Geophysical prospection for late Holocene burials in coastal environments: Possibilities and problems from a pilot study in South Australia

Geophysical techniques have been widely employed for the noninvasive location of burial sites in archaeological and forensic investigations. This approach has met with varying degrees of success, depending on factors such as equipment choice, survey methodology, burial type, and geological setting. This paper reports the results of a multitechnique geophysical survey carried out immediately prior to the salvage excavation of two Indigenous burials from an eolian dune in coastal South Australia. Ground‐penetrating radar was not successful in defining the location of the burials owing to the disturbed nature of the local stratigraphy. Magnetic field intensity and apparent magnetic susceptibility surveys identified discrete anomalies that coincided with the location of skeletal material revealed during excavation, which we hypothesize to be due to burning or ochre use during funerary practices. Despite the spatial association of these features, subsequent laboratory analyses of the mineralogy and magnetic properties of sediments collected from the site failed to find a definite cause of the anomalies. Nevertheless, the association between them and the primary interment locations has implications for archaeological surveys carried out in the Australian coastal zone, as it highlights the potential of magnetic field intensity and apparent magnetic susceptibility geophysical techniques undertaken with a more refined survey methodology to afford a noninvasive, culturally appropriate means through which to detect Indigenous burials. This approach may prove particularly useful in areas with disturbed stratigraphy where ground‐penetrating radar is less effective. © 2010 Wiley Periodicals, Inc.     

Decay mechanism of indoor porous opuka stone: a case study from the main altar located in the St. Vitus Cathedral,Prague (Czech Republic)

A carving of the indoor main altar of St. Vitus Cathedral in Prague (Czech Republic) is made of the opuka stone—a clayey–calcareous silicite—which now exhibits the development of decay phenomena such as the formation of salt-laden case-hardened subsurface layer (approx. 150 mm thick), with detachment of the case-hardened layer manifested by blistering and/or flaking. Formation of this gypsum-rich layer is linked to the reaction of components (SO₂) from polluted air (both outdoor and indoor) and from the rock itself (calcium ion from calcite). Development of brittle damage in the subsurface layer and underlying stone is interpreted based on the results from previous environmental monitoring in the Cathedral’s interior, which indicated highly fluctuating temperature and humidity, resulting in a hygrothermal stress in the material described by the “double-layer sandwich” model. The sensitivity of the studied stone to the above-mentioned processes is evidenced by its microstructural properties, specifically parameters of the pore spaces which indicate an extremely high susceptibility to damage by the actions of freezing water and/or salt crystallisation.     

The role of reaction affinity and secondary minerals in regulating chemical weathering rates at the Santa Cruz Soil Chronosequence, California

In order to explore the reasons for the apparent discrepancy between laboratory and field weathering rates and to determine the extent to which weathering rates are controlled by the approach to thermodynamic equilibrium, secondary mineral precipitation, and flow rates, a multicomponent reactive transport model (CrunchFlow) was used to interpret soil profile development and mineral precipitation and dissolution rates at the 226 ka Marine Terrace Chronosequence near Santa Cruz, CA. Aqueous compositions, fluid chemistry, transport, and mineral abundances are well characterized [White A. F., Schulz M. S., Vivit D. V., Blum A., Stonestrom D. A. and Anderson S. P. (2008) Chemical weathering of a Marine Terrace Chronosequence, Santa Cruz, California. I: interpreting the long-term controls on chemical weathering based on spatial and temporal element and mineral distributions. Geochim. Cosmochim. Acta72 (1), 36-68] and were used to constrain the reaction rates for the weathering and precipitating minerals in the reactive transport modeling. When primary mineral weathering rates are calculated with either of two experimentally determined rate constants, the nonlinear, parallel rate law formulation of Hellmann and Tisserand [Hellmann R. and Tisserand D. (2006) Dissolution kinetics as a function of the Gibbs free energy of reaction: An experimental study based on albite feldspar. Geochim. Cosmochim. Acta70 (2), 364-383] or the aluminum inhibition model proposed by Oelkers et al. [Oelkers E. H., Schott J. and Devidal J. L. (1994) The effect of aluminum, pH, and chemical affinity on the rates of aluminosilicate dissolution reactions. Geochim. Cosmochim. Acta58 (9), 2011-2024], modeling results are consistent with field-scale observations when independently constrained clay precipitation rates are accounted for. Experimental and field rates, therefore, can be reconciled at the Santa Cruz site.Additionally, observed maximum clay abundances in the argillic horizons occur at the depth and time where the reaction fronts of the primary minerals overlap. The modeling indicates that the argillic horizon at Santa Cruz can be explained almost entirely by weathering of primary minerals and in situ clay precipitation accompanied by undersaturation of kaolinite at the top of the profile. The rate constant for kaolinite precipitation was also determined based on model simulations of mineral abundances and dissolved Al, SiO₂(aq) and pH in pore waters. Changes in the rate of kaolinite precipitation or the flow rate do not affect the gradient of the primary mineral weathering profiles, but instead control the rate of propagation of the primary mineral weathering fronts and thus total mass removed from the weathering profile. Our analysis suggests that secondary clay precipitation is as important as aqueous transport in governing the amount of dissolution that occurs within a profile because clay minerals exert a strong control over the reaction affinity of the dissolving primary minerals. The modeling also indicates that the weathering advance rate and the total mass of mineral dissolved is controlled by the thermodynamic saturation of the primary dissolving phases plagioclase and K-feldspar, as is evident from the difference in propagation rates of the reaction fronts for the two minerals despite their very similar kinetic rate laws.     

Brackish water faunas from the St Maughans Formation: The Old Red Sandstone section at Ammons Hill,Hereford and Worcester,UK, re-examined

The disused railway cutting at Ammons Hill, Hereford and Worcester, exposes a sequence of beds belonging to the Devonian St Maughans Formation of Lochkovian (Gedinnian) age. The beds are of Old Red Sandstone facies, but contain brackish water faunas. These faunas occur at a level generally considered to be above the level of marine influence that affected the older Raglan Mudstone Formation of mainly Přídolí Series age. The section, described by King in 1934, is now overgrown, but was excavated in 1986 by the British Geological Survey during its survey of the Worcester 1:50000 sheet. The evidence of the section calls for slight amendment of Allen's (1985) model of an interrupted transition from marine deposition in Ludlow time to freshwater deposition in Gedinnian time that was complete by the time of the formation of a regionally extensive calcrete palaeosol, the Psammosteus Limestone. Subsequent transgressive events took place before the establishment of apparently wholly fluvial and floodplain environments.     

The Cwm Llwyd Outlier,Carmarthenshire, South‐West Wales – Britain's deepest karstic subsidence or Variscan pull‐apart structure?

The Cwm Llwyd Outlier of Namurian Middle Shales in the central part of the Black Mountain escarpment of South Wales is an unusual structure. It occupies a topographic depression located more than 2 km from the main outcrop of the Middle Shales and has a stratigraphic discordance with its wall‐rocks of more than 300 m. Previous interpretations advocating a karstic origin imply that this is the deepest known subsidence in Great Britain. However, although the outlier lies among some of the finest epikarst landforms in the country, several factors indicate that the subsidence was not caused by a karstic mechanism. These include the amount of stratigraphic displacement in contrast to the depth of available vertical space in the putative host Carboniferous Limestone, the relatively simple form of the outlier, and the absence of brecciation, marginal solution residues and associated palaeoendokarst features in the adjacent wall‐rocks. The outlier is re‐interpreted here as the product of faulting which occurred during a Variscan strike‐slip or transpressive tectonic regime, producing local sinistral transtension that may have been re‐activated in the Palaeogene period. Remapping the outlier at a scale of 1:2 500 indicates that the present structure is related principally to a left‐stepping offset between the Cwm Llwyd and Llwyn Celyn faults. Analogies are drawn with the Cainozoic pull‐apart structures in Southwest England. Near‐surface reddening and kaolinization of the beds probably represent pre‐Pleistocene weathering. Copyright © 2006 John Wiley & Sons, Ltd.