclase should have separated from the magma ocean with low crystal fraction.Crystal networks of plagioclase and mafic minerals develop when the crystal fraction in the magma(φ) is higher than ca.40-60 vol.%,which inhibit the formation of pure anorthosite.In contrast,when φ is small,the magma ocean is highly turbulent,and plagioclase is likely to become entrained in the turbulent magma rather than separated from the melt.To determine the necessary conditions in which anorthosite forms from the LMO,this study adopted the energy criterion formulated by Solomatov.The composition of melt,temperature,and pressure when plagioclase crystallizes are constrained by using MELTS/pMELTS to calculate the density and viscosity of the melt.When plagioclase starts to crystallize,the Mg~# of melt becomes 0.59 at 1291 C.The density of the melt is smaller than that of plagioclase for P 2.1 kbar(ca.50 km deep),and the critical diameter of plagioclase to separate from the melt becomes larger than the typical crystal diameter of plagioclase(1.8-3 cm).This suggests that plagioclase is likely entrained in the LMO just after the plagioclase starts to crystallize.When the Mg~# of melt becomes 0.54 at 1263 C,the density of melt becomes larger than that of plagioclase even for 0 kbar.When the Mg~# of melt decreases down to 0.46 at 1218 C,the critical diameter of plagioclase to separate from the melt becomes 1.5-2.5 cm,which is nearly equal to the typical plagioclase of the lunar anorthosite.This suggests that plagioclase could separate from the melt.One of the differences between the Earth and the Moon is the presence of water.If the terrestrial magma ocean was saturated with H_2O,plagioclase could not crystallize,and anorthosite could not form.     

Subsidence of the Miyako‐Sone submarine carbonate platform,east of Miyako‐jima Island,northwestern Pacific Ocean

Bathymetric mapping and observations of the seafloor using a remotely operated vehicle (ROV, Hyper‐Dolphin 3K) were carried out on the slopes of the Miyako‐Sone submarine platform, east of Miyako‐jima in the Ryukyu Islands, northwestern Pacific Ocean. The bathymetric map indicates that terraces are present at water depths of approximately 140 m, 330 m, 400 m, and 680 m on the northwestern slope of the platform. A number of NW–SE trending lineaments, probably faults, extend perpendicular to the axis of the Ryukyu Island Arc. Two ROV surveys were conducted at water depths ranging from 519 m (on the slope) to 121 m (shallowest part of the platform). The surveys revealed that well‐indurated carbonate rocks are exposed at terrace margins and on upper slopes, and that the lower slopes are covered with modern sediments consisting of unconsolidated, coarse‐sand‐sized bioclastic carbonates. Calcareous nannofossils from the well‐indurated carbonate rocks indicate a Middle–Late Pleistocene age, which suggests that the rocks correlate with the Quaternary reef and fore‐reef deposits of the Ryukyu Group (Ryukyu Limestone) on the Ryukyu Islands. No siliciclastic deposits corresponding to the upper Miocene–lower Pleistocene Shimajiri Group (as exposed on Okinawa‐jima and Miyako‐jima islands) were recovered during the surveys. Coeval well‐indurated carbonate rocks, all of which formed in a similar sedimentary environment, have been downthrown towards the west due to displacements on the western sides of normal faults. Subsidence of the Miyako‐Sone submarine platform was the result of large vertical displacements on such normal faults. The timing of initial subsidence cannot be tightly constrained, but the presence of the youngest limestone at progressively lower levels towards the west suggests the subsidence continued until after 0.265 Ma.     

Platinum-group elements distribution and spinel composition in podiform chromitites and associated rocks from the upper mantle section of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco

The distribution of platinum-group elements (PGEs), together with spinel composition, of podiform chromitites and serpentinized peridotites were examined to elucidate the nature of the upper mantle of the Neoproterozoic Bou Azzer ophiolite, Anti-Atlas, Morocco. The mantle section is dominated by harzburgite with less abundant dunite. Chromitite pods are also found as small lenses not exceeding a few meters in size. Almost all primary silicates have been altered, and chromian spinel is the only primary mineral that survived alteration. Chromian spinel of chromitites is less affected by hydrothermal alteration than that of mantle peridotites. All chromitite samples of the Bou Azzer ophiolite display a steep negative slope of PGE spidergrams, being enriched in Os, Ir and Ru, and extremely depleted in Pt and Pd. Harzburgites and dunites usually have intermediate to low PGE contents showing more or less unfractionated PGE patterns with conspicuous positive anomalies of Ru and Rh. Two types of magnetite veins in serpentinized peridotite, type I (fibrous) and type II (octahedral), have relatively low PGE contents, displaying a generally positive slope from Os to Pd in the former type, and positive slope from Os to Rh then negative from Rh to Pd in the latter type. These magnetite patterns demonstrate their early and late hydrothermal origin, respectively. Chromian spinel composition of chromitites, dunites and harzburgites reflects their highly depleted nature with little variations; the Cr# is, on average, 0.71, 0.68 and 0.71, respectively. The TiO₂ content is extremely low in chromian spinels, <0.10, of all rock types. The strong PGE fractionation of podiform chromitites and the high-Cr, low-Ti character of spinel of all rock types imply that the chromitites of the Bou Azzer ophiolite were formed either from a high-degree partial melting of primitive mantle, or from melting of already depleted mantle peridotites. This kind of melting is most easily accomplished in the supra-subduction zone environment, indicating a genetic link with supra-subduction zone magma, such as high-Mg andesite or arc tholeiite. This is a general feature in the Neoproterozoic upper mantle.     

Chemical characteristics of chromian spinel in plutonic rocks: Implications for deep magma processes and discrimination of tectonic setting

We summarize chemical characteristics of chromian spinels from ultramafic to mafic plutonic rocks (lherzolites, harzburgites, dunites, wehrlites, troctolites, olivine gabbros) with regard to three tectonic settings (mid‐ocean ridge, arc, oceanic hotspot). The chemical range of spinels is distinguishable between the three settings in terms of Cr# (= Cr/(Cr + Al) atomic ratio) and Ti content. The relationships are almost parallel with those of chromian spinels in volcanic rocks, but the Ti content is slightly lower in plutonics than in volcanics at a given tectonic environment. The Cr# of spinels in plutonic rocks is highly diverse; its ranges overlap between the three settings, but extend to higher values (up to 0.8) in arc and oceanic hotspot environments. The Ti content of spinels in plutonics increases, for a given lithology, from the arc to oceanic hotspot settings by mid‐ocean ridge on average. This chemical diversity is consistent with that of erupted magmas from the three settings. If we systematically know the chemistry of chromian spinels from a series of plutonic rocks, we can estimate their tectonic environments of formation. The spinel chemistry is especially useful in dunitic rocks, in which chromian spinel is the only discriminating mineral. Applying this, discordant dunites cutting mantle peridotites were possibly precipitated from arc‐related magmas in the Oman ophiolite, and from an intraplate tholeiite in the Lizard ophiolite, Cornwall.     

Comparison of organotin accumulation on the white-spotted charr Salvelinus leucomaenis between sea-run and freshwater-resident types

To examine the accumulation pattern of organotin compounds (OTs) in relation to the migration of diadromous fish, tributyltin (TBT) and triphenyltin (TPT) compounds and their derivatives were determined in the muscle tissue of both sea-run (anadromous) and freshwater-resident (nonanadromous) types of the white-spotted charr Salvelinus leucomaenis. There were generally no significant correlations between the TBT and TPT accumulation and various biological characteristics such as the total length (TL), body weight (BW), age and sex in S. leucomaenis. It is noteworthy that the TBT and TPT concentrations in sea-run white-spotted charr were significantly higher than in freshwater-resident individuals, although they are intraspecies. These results suggest that the sea-run S. leucomaenis has a higher ecological risk of TBT and TPT exposure than the freshwater-residents during their life history.     

Petrology of the Yugu peridotites in the Gyeonggi Massif,South Korea: Implications for its origin and hydration process

Peridotites exposed in the Yugu area in the Gyeonggi Massif, South Korea, near the boundary with the Okcheon Belt, exhibit mylonitic to strongly porphyroclastic textures, and are mostly spinel lherzolites. Subordinate dunites, harzburgites, and websterites are associated with the lherzolites. Amphiboles, often zoned from hornblende in the core to tremolite in the rim, are found only as neoblasts. Porphyroclasts have recorded equilibrium temperatures of about 1000°C, whereas neoblasts denote lower temperatures, about 800°C. Olivines are Fo_90–91 in lherzolites and Fo₉₁ in a dunite and a harzburgite. The Cr# (= Cr/(Cr + Al) atomic ratio) of spinels varies together with the Fo of olivines, being from 0.1 to 0.3 in lherzolites and around 0.5 in the dunite and harzburgite. The Na₂O content of clinopyroxene porphyroclasts is relatively low, around 0.3 to 0.5 wt% in the most fertile lherzolite. The Yugu peridotites are similar in porphyroclast mineral chemistry not to continental spinel peridotites but to sub‐arc or abyssal peridotites. Textural and mineralogical characteristics indicate the successive cooling with hydration from the upper mantle to crustal conditions for the Yugu peridotites. Almost all clinopyroxenes and amphiboles show the same U‐shaped rare earth element (REE) patterns although the level is up to ten times higher for the latter. The hydration was associated with enrichment in light REE, resulting from either a slab‐derived fluid or a fluid circulating in the crust. The mantle‐wedge or abyssal peridotites were emplaced into the continental crust as the Yugu peridotite body during collision of continents to form a high‐pressure metamorphic belt in the Gyeonggi Massif. The peridotites from the Gyeonggi Massif exhibit lower‐pressure equilibration than peridotites, with or without garnets, from the Dabie–Sulu Collision Belt, China, which is possibly a westward extension of the Gyeonggi Massif.     

Early Cretaceous paleogeography of Korea and Southwest Japan inferred from occurrence of detrital chromian spinels

The Sindong Group was deposited in the north–south trending half‐graben Nakdong Trough, southern Korean peninsula. The occurrence of detrital chromian spinels from the Jinju Formation of the Sindong Group in the Gyeongsang Basin means that the mafic to ultramafic rocks were exposed in its provenance. The chromian spinels from the Jinju Formation are characterized by extremely low TiO₂ and Fe³⁺. Moreover, their range of Cr# is from 0.45 to 0.80 and makes a single trend with Mg#. The chemistry of chromian spinels implies that the source rocks for chromian spinels were peridotites or serpentinites, which originated in the mantle wedge. To more narrowly constrain their source rocks, the Ulsan and Andong serpentinites exposed in the Gyeongsang Basin were examined petrographically. Chromian spinels in the Andong serpentinite differ from those of the Jinju Formation and those in the Ulsan serpentinite partly resemble them. Furthermore, the Jinju chromian spinel suite is similar to the detrital chromian spinels from the Mesozoic sediments in the Circum‐Hida Tectonic zone, which includes the Nagato Tectonic zone in Southwest Japan and the Joetsu Belt in Northeast Japan. This suggests that the basement rocks, which were located along the main fault bounding the eastern edge of the Nakdong Trough, had exposures of peridotite or serpentinite. It is possible that the Nakdong Trough was directly adjacent to the Circum‐Hida Tectonic zone before the opening of the Sea of Japan (East Sea).     

Pressure-temperature dependent compositional variation of phlogopitic micas in upper mantle peridotites

Compositional variation of phlogopitic micas in upper mantle peridotites is reviewed. Phlogopitic micas in garnet peridotites are systematically lower in Al (or eastonite component) than those in spinel peridotites. The core of phlogopite megacryst and phenocryst of kimberlite is always lower in Al than the rim. It is apparent that Al/(Al + Si) ratio or eastonite component in phlogopitic micas in ultramafic rocks is controlled by the equilibrium pressure and temperature. In the upper mantle peridotites containing garnet or spinel, the Al/(Al + Si) ratio of phlogopitic mica decreases with increasing pressure at constant temperature. Phlogopitic mica is a potential thermo-barometer in both garnet- and spinel-peridotite facies.