Biosorption optimization and equilibrium isotherm of industrial dye compounds in novel strains of microscopic fungi

The aim of this study was to evaluate the biosorption capacity of selected strains of microscopic fungi. We optimized the biosorption process and used the Freundlich isotherm for three strains: H. haematococca BwIII43, K37 and T. harzianum BsIII33 to describe the biosorption equilibrium of anthraquinone dye, Alizarin Blue Black B (ABBB) and alkali lignin (AL). In optimal conditions (1 g of mycelium biomass, pH = 7.0, 28 °C) for ABBB and AL sorption, the live biomass of H. haematococca BwIII43 was characterized by a higher sorption capacity, amounting to 247.47 and 161.00 mg g^?1, respectively. The highest sorption properties toward anthraquinone dye (K _F = 19.96 mg g^?1) were shown for the biomass of H. haematococca K37. In the presence of alkali lignin, the highest sorption capacity and bond strength exhibited the biomass of H. haematococca BwIII43 (K _F = 28.20 mg g^?1, n = 3.46). Effective decolorization of ABBB and AL by the selected strains of microscopic fungi indicated that the biosorption process additionally enhanced the removal of color compounds from the solution.     

Non-woven polypropylene fabric modified with carbon nanotubes and decorated with nanoakaganeite for arsenite removal

Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L^?1, at pH 6.5 and with a sorbent dose of 5 g L^?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g^?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g^?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided.     

Mg-enriched erythrite from Bou Azzer,Anti-Atlas Mountains,Morocco: geochemical and spectroscopic characteristics

Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,...     

A GIS-based WFD oriented typology of shallow micro-tidal soft bottom using wave exposure and turbidity mapping

Our GIS based project aims at producing a classification scheme to develop a typology of the bottom of the Bay of Gdansk in the southern Baltic. The typology was based on the abiotic factors which are used to define water body types by the European Water Framework Directive (WFD). Significance analysis of particular factors has shown that within the discussed area wave exposure seems to play the most important role. All other factors are to a greater or lesser degree correlated with these two. Taking into consideration the shallows and the varied coastline of the investigated area it was decided to make use of the SWAN numerical wave model to determine the influence of wave impact upon the bottom. The model was used to produce raster maps of orbital velocity near the bottom for each wind scenario. With the help of the GIS analysis the maps were turned into layers: the mean velocity and the maximum velocity at the bottom. To produce the layer of yearly amount of solar radiation a GIS model was built which main parameters were the layer of depth and three layers of turbidity for three seasons. The layers of the maximum orbital velocity and of the solar radiation at the bottom were then used in a classificatory procedure consisted in an iterative sequence of the three following steps: cluster formation, dendrogram analysis and classification using the maximum likelihood method. Ecological importance of the classification has been obtained by means of the aggregation of a part of classes based upon the statistics calculated for them within the GIS system with the help of the zonal function out of the following parameters: salinity, depth, mean and maximum orbital velocity at the bottom, temperature differences between warm and cold seasons, solar radiation, and type of sediments. The method proposed here makes it possible to produce high resolution thematic maps of the bottom even with incomplete data cover of the investigated area.     

Dissolved organic carbon in the southern Baltic Sea: Quantification of factors affecting its distribution

During a cruise of r/v ‘Oceania’ in May 2006, seven vertical dissolved organic carbon (DOC) concentration profiles were produced against a background of CTD, chlorophyll a (chl a) and phaeopigment concentration profiles. The results indicate distinct vertical and spatial DOC fluctuations, ranging from 248 ± 7 μmol C dm⁻³ at 70 m depth at the westernmost station G/06 to 398 ± 5 μmol C dm⁻³ at 5 m depth at station A/06 in the western Gulf of Gdańsk. DOC concentrations were the highest at 10 m depth, where phytoplankton activity was relatively intensive, as reflected by the active chl a concentration distribution. DOC concentrations decreased towards the sea bottom.     

Abundance and Taxonomic Diversity of Bacteria Inhabiting the Sediment-Water Interface in a Marine Harbor Channel

Ocean Science Journal - The abundance of bacteria inhabiting the sediment-water interface and their taxonomic composition were determined with the fluorescence in situ hybridization (FISH) method...     

Versuch der Geschlechtsbestimmung beim Wels,Silurus glanis L., mit Hilfe der Diskriminanzanalyse von Brustflossendaten

Width of the first ray of the pectoral fin has been measured in two places for 154 young and 89 adult wels. Statistical relationships between the above characters and fish length as well as its maturity and sex have been proved. Three models of discriminant function for identification of adult fish sex have been derived and verified. The accuracy of sex separation has been 89,5% in a standard sample of wels, and 90,6% in a routine sample, after an adjustment in the procedure.