From geometry to dynamics of microstructure: using boundary lengths to quantify boundary misorientations and anisotropy

The microstructure of a quartzite experimentally deformed and partially recrystallised at 900 °C, 1.2 GPa confining pressure and strain rate 10⁻⁶/s was investigated using orientation contrast and electron backscatter diffraction (EBSD). Boundaries between misoriented domains (grains or subgrains) were determined by image analysis of orientation contrast images. In each domain, EBSD measurements gave the complete quartz lattice orientation and enabled calculation of misorientation angles across every domain boundary. Results are analysed in terms of the boundary density, which for any range of misorientations is the boundary length for that range divided by image area. This allows a more direct comparison of misorientation statistics between different parts of a sample than does a treatment in terms of boundary number.The strain in the quartzite sample is heterogeneous. A 100×150 μm low-strain partially recrystallised subarea C was compared with a high-strain completely recrystallised subarea E. The density of high-angle (>10°) boundaries in E is roughly double that in C, reflecting the greater degree of recrystallisation. Low-angle boundaries in C and E are produced by subgrain rotation. In the low-angle range 0–10° boundary densities in both C and E show an exponential decrease with increasing misorientation. The densities scale with exp(−θ/λ) where λ is approximately 2° in C and 1° in E; in other words, E has a comparative dearth of boundaries in the 8–10° range. We explain this dearth in terms of mobile high-angle boundaries sweeping through and consuming low-angle boundaries as the latter increase misorientation through time. In E, the density of high-angle boundaries is larger than in C, so this sweeping would have been more efficient and could explain the relative paucity of 8–10° boundaries.The boundary density can be generalised to a directional property that gives the degree of anisotropy of the boundary network and its preferred orientation. Despite the imposed strain, the analysed samples show that boundaries are not, on average, strongly aligned. This is a function of the strong sinuosity of high-angle boundaries, caused by grain boundary migration. Low-angle boundaries might be expected, on average, to be aligned in relation to imposed strain but this is not found.Boundary densities and their generalisation in terms of directional properties provide objective measures of microstructure. In this study the patterns they show are interpreted in terms of combined subgrain rotation and migration recrystallisation, but it may be that other microstructural processes give distinctive patterns when analysed in this fashion.     

Across-arc variation of lava chemistry in the Izu-Bonin Arc: identification of subduction components

In order to understand the role of the subducted lithosphere in producing the geochemical characteristics of arc magmas, major- and trace-element along with Sr- and Nd-isotope compositions have been determined for Quaternary volcanic rocks from the Izu-Bonin intra-oceanic arc. ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios decrease away from the volcanic front of this arc and lie on mixing lines between the assumed isotopic compositions of fluid phases mainly derived from the basalt layer of the subducted lithosphere and upper-mantle materials in the sub-arc wedge. This across-arc variation can be explained through a simple sequence of processes involving initial release of fluid phases from the subducted oceanic crust to produce hydrous peridotite at the base of the mantle wedge. This hydrous peridotite is dragged downward with the slab and releases a second-stage metasomatizing fluid beneath the volcanic arc. The higher concentrations of both Sr and Nd in the fluid beneath the volcanic front than those beneath the back-arc side may be a possible cause of the observed across-arc variation in Sr-Nd isotopic ratios. The difference in compositions of fluid phases is attributed to the different hydrous phases which decompose in the hydrous peridotite layer; amphibole beneath the volcanic front and phlogopite beneath the back-arc side of the volcanic arc. The mineralogically controlled fluid addition may also be responsible for the across-arc variation in Rb/K and Rb/Zr ratios, increasing away from the volcanic front.     

Effect of atmospheric pressure and temperature on entrapped gas content in peat

Entrapped biogenic gas in peat can greatly affect peatland biogeochemical and hydrological processes by altering volumetric water content, peat buoyancy, and ‘saturated’ hydraulic conductivity, and by generating over‐pressure zones. These over‐pressure zones further affect hydraulic gradients which influence water and nutrient flow direction and rate. The dynamics of entrapped gas are of global interest because the loss of this gas to the atmosphere via ebullition (bubbling) is likely the dominant transport mechanism of methane (CH₄) to the atmosphere from peatlands, which are the largest natural terrestrial source per annum of atmospheric CH₄. We investigated the relationship between atmospheric pressure and temperature on volumetric gas content (VGC) and CH₄ ebullition using a laboratory peat core incubation experiment. Peat cores were incubated at three temperatures (one core at 4 °C, three cores at 11 °C, and one core at 20 °C) in sealed PVC cylinders, instrumented to measure VGC, pore‐water CH₄ concentrations, and ebullition (volume and CH₄ concentrations). Ebullition events primarily occurred (71% of the time) during periods of falling atmospheric pressure. The duration of the drop in atmospheric pressure had a larger control on ebullition volume than the magnitude of the drop. VGC in the 20 °C core increased from the onset of the experiment and reached a fluctuating but time‐averaged constant level between experiment day 30 and 115. The change in VGC was low for the 11 °C cores for the initial period of the experiment but showed large increases when the growth chamber temperature increased to 20 °C due to a malfunction. The core maintained at 4 °C showed only a small increase in entrapped gas content throughout the experiment. The 20 °C core showed the largest increase in VGC. The increases in VGC occurred despite pore‐water concentrations of CH₄ being below the equilibrium solubility level. Copyright © 2009 John Wiley & Sons, Ltd.     

Transitional basalts of alkaline or tholeiitic affinity in the somali trap series (southeastern margin of the main Ethiopian rift from 8° 10′ to 8° 70′ Lat. N)

The Trap Series outcropping in the southeastern margin of the Main Ethiopian Rift has a total thickness of not less than 500–600 m. In this series, mainly composed of flood lavas and rare scoriaceous beds, basaltic rocks — which on a serial viewpoint are transitional basalts — are the best represented. Alkali-olivine basalts (with modal and normative nepheline) are interbedded within the lower and middle members of the series, while in the upper members andesine basalts and dark phonolitic tephrites are present. Among the transitional basalts, rocks of alkaline and of tholeiitic affinity are present as shown by petrographic and chemical analyses. On the basis of petrochemical and geovolcanological data, it is probable that these rocks and the phonolitic-tephrites originated from different primary magmas.     

Geothermal energy prospects in Brazil: A preliminary analysis

Results of geothermal gradient measurements in 44 localities in Brazil are presented. The Precambrian shield areas are found to be characterized by relatively low temperature gradients in the range 6 to 20°C/km while younger sedimentary basins are characterized by gradients in the range 15 to 35°C/km. An inverse correlation between geothermal gradient and tectonic age has been observed. This as well as the favourable hydrological conditions suggest that the best sites for extraction of geothermal energy in Brazil are the younger sedimentary basins. The Parana Basin is found to offer at present the best site for extraction of geothermal energy in Brazil. Preliminary examination of the temperature distributions in the major aquifer (Botucatu sandstone) suggest that this aquifer contains substantial quantities of warm waters in the temperature range 40 to 90°C. The water layer in this confined aquifer is in convective motion and can be considered as a low enthalphy geothermal system. Many of the routine uses to which geothermal waters are put, such as space heating and soil warming, are not applicable in Brazil mainly because of the favourable climatic conditions. Conversion of this geothermal energy into electrical energy is also unlikely to be economical. Hence we do not consider the Parana Basin geothermal system as an independent ec9nomically exploitable energy resource. However, a few other applications are pointed out where geothermal waters can be used as a supplementary or supporting energy source in increasing the efficiency of economically viable systems utilizing hot waters.     

S xi Emission Lines in Active Region Spectra Obtained with the Solar euv Rocket Telescope and Spectrograph (Serts)

Theoretical electron density sensitive emission line ratios involving a total of eleven 2s ²2p ²–2s2p ³ transitions in Sxi between 187 and 292 Å are presented. A comparison of these with solar active region observations obtained during rocket flights by the Solar EUV Rocket Telescope and Spectrograph (SERTS) reveals generally good agreement between theory and experiment. However, the 186.87 Å line is masked by fairly strong Fexii emission at the same wavelength, while 239.83 Å is blended with an unknown feature, and 285.58 Å is blended with possibly Niv 285.56 Å. In addition, the 191.23 Å line appears to be more seriously blended with an Fexiii feature than previously believed. The presence of several new Sxi lines is confirmed in the SERTS spectra, at wavelengths of 188.66, 247.14 and 291.59 Å, in excellent agreement with laboratory measurements. In particular, the detection of the 2s ²2p ^{2 3} P ₁ –2s2p ^{3 3} P _0,1 transitions at 242.91 Å is the first time (to our knowledge) that this feature has been identified in the solar spectrum. The potential usefulness of the Sxi line ratios as electron density diagnostics for the solar transition region and corona is briefly discussed.     

Efficacy of Coagulants and Ballast Compounds in Removal of Cyanobacteria (<Emphasis Type="Italic">Microcystis</Emphasis>) from Water of the Tropical Lagoon Jacarepaguá (Rio de Janeiro,Brazil)

Eutrophication is considered the most important water quality problem in freshwaters and coastal waters worldwide promoting frequent occurrence of blooms of potentially toxic cyanobacteria. Removal of cyanobacteria from the water column using a combination of coagulant and ballast is a promising technique for mitigation and an alternative to the use of algaecides. In laboratory, we tested experimentally the efficiency of two coagulants, polyaluminium chloride (PAC) and chitosan (made of shrimp shells), alone and combined with two ballasts: red soil (RS) and the own lagoon sediment, to remove natural populations of cyanobacteria, from an urban brackish coastal lagoon. PAC was a very effective coagulant when applied at low doses (≤8 mg Al L^?1) and settled the cyanobacteria, while at high doses (≥16 mg Al L^?1) large flocks aggregated in the top of test tubes. In contrast, chitosan was not able to form flocks, even in high doses (>16 mg L^?1) and did not efficiently settle down cyanobacteria when combined with ballast. The RS itself removed 33–47 % of the cyanobacteria. This removal was strongly enhanced when combined with PAC in a dose-dependent matter; 8 mg Al L^?1 was considered the best dose to be applied. The lagoon sediment alone did not promote any settling of cyanobacteria but removal was high when combined with PAC. Combined coagulant and ballast seems a very efficient, cheap, fast and safe curative measure to lessen the harmful cyanobacteria bloom nuisance in periods when particularly needed, such as around the 2016 Olympics in Jacarepaguá Lagoon.