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141.
Paul M. Myrow Jahandar Ramezani Anne E. Hanson Samuel A. Bowring Grzegorz Racki Michał Rakociński 《地学学报》2014,26(3):222-229
Precise U–Pb zircon dates from three volcanic ash beds that bracket the Hangenberg Shale in the Holy Cross Mountains, Poland, constrain the age and duration of one of the most significant palaeobiological events of the Palaeozoic Era, the Hangenberg Event. It is linked to a terminal Devonian global shift from greenhouse to icehouse climate conditions, a global transgression, and widespread black shale deposition. Our results constrain the Hangenberg Event to between 358.97 ± 0.11 Ma and 358.89 ± 0.20 Ma, with a calculated duration of 0.05 +0.14/?0.05 Ma. A third, underlying ash bed yielded a distinctly older age of 359.97 ± 0.46 Ma. The duration of ~50–100 ka. for the event is comparable to those of Quaternary glaciations, and is consistent with both a glacio‐eustatic origin for the eustatic fluctuations and changes in ocean chemistry that led to this major reorganization of the biosphere. 相似文献
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Konrad Miotliński 《Aquatic Geochemistry》2008,14(2):117-131
The reactive transport modeling of a complicated suite of reactions apparent in the aquifer during the application of N-containing
fertilizers is reported. The unconfined sandy aquifer can be subdivided into an oxic zone which contains groundwater with
oxygen and nitrate and an anoxic zone characterized by elevated iron and sulfate concentrations in groundwater. Oxygen and
nitrate are being reduced by pyrite and organic matter that commonly apparent in the aquifer. The oxidation of pyrite is modeled
using the local equilibrium approach, whereas decomposition of organic matter, with the adoption of kinetic approach. The
system is buffered by dissolution of aluminum and iron oxides. The modeling process is a two-step procedure. First, the processes
are modeled in the one-dimensional (1D) column using PHREEQC code. Subsequently, the calibrated and verified data were copied
and used in two-dimensional (2D) PHAST model. Prior to the performance of reactive transport modeling operations with PHAST,
a reliable flow model was executed. Finally, predictions are made for the distribution of water chemistry for the year 2008.
Model predicts that sulfate derived from the ongoing pyrite oxidation is reduced by the dissolved organic carbon at the higher
depth and forms pyrite by the reaction with iron. The results of this study highlight the importance of understanding the
interplay between the transport and chemical reactions that occur during the input of nitrate to the aquifer. Reactive transport
modeling incorporating the use of a newly developed code PHAST have proved to be a powerful tool for analyzing and quantifying
such interactions. 相似文献
144.
Summary Pre-Variscan basement in southern Poland is poorly exposed and thus known mostly from subsurface data. The availability of the latter is reviewed for terrains located between the Sudetes and the East European Platform. In these terrains the following relationships have been documented: Cadomian granitoids capped by Variscan flysch, Palaeozoic platform strata, Palaeozic folded and partly thermally altered successions, and low-grade metamorphic rocks overlain by Middle Cambrian strata. In view of their interrelationships the location of the Avalonia-Baltica suture in southeastern Poland is uncertain. 相似文献
145.
There are about 50 galactic planetary nebulae know to have [WR] type nuclei. We have compared their nebular properties with those of the other planetary nebulae in the Galaxy. We have found that the nebular morphological types are similarly distributed in the two groups. Bipolar nebulae constitute only 20% of the total in each group. The distribution of the nebular electron densities and abundance ratios N/O, He/H and C/O are the same in the two groups. The only marked difference is that nebular expansion velocities are larger in the group of planetary nebulae with [WR] central stars. We argue that the WR phenomenon does not preferentially occur in more massive central stars of planetary nebulae, contrary to what has been suggested in some former studies. We demonstrate that, for most of the observed [WR] type objects, the WR phenomenon cannot be triggered by a late helium shell flash event.The results of our investigation are published inAstronomy & Astrophysics
303, 893 (1995) and in the proceedings of the 2nd International Colloquium on Hydrogen-deficient Stars, C.S. Jeffery & U. Heber (eds), Astronomical Society of the Pacific Conference Series, Vol. 96, p. 209 (1996). 相似文献
146.
Mining in the Upper Silesian Coal Basin, Poland, induces tremors with magnitudes ranging up to 4.3. The recordings of mining tremors from the near-wave fiel and the far-wave field show different characteristics of ground motion.Knowledge of these characrteristics, has an enormous practical importance when solving the problems of resistance of underground workings against seismic impacts. The near-wave field is characterized by a domination of the high frequency components of motion, and the seismograms often are a single pulse Geomechanical interpretation of them leads to the conclusion that this pulse corresponds to a single exciting force. This fact is also reflected in the rockbursts: the potentially damaging ground motion which is restricted to the seismic source region.The seismometric data have shown that the peak particle velocities from a hypocentral distance of 200–300 m, resulted in more than 3 cm/s. The peak ground velocities appear to be dependent on stress drop , and peak particle velocities reaching 5 m/s may occur. The computational example proves that in a thick coal seam the pulse with the stress =1.8 MPa from the tremor at the short source distance can generate the rockburst. 相似文献
147.
Secondary Ion Mass Spectrometry Bias on Isotope Ratios in Dolomite–Ankerite,Part II: δ13C Matrix Effects 下载免费PDF全文
Maciej G. Śliwiński Kouki Kitajima Reinhard Kozdon Michael J. Spicuzza John H. Fournelle Adam Denny John W. Valley 《Geostandards and Geoanalytical Research》2016,40(2):173-184
This study is Part II of a series that documents the development of a suite of calibration reference materials for in situ SIMS analysis of stable isotope ratios in Ca‐Mg‐Fe carbonates. Part I explored the effects of Fe2+ substitution on SIMS δ18O bias measured from the dolomite–ankerite solid solution series [CaMg(CO3)2–CaFe(CO3)2], whereas this complementary work explores the compositional dependence of SIMS δ13C bias (calibrated range: Fe# = 0.004–0.789, where Fe# = molar Fe/(Mg+Fe)). Under routine operating conditions for carbonate δ13C analysis at WiscSIMS (CAMECA IMS 1280), the magnitude of instrumental bias increased exponentially by 2.5–5.5‰ (session‐specific) with increasing Fe‐content in the dolomite structure, but appeared insensitive to minor Mn substitution [< 2.6 mole % Mn/(Ca+Mg+Fe+Mn)]. The compositional dependence of bias (i.e., the matrix effect) was expressed using the Hill equation, yielding calibration residual values ≤ 0.3‰ relative to CRM NBS‐19 for eleven carbonate reference materials (6‐μm‐diameter spot size measurements). Based on the spot‐to‐spot repeatability of a drift monitor material that ‘bracketed’ each set of ten sample‐spot analyses, the analytical precision was ± 0.6–1.2‰ (2s, standard deviations). The analytical uncertainty for individual sample analyses was approximated by combining the precision and calibration residual values (propagated in quadrature), suggesting an uncertainty of ± 1.0–1.5‰ (2s). 相似文献
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