AGN effect on cooling flow dynamics

We analyzed the feedback of AGN jets on cooling flow clusters using three-dimensional AMR hydrodynamic simulations. We studied the interaction of the jet with the intracluster medium and creation of low X-ray emission cavities (Bubbles) in cluster plasma. The distribution of energy input by the jet into the system was quantified in its different forms, i.e. internal, kinetic and potential. We find that the energy associated with the bubbles, (pV+γ pV/(γ−1)), accounts for less than 10 percent of the jet energy.     

Radio and X-ray study of Cygnus A

We present a comparative analysis of 5 GHz VLA and 200 ks Chandra ACIS-I image. In the 5 GHz image the familiar jet and much weaker counterjet are seen, which bend as the jet propagates towards the hotspots. Furthermore, where the lobe detected in 5 GHz emission starts to interact with the jet, we see that the jet “threads”. In the 0.2–10 keV X-ray image we do not detect the jet, but do detect a relic of the counterjet.     

Limitations of Current Approaches for Predicting Groundwater Vulnerability from PFAS Contamination in the Vadose Zone

Published literature for reported sorption coefficients (K_d) of eight anionic per- and polyfluoroalkyl substances (PFAS) in soil was reviewed. K_d values spanned three to five log units indicating that no single value would be appropriate for use in estimating PFAS impacts to groundwater using existing soil-water partition equations. Regression analysis was used to determine if the soil or solution parameters might be used to predict K_d values. None of the 15 experimental parameters collected could individually explain variability in reported K_d values. Significant associations between K_d and soil calcium and sodium content were found for many of the selected PFAS, suggesting that soil cation content may be critical to PFAS sorption, as previously noted in sources like Higgins and Luthy (2006), while organic carbon content was significant only at elevated levels (>5%). Unexplained discrepancies between the results from studies where PFAS were introduced to soil and desorbed in the laboratory and those that used material from PFAS-impacted sites suggest that laboratory experiments may be overlooking some aspects critical to PFAS sorption. Future studies would benefit from the development and use of standardized analytical methods to improve data quality and the establishment of soil parameters appropriate for collection to produce more complete data sets for predictive analysis.     

Resistance of salt marsh substrates to near-instantaneous hydrodynamic forcing

Salt marshes deliver vital ecosystem services by providing habitats, storing pollutants and atmospheric carbon, and reducing flood and erosion risk in the coastal hinterland. Net losses in salt marsh areas, both modelled globally and measured regionally, are therefore of concern. Amongst other controls, the persistence of salt marshes in any one location depends on the ability of their substrates to resist hydrodynamic forcing at the marsh front, along creek margins and on the vegetated surface. Where relative sea level is rising, marsh elevation must keep pace with sea-level rise and landward expansion may be required to compensate for areal loss at exposed margins. This paper reviews current understanding of marsh substrate resistance to the near-instantaneous (seconds to hours) forcing induced by hydrodynamic processes. It outlines how variability in substrate properties may affect marsh substrate stability, explores current understanding of the interactions between substrate properties and erosion processes, and how the cumulative impact of these interactions may affect marsh stability over annual to decadal timescales. Whilst important advances have been made in understanding how specific soil properties affect near-instantaneous marsh substrate stability, less is known about how these properties interact and alter bulk substrate resistance to hydrodynamic forcing. Future research requires a more systematic approach to quantifying biological and sedimentological marsh substrate properties. These properties must then be linked to specific observable erosion processes, particularly at the marsh front and along creek banks. A better understanding of the intrinsic dynamics and processes acting on, and within, salt marsh substrates will facilitate improved prediction of marsh evolution under future hydrodynamic forcing scenarios. Notwithstanding the additional complications that arise from morphodynamic feedbacks, this would allow us to more accurately model the future potential protection from flooding and erosion afforded by marshes, while also increasing the effectiveness of salt marsh restoration and recreation schemes. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Aeolian transport rates across raked and unraked beaches on a developed coast

Wind characteristics and aeolian transport were measured on a naturally evolving beach and dune and a nearby site where the beach is raked and sand‐trapping fences are deployed. The beaches were composed of moderately well sorted to very well sorted fine to medium sand. The backshore at the raked site was wider and the foredune was more densely vegetated and about 1 m higher than at the unraked site. Wind speeds were monitored using anemometers placed at 1 m elevation and sand transport was monitored using vertical traps during oblique onshore, alongshore and offshore winds occurring in March and April 2009. Inundation of the low backshore through isolated swash channels prevented formation of a continuously decreasing cross‐shore moisture gradient. The surface of the berm crest was dryer than the backshore, making the berm crest the greatest source of offshore losses during offshore winds. The lack of storm wrack on the raked beach reduced the potential for sediment accumulation seaward of the dune crest during onshore winds, and the higher dune crest reduced wind speeds and sediment transport from the dune to the backshore during offshore winds. Accretion at wrack seaward of the dune toe on the unraked beach resulted in a wider dune field and higher, narrower backshore. Although fresh wrack is an effective local trap for aeolian transport, wrack that becomes buried appears to have little effect as a barrier and can supply dry sand for subsequent transport. Aeolian transport rates were greater on the narrower but dryer backshore of the unraked site. Vegetation growth may be necessary to trap sand within zones of buried wrack in order to allow new incipient foredunes to evolve. Copyright © 2010 John Wiley & Sons, Ltd.     

Antifouling strategies: history and regulation, ecological impacts and mitigation

Biofouling increases drag on marine vessels resulting in higher fuel consumption and can also facilitate the transport of harmful non-indigenous species (NIS). Antifouling technologies incorporating biocides (e.g., copper and tributyltin) have been developed to prevent settlement of organisms on vessels, but their widespread use has introduced high levels of contamination into the environment and raised concerns about their toxic effects on marine communities. The recent global ban on tributyltin (1 January 2008) and increasing regulation of copper have prompted research and development of non-toxic paints. This review synthesises existing information regarding the ecological impact of biocides in a wide range of organisms and highlights directions for the management of antifouling paints. We focus particularly on representatives of the recent past (copper and tributyltin) and present (copper and ‘booster’) biocides. We identify knowledge gaps in antifouling research and provide recommendations relating to the regulation and phasing-out of copper.     

Extended planar defects and the rapid incorporation of Ti4+ into olivine

The formation of extended planar defects in minerals such as olivine is related to high point defect concentration and can be driven by large gradients in chemical potential, where the energy of the system is lowered by the ordering of defects along specific planes in the crystal. The presence of extended defects has the potential to create the (apparently) anomalous ionic diffusion in olivine as reported recently (Spandler and O’Neill in Contrib Mineral Petrol 159(6):791–818, 2010). High-resolution transmission electron microscopy and energy-filtered imaging were done using experimental samples designed to examine the impact of a _TiO2 and f _O2 on the potential to form such defects in ferromagnesian olivine. Doped basalt (5 wt% TiO₂)–olivine reaction couple experiments were run at 1 atm and 1,310 and 1,410 °C for 50 h at various f _O2, ranging from 10² below to 10² above the quartz–fayalite–magnetite buffer. Our results show that extended planar defects in olivine, parallel to {101}_ol and occurring in ordered “clusters” with a prolate spheroid geometry ~5–25 nm across and extending up to 150 nm into the olivine, are present near the olivine–glass interfaces in all of our experimental high-TiO₂ basalt–olivine samples. Increased Ti content in the olivine is associated with the defects; ordering of Ti⁴⁺ and octahedral site vacancies leads to a two- or three-layer superstructure in the olivine. Defect nucleation and growth is driven by the large TiO₂ chemical potential gradient across the phase boundary at the start of the experiments, which provides access to microstructures not otherwise present.